The invention relates to an imageable coating layer, thermal negative-working lithography printing plate, and platemaking method. The coating layer includes constituents in parts by weight: a radically polymerizable compound 20-60 parts, a radiation-absorbing compound 0.5-12 parts, a free radical initiator 1-25 parts, a binding agent 10-70 parts, and a development accelerator 0.5-15 parts. The platemaking method includes the steps: S1, preparing a printing plate precursor that includes a substrate having a hydrophilic surface or is provided with a hydrophilic layer and imageable coating layer covering the substrate; S2, patternedly exposing the printing plate precursor, forming an exposed area and an unexposed area; and S3, removing the unexposed area via a development process. The employment of the imageable coating layer and the plate making method allows the implementation of a flexible development process of on-press development or off-press development and produces a printing plate provided with great printing performance.

Provided are a positive type planographic printing plate precursor including: a support which has a hydrophilic surface; and an image recording layer on the support, the image recording layer containing: a polymer compound 1 having at least one bond selected from the group consisting of a urea bond, a urethane bond, and a carbonate bond in a main chain and containing a sulfonamide group in the main chain; a polymer compound 2-1 having at least one of a constitutional unit represented by Formula S-1 or a constitutional unit represented by Formula S-2 or a polymer compound 2-2 having a constitutional unit represented by Formula EV-1 and a constitutional unit represented by Formula EV-2; and an infrared absorbent, and a method of producing a planographic printing plate obtained by using the positive type planographic printing plate precursor.

##STR00001##

The present invention provides an on-press development type lithographic printing plate precursor including, in the following order, a support, an image-recording layer, and a protective layer, in which the image-recording layer contains a) a polymerizable compound, b) an infrared absorber, c) a polymerization initiator, and d) a color forming substance precursor, and the protective layer contains an ultraviolet absorber, and a method of preparing a printing plate.

The present invention provides a support for a lithographic printing plate, from which a lithographic printing plate precursor having excellent scratch resistance can be obtained by combining the support with an image recording layer, a lithographic printing plate precursor, and a method of producing a lithographic printing plate. The support for a lithographic printing plate according to the present invention, including an aluminum plate, and an anodized aluminum film disposed on the aluminum plate, in which a plurality of projections are present on a surface of the support for a lithographic printing plate on a side of the anodized film, an average value of equivalent circular diameters of the projections in a cut surface at a position that is 0.5 ?m greater than a position of the projections with an average height is in a range of 3.0 to 10.0 ?m, and a density of the projections with a height of 0.5 ?m or greater from the position of the projections with the average height is in a range of 3,000 to 9,000 pc/mm.sup.2.

The present invention aims at providing a lithographic printing plate precursor, a lithographic printing plate manufacturing method, a printing method and an aluminum support manufacturing method that enable the resulting lithographic printing plate to have a long tiny dot press life. The lithographic printing plate precursor of the invention is a lithographic printing plate precursor having an aluminum support and an image recording layer disposed above the aluminum support. When measured over a 400 m400 m region of a surface of the aluminum support on the image recording layer side using a three-dimensional non-contact roughness tester, pits with a depth from centerline of at least 0.70 m are present at a density of at least 3,000 pits/mm.sup.2; and a surface area ratio S is not less than 35%, the surface area ratio S being determined using an actual area S.sub.x obtained, through three-point approximation, from three-dimensional data acquired by measurement at 512512 points in 25 m square of the surface of the aluminum support on the image recording layer side by means of an atomic force microscope and a geometrically measured area S.sub.o.

The present invention provides a silicone composition for use in a printing plate, the composition including at least: a SiH group-containing compound; a compound represented by the following general formula (I); a compound represented by the following general formula (II); and/or a compound represented by the following general formula (III); wherein Ds in the compound represented by the general formula (I), Gs in the compound represented by the general formula (II) and Js in the compound represented by the general formula (III) each represents an acetoxy group or a dialkyloximino group: A-Si-(D).sub.3 (I) (wherein in the general formula (I), A represents a non-hydrolyzable functional group capable of undergoing a hydrosilylation reaction with a SiH group); E-Si-(G).sub.3 (II) (wherein in the general formula (II), E represents a non-hydrolyzable functional group incapable of undergoing a hydrosilylation reaction with a SiH group); and Si-(J).sub.4 (III). An object of the present invention is to provide a silicone composition for use in a printing plate, for obtaining a planographic printing plate precursor or a planographic printing plate which includes a silicone rubber layer having an excellent adhesion to an underlying layer despite being a fast-curing silicone rubber layer, and which has an excellent ink repellency and scratch resistance.

Provided is a positive type photosensitive resin composition including: a polymer compound which contains, in a main chain thereof, a sulfonamide group and a structure represented by Formula A-1; and an infrared absorbent. In Formula A-1, X represents NR.sup.1, S, or O, R.sup.1 represents a hydrogen atom or an alkyl group, and each symbol * independently represents a bonding position with respect to another structure.

##STR00001##

A color developing composition which develops colors in a high density and does not significantly discolor when aged, a lithographic printing plate precursor which has excellent plate-inspecting properties by means of color development and is capable of maintaining strong color development even when aged after color development, a plate making method for a lithographic printing plate in which the lithographic printing plate precursor is used, and a new compound that can be preferably used as a color developer. The color developing composition of the present invention includes a compound represented by Formula 1. The compound in the present invention is represented by Formula 1. In Formula 1, R.sup.1 represents a group in which an R.sup.1O bond is cleaved by heat or exposure to infrared rays. ##STR00001##

A lithographic printing plate precursor is disclosed including a support and a coating comprising (i) a photopolymerisable layer including a polymerisable compound and a photoinitiator, and a toplayer provided above the photopolymerisable layer: characterized in that the toplayer includes a halogenated polymer and a nitrite and/or nitrate salt.

Flexographic printing members are prepared from a flexographic printing plate precursor consisting essentially of: backing film, water- or water-dispersible photosensitive layer, and cover sheet in contact with the photosensitive layer. The cover sheet is removed and a mask element is laminated directly in contact with the photosensitive layer. Exposure through the mask element provides exposed regions and non-exposed regions. The non-exposed regions are removed with an aqueous developer having: a) a C.sub.12-20 saturated or unsaturated fatty acid (or alkali metal salt) at 0.25-2.0 weight %, and at least 85 weight % of a C.sub.18 mono- or poly-unsaturated fatty acid (or alkali metal salt); b) an aminopolycarboxylic acid (or alkali metal salt) at 0.05-0.30 weight %; c) a buffer at 05-0.60 weight %; and d) water. The photosensitive layer has a controlled release of 5-500 g/cm using ASTM D-3330 Method D, between its front imaging surface and the mask element.