An embodiment of the present specification provides a latex composition for dip-forming, comprising a copolymer latex obtained by polymerizing a monomer mixture of a conjugated diene-based monomer, an ethylenically unsaturated nitrile monomer and an ethylenically unsaturated acid monomer; and a polyester polyol, and a dip-formed article prepared therefrom.

The described invention relates to an ambidextrous working glove having fish scale-textured inner and outer surfaces and methods of making same.

Disclosed herein is a method of forming a mold comprising disposing a film having a textured surface on a support; pressing the film onto the support to cover a surface of the support; disposing a backing on the film; separating the support from the backing; and molding a material in the backing. Disclosed herein too is a method comprising contacting a first mandrel with a first mold; where the first mold has a textured surface; texturing a surface of the first mandrel with the first mold; disposing the first mandrel in a die; disposing a first material in the die to contact the first mandrel; imparting a texture from the surface of the first mandrel onto the material to form a second mold; and disposing a texture from the second mold onto a second material; where the second material is different from the first material.

Methods and processes are described that enable the manufacture of a superior thin-walled mold from which higher-quality, less-costly disposable gloves can be more efficiently produced. The method can include creating a glove form in a sacrificial material; electroforming an electroformed master from the glove form; removing sacrificial material from the electroformed master; creating a tertiary form from the electroformed master; forming an initial copper layering on the tertiary form; and developing the initial copper layering into a thick copper plating to create a copper mold for gloves.

A process for thermo-adhesive bonding of semi-finished products includes preparing an inner sock, an outer sock and an impermeable membrane provided with a thermo-adhesive disposed on an inner surface and/or an outer surface of the membrane; fitting the inner sock onto a rigid reference shape; fitting the membrane over the inner sock; fitting the outer sock over the membrane; heating the outer sock, the membrane and the inner sock arranged on the rigid reference shape in an oven until at least partial melting of the thermo-adhesive; cooling the outer sock, the membrane and the inner sock arranged on the rigid reference shape until cross-linking of the thermo-adhesive and stable bonding of the membrane to the outer sock and/or the inner sock. Also, exerting a substantially uniform pressure on the outer sock, the membrane and the inner sock disposed on the rigid reference shape during cooling, so as to compact them.

An elastomeric glove includes a body-facing layer of a first elastomeric material, a middle layer of a second elastomeric material, and an outer layer of a third elastomeric material different than at least the second elastomeric material. The third elastomeric material has an acrylonitrile content greater than at least the second elastomeric material.

An improved glove has both anatomically correlating stress relief zones and/or reinforced zones to add support in areas opposite the stress relief zones to keep bunching or slipping of the glove from interfering with the bending of the user's joints. The glove may have corrugated relief zones over some or all of the joints and knuckles of the hand, wherein the relief zones are formed of peaks and valleys. A relief zone can also be provided over the webbing between the thumb and the palm. The vertical or longitudinal relief zones provide for improved glove quality while keeping manufacturing difficulty and costs at a minimum.

A layered, laminated glove includes an outer layer, a membrane formed from a liquid-resistant, air permeable material positioned on an inner surface of the outer layer and a liner formed from a moisture absorbing material. The liner is positioned on an inner surface of the membrane. The outer layer, membrane and liner are laminated to form a single glove. The glove includes a plurality of fingertip portions in which the outer layer, membrane and liner are substantially fully laminated throughout. The glove may include a 3D pattern formed in one or more layers of the laminate. The glove may include an enlarged knuckle section. A hand mold and system for making the gloves and a method are also disclosed.

The present invention relates to a chloroprene copolymer latex composition, a molded article of chloroprene copolymer rubber, or a dip-molded product, and the chloroprene copolymer latex composition includes a chloroprene copolymer (A) and a vulcanization accelerator (B). The chloroprene copolymer (A) includes monomer units derived from chloroprene and from 2-methyl-1,3-butadiene. The chloroprene copolymer latex composition includes a carbamate-based vulcanization accelerator and a thiazole-based vulcanization accelerator as the vulcanization accelerator (B). The chloroprene copolymer latex composition enables production of a molded article having high flexibility and high tensile strength without use of a vulcanization accelerator that is feared to have skin sensitization.

A carboxylic acid-modified nitrile-based copolymer latex includes a carboxylic acid-modified nitrile-based copolymer including: 65.5 wt % to 82.5 wt % of a conjugated diene-based monomer-derived unit, 15 wt % to 30 wt % of an ethylenic unsaturated nitrile-based monomer-derived unit, and 2.5 wt % to 4.5 wt % of an ethylenic unsaturated acid monomer-derived unit, wherein the carboxylic acid-modified nitrile-based copolymer latex satisfies General Formula 1:

1.0 mm.sup.2/s≤CV.sub.0≤3.0 mm.sup.2/s  [General Formula 1]

wherein CV.sub.0 represents a capillary viscosity of the carboxylic acid-modified nitrile-based copolymer latex which is measured in a swollen state in a methyl ethyl ketone solvent.