Drainage water that includes anions and cations dissolved in water and that is received from an agricultural or industrial facility is treated by applying a voltage to an anode and a cathode on opposite sides of an electrically driven separation apparatus that further includes at least one monovalent-selective ion exchange membrane between the anode and the cathode. The drainage water is passed through the electrically driven separation apparatus, wherein monovalent ions are selected from the drainage water through the monovalent-selective ion exchange membrane. The drainage water is then recirculated as treated water through the facility after the monovalent ions are removed.

An alternating current electrodialysis device that uses two synergistic energy efficiency-increasing improvements to a traditional electrodialysis system: (1) membranes which rectify ionic currents and (2) supercapacitor electrodes. Together these components enable alternating current electrodialysis, offering significantly decreased system complexity, improved energy efficiency, and increased systems lifetimes.

A process for the removal of divalent cations, such as calcium and magnesium, from a saline aqueous solution such as a natural brine comprising lithium, using an electrolytic cell comprising at least one anion exchange membrane. The process allows removal of undesired components before lithium recovery, by reducing their concentrations to less than 0.1% of their original concentration in the brine while the lithium concentration remains unchanged.

Electrodialysis cell systems for water deionization is provided. Also provided are methods for using the electrodialysis cell systems. The cells use the forward and reverse reactions of a redox mediator and the combined operations of a deionization cell and an ion-accumulation cell to enable sustainable deionization with a significantly decreased operating voltage, relative to conventional deionization cells. The cells have applications in seawater desalination, water purification, and wastewater treatment.

The present disclosure is directed to ion-exchange systems and devices that can monitor key parameters related to the performance of the ion-exchange device. Specifically, the ion-exchange systems and devices disclosed herein can provide real time voltage drop across groups of membrane pairs using diagnostic spacer borders between the pairs. In addition, the ion-exchange systems and devices disclosed herein can monitor the compression force applied by the compression plates holding the ion-exchange systems and devices together.

An ion exchange membrane according to the present disclosure is provided with: a cation exchange composition body that is composed of cation exchange resin particles and a binder resin; and an anion exchange composition body that is composed of anion exchange resin particles and a binder resin. At least one of the cation exchange composition body and the anion exchange composition body is configured to contain a thermally infusible additive.

A three-dimensional photo/electrodialysis unit includes four compartments. A first compartment holds a three-dimensional electrode and a group of one or more electrochemically active redox species. A first electroactive cation selective membrane couples the first compartment to a second compartment that provides a first feedstock. An electroactive anion selective membrane couples the second compartment to a third compartment that provides a second feedstock. And a second electroactive cation selective membrane couples the third compartment to a fourth compartment

Described are improved electrodialysis (ED) desalination systems and methods comprising voltage regulation and/or improved stack geometries. The systems and methods provide product water concentrations suitable for drinking (having a total dissolved solids concentration of less than 500 mg/L or 500 ppm) and have a high product recovery ratio.

Electrochemical treatment devices for treating water and methods of assembling the devices are provided. Disclosed masking and potting techniques allow separate feeds to be delivered to and/or collected from the depleting compartments and concentrating compartments.

The present disclosure describes a flow-electrode capacitive deionization (FCDI) desalination system and method of use. The system employs clusters of tubular membranes oriented parallel to each other, each membrane having an internal flow path capable of receiving an electrolyte slurry (carbon slurry) therethrough. Each tubular membrane further comprises an electrode coaxially extending through the entire length of the electrode. Preferably, adjacent electrodes within the cluster receive a positive or negative charge, respectively. The cluster of tubular membranes is nested within a flow chamber capable of receiving saline or brackish water to be flowed along the outside surfaces of the tubular membranes to cause selected ions, e.g., Na+, Cl to pass through the membranes and into the carbon slurry circuit. The desalinated water then passes out of the flow chamber. The outer diameter of the electrodes can be optimized based on the inner diameter of the tubular membrane.