Provided is a thermosensitive recording medium, which is excellent in color developing property, especially excellent in bar code readability, under severe environment, further, excellent in resistance to discoloration under severe environment. That is a thermosensitive recording medium having a thermosensitive recording layer comprising a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent on a substrate, wherein the thermosensitive recording layer comprises, as the electron accepting color developing agent, a specific sulfone compound and a phenolic compound in a specific ratio, wherein the phenolic compound contains two or more hydroxyl groups and two or more diphenylsulfone backbone but contains neither urethane bond nor urea bond. The thermosensitive recording layer optionally may further comprise a specific urea-urethane-based compound.

A heat-sensitive recording material having i) a carrier substrate and ii) a heat-sensitive recording layer. The heat-sensitive recording layer contains a color former and a color developer mixture and the color developer mixture contains a) N/-[2-(3-phenylureido)phenyl]benzole sulfonamide (compound of formula (I)). The compound of formula (I) is present in a crystalline form, which has an absorption band in the IR spectrum at 340120 cm1, and b) N-(4-methylphenylsulfonyl)-N-(3-(4-methylphenylsulfonyloxy)phenyl)urea (compound of formula (II)).

A label assembly including one or more dissolvable thermal direct adhesive labels and methods of assembly and use. According to one embodiment, each label includes a base layer, a thermal direct layer, an adhesive layer, and a barrier layer. The base layer, which has an upper surface and a lower surface, is water-dissolvable and may be made of a water-dissolvable paper. The thermal direct layer is positioned directly over the upper surface of the base layer and functions in the conventional manner to produce markings therein in response to heat. The adhesive layer is water-dissolvable and is positioned below the lower surface of the base layer. The barrier layer, which is positioned directly below the lower surface of the base layer and directly over the adhesive layer, serves to prevent migration of the adhesive layer through the base layer and into contact with the thermal direct layer.

A heat-sensitive recording material including a substrate, a heat-sensitive recording layer which includes N-(4-methylphenylsulfonyl)-/V-(3-(4-methylphenylsulfonyloxy)pheny-purea and/or N42-(3-phenylureido)phenyl]benzol sulfonamide, and an intermediate layer which is arranged between the substrate and the heat-sensitive recording layer and which includes calcined aluminum silicate, and a method for producing a heat-sensitive recording material and to the use of calcined aluminum silicate in an intermediate layer of a heat-sensitive recording material.

In the present invention, there is provided a use of 1,1,1-tris(4-hydroxyphenyl)ethane in a composition in the formation of an image on a substrate having said composition applied thereon, wherein the image is formed upon exposure of the composition to NIR or IR radiation, and wherein the image is capable of being retained on the substrate for at least 1 day under conditions of at least 50% relative humidity. The present invention is further directed towards compositions comprising 1,1,1-tris(4-hydroxyphenly)ethane, in addition to substrates, methods of forming an image and printing processes comprising said compositions.

To provide a heat-sensitive recording material which produces images with excellent resistance to water, while producing background with resistance to heat. A heat-sensitive recording material which is characterized by containing at least one compound represented by general formula (1) as a color-developing compound: ##STR00001##
wherein, R1-R5 each independently represents a hydrogen atom, a halogen atom, a nitro group, an amino group, an alkyl group, an alkoxy group, an aryloxy group, an alkylcarbonyloxy group, an arylcarbonyloxy group, an alkylcarbonylamino group, an arylcarbonylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, a monoalkylamino group, a dialkylamino group or an arylamino group.

A composition includes a capsules having an improved solvent and heat resistance. The capsules are prepared via interfacial polymerization between a polyisocyanate including at least one substituted or unsubstituted arylene or heterearyl group and a compound including an active hydrogen. The capsules include a leuco dye and may be used in laser markable compositions.

An erasing unit according to an embodiment of the present disclosure is a unit that performs erasing of information written on a reversible recording medium. This erasing unit includes: a light source section including one or a plurality of laser devices; and a controller that controls the light source section to cause the light source section to emit a smaller number of laser light beams having emission wavelengths than the number of the recording layers included in the reversible recording medium.

The present invention relates to method of manufacturing a tamper-proof medium for thermal printing, wherein a liquid treatment composition comprising at least one acid is deposited on a substrate which comprises a thermochromic coating layer comprising at least one halochromic leuco dye.

A three-dimensional structure according to an embodiment of the present disclosure includes a plurality of resin layers including a light curable resin, a coloring compound, a color developing-reducing agent, and a photothermal conversion agent, the plurality of resin layers being stacked.