Method for removal of soot, ash and metals or metal compounds, together with removal of NOx and SOx being present in process off-gasses or engine exhaust gasses.

The current invention consists of a method and device that is coated with at least one predeposited photocatalyst to reduce or eliminate exhaust emissions and powered by a thermoelectric generator. The method and device comprises a light source emitting sufficient light between 10 nm and 700 nm for the photocatalyst coating and a means to attach said method and device to the source of exhaust emissions.

An oxidation catalyst for treating an exhaust gas from a diesel engine, which oxidation catalyst comprises: a first washcoat region comprising platinum (Pt), manganese (Mn) and a first support material; a second washcoat region comprising a platinum group metal (PGM) and a second support material; and a substrate having an inlet end and an outlet end; wherein the second washcoat region is arranged to contact the exhaust gas at the outlet end of the substrate and after contact of the exhaust gas with the first washcoat region.

The present disclosure generally provides catalysts, catalyst articles and catalyst systems including such catalyst articles. In particular, the catalyst composition includes a metal ion-exchanged molecular sieve ion-exchanged with at least one additional metal, which reduces the number of metal centers often present in metal promoted zeolite catalysts. Methods of making and using the catalyst composition are also provided, as well as emission treatment systems including a catalyst article coated with the catalyst composition. The catalyst article present in such emission treatment systems is useful to catalyze the reduction of nitrogen oxides in gas exhaust in the presence of a reductant while minimizing the amount of dinitrogen oxide emission.

Systems, methods, and apparatus are contemplated in which a tube cell that produces a dielectric barrier discharge (DBD) is individually configured to minimize the mixing of unwanted byproducts of the generated plasma with an exhaust air stream. The tube cell generates a DBD within a tube cell, such that oxidants or radicals are generated in an environment substantially separated from the exhaust stream. The generated oxidants are directed to intersect with the exhaust stream to minimize the generation of unwanted byproducts. The tube cells are further shaped and arranged in tube cell arrays to alter the flow dynamics of the exhaust stream and the oxidant or radical streams, including mixing of the streams.

An engine assembly includes a diesel internal combustion engine and an aftertreatment system coupled to the diesel internal combustion engine. The aftertreatment system includes a diesel oxidation catalyst coupled to the diesel internal combustion engine such that the diesel oxidation catalyst receives exhaust gases from the diesel internal combustion engine. The aftertreatment system includes a plasma generator in fluid communication with the diesel oxidation catalyst, wherein the plasma generator is upstream of the diesel oxidation catalyst and downstream of the diesel internal combustion engine, and the plasma generator is configured to generate oxidizers to at least partially oxidize hydrocarbons in the exhaust gases exiting the diesel internal combustion engine.

An exhaust system for a diesel engine comprises an oxidation catalyst for treating an exhaust gas from the diesel engine and an emissions control device, wherein the oxidation catalyst comprises: a first washcoat zone for oxidizing carbon monoxide (CO) and hydrocarbons (HCs), wherein the first washcoat zone comprises a first platinum group metal (PGM), which is a combination of platinum and palladium, a first support material and a hydrocarbon adsorbent material, which is a zeolite, and wherein the first washcoat zone does not comprise rhodium and is substantially free of manganese or an oxide thereof; a second washcoat zone for oxidizing nitric oxide (NO), wherein the second washcoat zone comprises platinum (Pt) and manganese (Mn) disposed or supported on a second support material, wherein the second support material comprises a refractory metal oxide, wherein the refractory metal oxide is silica-alumina or an alumina doped with silica in a total amount of 0.5 to 45% by weight of the alumina, and wherein the second washcoat zone does not comprise a hydrocarbon adsorbent material, which is a zeolite; and a substrate having and inlet end and an outlet end, and wherein the second washcoat zone is disposed at an outlet end of the substrate, and the first washcoat zone disposed at an inlet end of the substrate; and wherein the emissions control device is a selective catalytic reduction (SCR) catalyst, a selective catalytic reduction filter catalyst, a diesel particulate filter (DPF), or a catalyzed soot filter (CSF).

An oxidation catalyst for treating an exhaust gas from a diesel engine comprises: a first washcoat region for oxidising carbon monoxide (CO) and hydrocarbons (HCs), wherein the first washcoat region comprises a first platinum group metal (PGM) and a first support material, and wherein the first washcoat region does not comprise manganese or an oxide thereof; a second washcoat region for oxidising nitric oxide (NO), wherein the second washcoat region comprises platinum (Pt), manganese (Mn) and a second support material comprising a refractory metal oxide, which is silica-alumina or alumina doped with silica in a total amount of 0.5 to 45% by weight of the alumina, wherein the platinum (Pt) is disposed or supported on the second support material and the manganese (Mn) is disposed or supported on the second support material; and a substrate having an inlet end and an outlet end, and wherein the first washcoat region is a first washcoat layer and the second washcoat region is a second washcoat layer, and the second washcoat layer is disposed on the first washcoat layer; and wherein when the oxidation catalyst comprises a hydrocarbon adsorbent, which is a zeolite, then the first washcoat region further comprises the hydrocarbon adsorbent

An oxidation catalyst is described for treating an exhaust gas produced by a diesel engine. The oxidation catalyst comprises: a substrate; a capture material for capturing at least one sulfur containing impurity in the exhaust gas produced by the diesel engine; wherein the capture material comprises a metal for reacting with an oxide of sulfur in the exhaust gas and particles of a refractory oxide, wherein the particles of the refractory oxide have a mean specific surface area ?50 m.sup.2/g; and a catalytic region disposed on the substrate; wherein the catalytic region comprises a catalytic material comprising a platinum group metal (PGM) selected from the group consisting of platinum (Pt), palladium (Pd) and a combination of platinum (Pt) and palladium (Pd).

A catalytic converter includes a hydrocarbon catalyst trap including BEA zeolite configured to adsorb iso-octane at ambient temperatures and desorb iso-octane at temperatures between 150 C. and 170 C., and active metal supercage impregnated USY zeolite configured to adsorb and coke iso-octane at temperatures greater than 150 C.