A drawing system according to an embodiment of the present disclosure includes a light source section and a scanning section. The light source section generates a plurality of laser light beams having wavelengths that are different from each other and each correspond to an absorption wavelength of a photothermal conversion agent included in a recording medium. The scanning section scans a surface of the recording medium with the plurality of laser light beams in a state in which irradiation spots of the plurality of laser light beams are arranged side by side at predetermined intervals in a direction orthogonal to or obliquely intersecting with a scanning direction of the plurality of laser light beams.

An offset printing process for manufacturing a laser markable packaging uses a laser markable offset ink and a laser markable varnish or a laser markable dispersion-lacquer in the process to provide a laser markable image or area on the packaging. The laser markable offset ink, offset varnish or offset dispersion-lacquer including a leuco dye and a metal free optothermal converting agent may be used in the offset printing process.

An offset printing process for manufacturing a laser markable packaging uses a laser markable offset ink and a laser markable varnish or a laser markable dispersion-lacquer in the process to provide a laser markable image or area on the packaging. The laser markable offset ink, offset varnish or offset dispersion-lacquer including a leuco dye and a metal free optothermal converting agent may be used in the offset printing process.

Color change compositions that transition from a first to second color state upon application of an applied stimulus are provided. Also provided are substrates having the compositions on a surface thereof, as well as methods of making and using the compositions.

A heat-sensitive recording material has a web-shaped substrate, having a front side and a reverse side opposite the front side, a heat-sensitive recording layer disposed to the front side of the web-shaped substrate, including at least one dye precursor and at least one (color) developer reactive with this at least one dye precursor. A front-side surface of the heat-sensitive recording material is formed dehesively with respect to layers of adhesive applied to the reverse side of the web-shaped substrate. The dehesive front-side surface includes a furnish which is disposed above the heat-sensitive recording layer and comprises at least one release agent. A diffusion layer is formed between the furnish and the heat-sensitive recording layer. A method for producing a heat-sensitive recording material of this kind, and possibilities for its use.

A heat-sensitive recording material has a web-shaped substrate, having a front side and a reverse side opposite the front side, a heat-sensitive recording layer disposed to the front side of the web-shaped substrate, including at least one dye precursor and at least one (color) developer reactive with this at least one dye precursor. A front-side surface of the heat-sensitive recording material is formed dehesively with respect to layers of adhesive applied to the reverse side of the web-shaped substrate. The dehesive front-side surface includes a furnish which is disposed above the heat-sensitive recording layer and comprises at least one release agent. A diffusion layer is formed between the furnish and the heat-sensitive recording layer. A method for producing a heat-sensitive recording material of this kind, and possibilities for its use.

The present invention relates to an N,N-diarylurea derivative represented by the following general formula (1) and a method for producing the same. In addition, the present invention relates to a thermosensitive recording material in which a thermosensitive recording layer including a basic dye which is colorless or lightly colored at room temperature and a developer capable of developing color upon contact with the basic dye by heating is provided on a base sheet, wherein the developer is the N,N-diarylurea derivative represented by the following general formula (1):

##STR00001##

(wherein R2 is an alkyl group, an aralkyl group, or an aryl group; and Al is a hydrogen atom or an alkyl group).

The present invention relates to an N,N-diarylurea derivative represented by the following general formula (1) and a method for producing the same. In addition, the present invention relates to a thermosensitive recording material in which a thermosensitive recording layer including a basic dye which is colorless or lightly colored at room temperature and a developer capable of developing color upon contact with the basic dye by heating is provided on a base sheet, wherein the developer is the N,N-diarylurea derivative represented by the following general formula (1):

##STR00001##

(wherein R2 is an alkyl group, an aralkyl group, or an aryl group; and Al is a hydrogen atom or an alkyl group).

A label (20) may have a facestock (21). A direct thermal coating layer (21A) may be on the facestock (21), the direct thermal coating configured to selectively darken or change color by heat activation when direct thermal printed. A layer of adhesive (22) may be provided, the direct thermal coating layer (21A) being between the facestock (21) and the layer of adhesive (22).

Provided is a thermosensitive recording medium including a support and a thermosensitive recording layer disposed on or above the support. The thermosensitive recording layer include a compound represented by General Formula (1) and a styreneacryl resin, where, in General Formula (1), R.sub.2 is a C1-12 straight-chain, branched-chain, or alicyclic alkyl group, C7-12 aralkyl group that is substituted with a C1-12 alkyl group, a C1-12 alkoxy group, a C6-12 aryl group or a halogen atom, or a C6-12 aryl group that is unsubstituted or substituted with a C1-12 alkyl group, a C1-12 alkoxy group, a C6-12 aryl group, or a halogen atom, where two or more R.sub.2 may be identical to or different from each other; and A.sub.1 is a hydrogen atom or a C1-4 alkyl group, where two or more A.sub.1, may be identical to or different from each other.

##STR00001##