The present invention relates to thermal recording materials comprising (in order): a support (base) layer; one or more undercoat layers; a thermal layer (thermosensitive coloring layer); and one or more protective layers, wherein the thermal recording material contains an aminocarboxylic and/or phosphorus-based chelating agent.

The thermal (thermosensitive) recording materials of the invention show enhanced plasticizer resistance and/or preprint uniformity.

The invention relates to a heat-sensitive recording material, comprising a carrier substrate and at least one heat-sensitive thermal reaction layer, which is applied to at least one side of the carrier substrate and contains at least one fluoran color former, at least one color developer, at least one melting aid, and optionally typical additives, such as lubricants, stabilizers (anti-aging agents), and/or pigments, characterized in that the color developer is dodecyl gallate and the melting aid is an ethylene bis fatty acid amide of formula (I), wherein R.sub.1 and R.sub.2 are CH.sub.3(CH.sub.2).sub.mCH.sub.2 with m=13 and/or 15. The invention further relates to a method for producing said recording material.

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The invention relates to a heat-sensitive recording material. A heat-sensitive recording material, comprising a carrier substrate and a heat-sensitive, color-forming layer that contains at least one color former and at least one phenol-free color developer, is characterized in that said at least one color developer is a compound of formula (I) where Ar.sub.1 and Ar.sub.2 are a phenyl group and/or a C.sub.1-C.sub.4-alkyl substituted phenyl group. The invention also relates to a method for producing this heat-sensitive recording material and to the use, in a heat-sensitive recording material, of the color developer of formula (I) that is present in said heat-sensitive, color-forming layer. ##STR00001##

The present invention relates to a thermosensitive recording material and, specifically, to a thermosensitive recording material comprising: a colorless or light-colored leuco dye; a compound of chemical formula (1) containing a non-phenolic sulfonyl urea group as a developer; at least one of general formulas II-1, II-2, and II-3 as a sensitizer; a binder; and other fillers. The thermosensitive recording material of the present invention improves the background blurring of a color-developed image by using a non-phenolic developer and exhibits excellent effects in view of color development sensitivity, water resistance, oil resistance, plasticizer resistance, and the like.

Provided is a thermosensitive recording medium having a sufficient water resistance to moisture and humidity, such as for outdoor use in rainy weather and the like, and also having a superior color developing sensitivity, print image quality when printing at high speed, ink fixability and solvent resistance and the like. As the protective layer comprises a specific silane-modified acrylic resin which is an aqueous emulsion of core-shell type p articles, in a thermosensitive recording medium having a thermosensitive recording layer on a substrate and a protective layer on the thermosensitive recording layer, the thermosensitive re cording medium has a sufficient water resistance and also has a superior color developing sensitivity, print image quality when printing at high speed, ink fixability and solvent resistance and the like.

Provided is a thermosensitive recording medium having a sufficient water resistance to moisture and humidity, such as for outdoor use in rainy weather and the like, and also having a superior color developing sensitivity, print image quality when printing at high speed, ink fixability and solvent resistance and the like. As the protective layer comprises a specific silane-modified acrylic resin which is an aqueous emulsion of core-shell type p articles, in a thermosensitive recording medium having a thermosensitive recording layer on a substrate and a protective layer on the thermosensitive recording layer, the thermosensitive re cording medium has a sufficient water resistance and also has a superior color developing sensitivity, print image quality when printing at high speed, ink fixability and solvent resistance and the like.

A color laser markable article includes at least a first and a second laser markable layer including, respectively, a first infrared dye IR-1 having an absorption maximum in the infrared region .sub.max(IR-1) and a second infrared dye IR-2 having an absorption maximum in the infrared region .sub.max(IR-2), characterized in that the color laser markable layers further include a Diffusion Hindered Molecular Assembly (DHMA) which contains a leuco dye.

A color laser markable article includes at least a first and a second laser markable layer including, respectively, a first infrared dye IR-1 having an absorption maximum in the infrared region .sub.max(IR-1) and a second infrared dye IR-2 having an absorption maximum in the infrared region .sub.max(IR-2), characterized in that the color laser markable layers further include a Diffusion Hindered Molecular Assembly (DHMA) which contains a leuco dye.

A heat-sensitive recording material including a web-shaped substrate having a front side and an opposite reverse side, and at least one heat-sensitive recording layer on either or both of the sides of the web-shaped substrate. The heat-sensitive recording layer contains at least one dye precursor at least one salicylic acid derivative as a (color) developer reactive with this at least one dye precursor, and polyvinylpyrrolidone as auxiliary component augmenting the (color) developer the at least one salicylic acid derivative is 3,5-di(-methylbenzyl)salicylic acid.

The present invention relates to a thermally printable paper article with an elastomeric underlayer, which imparts improved printing performance.