A method for preparing a vapor sensitive sacrificial support material. The method may include decomposing a polycondensed PEO polymer with heat in the presence of a graphene-like material to release PEO polymer radicals from the polycondensed PEO polymer, such that at least a portion of the PEO polymer radicals become trapped on at least a portion of a surface of the graphene-like material to form a coated graphene-like material, which may be defined as a structural reinforcement material. The method may further include forming the vapor sensitive water-soluble thermoplastic polyethylene oxide graft polymer. The vapor sensitive water-soluble thermoplastic polyethylene oxide graft polymer may include a polyethylene oxide polymer backbone. The vapor sensitive water-soluble thermoplastic polyethylene oxide graft polymer may further include one or more nanoscopic particulate processing aids. The structural reinforcement material may be uniformly dispersed in the vapor sensitive water-soluble thermoplastic polymer composite.

The disclosed methods relate to forming microneedle arrays from a production mold that comprises a flexible mold material. The disclosed methods can be used to reproducibly manufacture undercut dissolvable and coated microneedle arrays with various shapes and structures.

An apparatus and method for embossing a substrate are disclosed. For example, the apparatus includes an embossing platform, a printhead to dispense ink on the embossing platform in a desired raised pattern on the embossing platform, a press to apply a load against a substrate placed on the desired raised pattern and the embossing platform to emboss the desired raised pattern onto the substrate, and an ink removal device to remove the ink that is dispensed on the embossing platform in the desired raised pattern.

A method of forming an automatic dishwashing pouch comprising the steps of: providing a sheet of material (10); identifying one or more regions of the material; heating the material with a heating device having a non-uniform heating profile, the non-uniform heating profile arranged to heat the identified region(s) to a greater temperature than other regions of the material; and forming the material in a mould to form the automatic dishwashing pouch, the automatic dishwashing pouch including a plurality of cavities (12).

A water dispersible sulfopolymer for use as a material in the layer-wise additive manufacture of a 3D part made of a non water dispersible polymer wherein the water dispersible polymer is a reaction product of a metal sulfo monomer, the water dispersible sulfo-polymer being dispersible in water resulting in separation of the water dispersible polymer from the 3D part made of the non water dispersible polymer.

A water soluble polymer composition includes a water soluble polymer and a sugar and may be used as a support in additive manufacturing processes.

A method of forming dual layer water soluble packets includes drawing a base film into a cavity of a mold, drawing air through openings in the base film, metering an amount of a first product of a first color onto the base film in the cavity, metering an amount of a second product of a second color onto the amount of the first product, and, sealing a lid film to the base film.

Provided are a water-soluble film having excellent solubility in water and capable of reducing the stickiness of the contact surfaces to each other at the edges during storage in rolls, a production method thereof, and a package using the water-soluble film. A water-soluble film of the present invention includes a polyvinyl alcohol resin. The water-soluble film satisfies a formula (1) below when amounts of crystalline component are respectively (A1).sub.0, (A1).sub.60, and (A1).sub.180, the amounts being obtained from a spin-spin relaxation curve by .sup.1H pulse NMR measurement of the water-soluble film immediately after, 60 seconds after, and 180 seconds after the water-soluble film is immersed in a mixed solution of deuterated water and deuterated methanol mixed at a volume ratio of 1:1 at 5° C.

[00001]$\begin{array}{cc}\left(\mathrm{Math}1\right)& \\ 0.2<{\left(A1\right)}_{60}/{\left(A1\right)}_0<0.6\mathrm{and}{\left(A1\right)}_{180}/{\left(A1\right)}_0<{\left(A1\right)}_{60}/{\left(A1\right)}_0& \left(1\right)\end{array}$

A water-soluble film is provided that is capable of achieving deformation resistance during pouch storage as well as excellent water solubility of the film and excellent reduction in undissolved residues. A water-soluble film includes a polyvinyl alcohol-based resin, wherein a crystal long period Ds obtained from an X-ray profile obtained by small-angle X-ray scattering measurement in a water/methanol mixed solvent (volume ratio: 2/8) is from 10.0 to 30.0 nm and a rate of increase (DS−Da)/Da of the crystal long period Ds to a crystal long period Da obtained by small-angle X-ray scattering measurement before immersion in the solvent is 30% or more and 130% or less.

A mold configuration for forming a pocket in a film comprising: a film support surface; a perimeter edge at said film support surface; wall surfaces inward of the perimeter edge defining a mold cavity; the wall surfaces including transition wall surfaces extending to a bottom wall surface; and a plateau surface inward of the perimeter edge. In one form, the perimeter edge includes sharp corner profile perimeter edge portions defining at least one sharp corner profile. A method of forming a pouch, includes using the disclosed mold configuration.