A laminate of a thermoplastic resin or thermoplastic elastomer composition film and a rubber composition layer, which can be used as an inner liner for a pneumatic tire, with improved adhesive strength at the interface of the thermoplastic resin or thermoplastic elastomer composition film and the rubber composition layer. A laminate comprising a thermoplastic resin or thermoplastic elastomer composition film and a rubber composition layer, the rubber composition containing a rubber component, a condensate of a phenol compound and formaldehyde, and methylene donor and a vulcanizing agent, wherein 2.5-40% by mass of the rubber component is halogenated isomonoolefin-p-alkyl styrene copolymer, the content of the condensate is 0.5-20 parts by mass per 100 parts by mass of the rubber component, and the content of the methylene donor is 0.25-200 parts by mass per 100 parts by mass of the rubber component.

A multilayered structure having a layer A constituted with a resin composition containing a gas barrier resin, and a layer B being adjacent to the layer A and being constituted with a resin composition containing an elastomer. The total number of the layer A and the layer B is at least 7. The average thickness of the layer A in terms of a single layer is no less than 0.001 m and no greater than 10 m, and the average thickness of the layer B in terms of a single layer is no less than 0.001 m and no greater than 40 m. The multilayered structure is formed by irradiating with an active energy ray. Furthermore, an inner liner having the multilayered structure, and a pneumatic tire provided with the inner liner are provided.

A method for manufacturing a pneumatic tire including: (a) an assembly step of bonding the inner liner and an unvulcanized rubber sheet with end portions thereof in a width direction being displaced from each other in the range of 50 mm to 500 mm in the width direction to manufacture a laminate; (b) a cutting step of cutting the laminate to have a constant length corresponding to a width of a drum to manufacture a cut sheet; and (c) a joining step of winding the cut sheet on entire circumference of the drum such that a cut surface thereof extends in a circumferential direction of the drum and the inner liner is disposed on an inner surface side, and joining the end portions of the inner liner and joining the end portions of the unvulcanized rubber sheet.

A pneumatic tire is provided in which an inner tie rubber layer and an outer tie rubber layer are selectively disposed between a carcass layer and an innerliner layer in a region on both sides in a tire width direction excluding a center region of a tread portion. End portions of the inner tie rubber layer and outer tie rubber layer on a tire equator side are disposed within a range of from 10 mm to 25 mm on an inner side in the tire width direction from an end portion on an outermost side in the tire width direction of a belt layer. A rubber thickness t1 of the inner tie rubber layer differs from a rubber thickness t2 of the outer tie rubber layer. A rubber thickness of the outer tie rubber layer is from 120% to 200% a rubber thickness of the inner tie rubber layer.

Provided is a pneumatic tire having an innerliner member pasted on a tire inner circumferential surface, the innerliner member being constituted from an at least three-layer structure including a film having a main component of a thermoplastic resin or a thermoplastic elastomer composition containing a blend of a thermoplastic resin and an elastomer, and rubber sheets layered on both sides of the film, the tire comprising a lap splice portion in which tire circumferential direction end portions of the film are overlapped via the rubber sheets. In the lap splice portion, the thickness of the film positioned at least on the tire radial direction inner side decreases toward the tip of the end portion thereof, and this tip bends toward the outer side or the inner side in the tire radial direction, and the tip is covered by the rubber sheets.

Inflatable article equipped with a layer impermeable to the inflation gases, of improved hysteresis and impermeability. The layer comprises an elastomer composition comprising at least, as the sole elastomer or as the predominant elastomer by weight, a thermoplastic styrene elastomer (TPS) and a platy filler having a volume content greater than 5%. According to one preferred embodiment, the TPS elastomer is a copolymer with polystyrene and polyisobutylene blocks such as SIBS (styrene/isobutylene/styrene) and the composition also comprises an extender oil for the elastomer, in particular a PIB (polyisobutylene) oil. The platy filler is especially chosen from graphites and phyllosilicates such as micas, clays or talcs. The inflatable article can be an inner tube or a pneumatic tire for a motor vehicle.

A laminate of a thermoplastic resin or thermoplastic elastomer composition film and a rubber composition layer, which can be used as an inner liner for a pneumatic tire, with improved adhesive strength at the interface of the thermoplastic resin or thermoplastic elastomer composition film and the rubber composition layer. A laminate comprising a thermoplastic resin or thermoplastic elastomer composition film and a rubber composition layer, the rubber composition containing a rubber component, a condensate of a phenol compound and formaldehyde, and methylene donor and a vulcanizing agent, wherein 2.5-40% by mass of the rubber component is butyl rubber or halogenated butyl rubber, the content of the condensate is 0.5-20 parts by mass per 100 parts by mass of the rubber component, and the content of the methylene donor is 0.25-200 parts by mass per 100 parts by mass of the rubber component.

A pneumatic tire is configured in such a manner that at least two carcass layers each have both end portions in the tire width direction extending to bead cores disposed in both bead portions, and the both end portions are wound up from the inner side in the tire width direction of the bead cores to the outer side in the tire width direction, and extend outward in the tire radial direction. In such a pneumatic tire, the carcass layers are formed by thermoplastic sheets, and a rubber layer is disposed at least between adjacent sheets of the thermoplastic sheets.

A method for manufacturing a pneumatic tire uses a tire vulcanizing bladder including a plurality of vent lines, and is characterized in that the pneumatic tire includes an inner liner on an inner surface thereof, the inner liner has an SIBS layer containing a styrene-isobutylene-styrene triblock copolymer, the SIBS layer has a thickness of more than or equal to 0.05 mm and less than or equal to 0.6 mm, the SIBS layer contains more than or equal to 0.5% by mass and less than or equal to 40% by mass of a polymer obtained by polymerization of a monomer unit having 4 carbon atoms, and the vent lines each include a first vent line at a part corresponding to from a tire bead toe part to a tire buttress part, and a second vent line at a part corresponding to from the tire buttress part to a tire crown part.

A pneumatic tire is formed by winding a sheet member (A) and a sheet member (B) onto a molding drum and molding a cylindrical body. A laminate body (M) in which the sheet member (B) is layered in advance on the outer periphery of the sheet member (A) is wound onto a molding drum (10), the tack value of a material (a) constituting the sheet member (A) being smaller than the tack value of a material (b) constituting the sheet member (B), the length of the sheet member (A) being configured so that a starting end (As) of winding on the molding drum (10) and an ending end (Ae) of winding do not overlap, and the length of the sheet member (B) being configured so that the ending end (Be) of winding extends longer in the circumferential direction than the ending end (Ae) of winding of the sheet member (A).