A system and method for processing unconditioned syngas first removes solids and semi-volatile organic compounds (SVOC), then removes volatile organic compounds (VOC), and then removes at least one sulfur containing compound from the syngas. Additional processing may be performed depending on such factors as the source of syngas being processed, the products, byproducts and intermediate products desired to be formed, captured or recycled and environmental considerations.

In a device for separating methane from a gas mixture containing methane, carbon dioxide and hydrogen sulfide, comprising a gas compressor, two or three membrane separation stages downstream of the compressor and a hydrogen sulfide adsorber, comprising a bed of activated carbon having catalytic activity for oxidizing hydrogen sulfide with oxygen, arranged upstream of the membrane separation stages, oxygen content and relative humidity can be adjusted for optimum adsorption capacity of the hydrogen sulfide adsorber by recycling permeate from the second membrane separation stage, which receives the retentate of the first membrane separation stage, to a point upstream of the hydrogen sulfide adsorber.

An apparatus for capturing a water content from a water containing gas, the apparatus comprising: a housing having an inlet into which the water containing gas can flow; a water adsorbent located in the housing, the water adsorbent comprising at least one water adsorbent metal organic framework composite capable of adsorbing a water content from the water containing gas; and a water desorption arrangement in contact with and/or surrounding the water adsorbent, the water desorption arrangement being selectively operable between (i) a deactivated state, and (ii) an activated state in which the arrangement is configured to apply heat, a reduced pressure or a combination thereof to the water adsorbent to desorb a water content from the water adsorbent.

The present disclosure relates to novel metal-organic frameworks (MOFs) comprising tetratopic ligands with small pore apertures. The present disclosure further relates to methods of utilizing the MOFs of the disclosure to separate hydrocarbons through adsorptive processes.

A natural gas adsorptive separation system and method is described. A method of separating natural gas includes directing a natural gas mixture through an activated carbon adsorption tower until the adsorption tower is saturated, collecting methane from the output of the adsorption tower, heating the saturated carbon adsorption tower with adsorbate using a heater and/or a vacuum pump in a closed loop circuit with the carbon adsorption tower until the input to the vacuum pump is within a specified temperature of the output of the heater, lowering the pressure in the heated activated carbon adsorption tower using the vacuum pump to desorb at least one hydrocarbon compound of the plurality of different hydrocarbon compounds, compressing and cooling the desorbed hydrocarbon compound, separating the cooled and compressed hydrocarbon compound into gas and liquid in a fluid separator, and collecting the liquid from the fluid separator.

Disclosed in certain embodiments are methods of removing water from a gas feed stream comprising hydrocarbons and water during an adsorption step of an adsorption cycle.

The present invention concerns a process for the separation of a gas mixture containing CO.sub.2 and at least one inert gaseous species, comprising (a) feeding the gas mixture into an adsorption column via a first inlet located at a first side of the column, wherein the adsorption column contains a solid CO.sub.2 sorbent loaded with H.sub.2O molecules and thereby desorbing H.sub.2O molecules and adsorbing CO.sub.2 molecules, to obtain a sorbent loaded with CO.sub.2 and an inert product stream; and then (b) feeding a stripping gas comprising H.sub.2O into the adsorption column via a second inlet located at a second side which is opposite to the first inlet, thereby stripping the sorbent and desorbing CO.sub.2 molecules and adsorbing H.sub.2O molecules, to obtain a sorbent loaded with H.sub.2O and the CO.sub.2 product stream, wherein the adsorption column is re-used in step (a) after being stripped in step (b). The invention also concerns an apparatus for performing the process according to the invention.

A composite material is used for desulfurization. The composite material contains activated carbon, alkali metal oxides, silicon oxides, iron oxides, and rare earth element oxides. The weight ratio among the activated carbon, iron oxides and rare earth element oxides is 100:(0.5-5):(1-10). The composite material, used as a sulfur adsorbent, has a higher sulfur breakthrough capacity and desulfurization rate.

A water harvesting device includes at least a first adsorption column including a first inlet, a first outlet, and a first interior region. A sorbent material is located within the first interior region of the first adsorption column. The sorbent material includes a metal organic framework (MOF) material including a plurality of metal ions or clusters of metal ions coordinated to one or more organic linkers, a plurality of nanofabrics comprising a hydrogel material, or a combination thereof.

A system for generating hydrogen includes an ammonia decomposition bed configured to introduce an ammonia gas, decompose the ammonia gas into a high-pressure first mixed gas including nitrogen and hydrogen, and discharge the high-pressure first mixed gas; an ammonia adsorption bed supplied with the high-pressure first mixed gas from the ammonia decomposition bed, and configured to adsorb ammonia of the first mixed gas, and discharge a high-pressure second mixed gas including nitrogen and hydrogen; and a nitrogen adsorption bed directly supplied with the high-pressure second mixed gas from the ammonia adsorption bed, and configured to adsorb the nitrogen, and discharge the hydrogen.