A method suppresses membrane thickness variation and air resistance variation after a compression at 60 C. or 80 C. Stretching is performed at least twice in at least different axial directions before the extraction of the solvent, and at the same time, at least one of (i) and (ii) is satisfied. (i) The step (c) is a first stretching step of stretching the sheet-shaped product at least once in a sheet transport direction (MD direction) and at least once in a sheet width direction (TD direction) individually, and the MD stretching magnification and the TD stretching magnification in the step (c) satisfy (TD stretching magnification MD stretching magnification2). (ii) The stretching temperature (T1) of a first axial stretching performed firstly in the step (c) and the maximal stretching temperature (T2) of a second stretching performed after the first axial stretching satisfy (T1T20).

Provided is a novel continuous single-step method of manufacturing a multilayer sorbent polymeric membrane having superior productivity, properties and performance. At least one layer of the polymeric membrane comprises sorbent materials and a plurality of interconnecting pores. The method includes: (a) coextruding layer-forming compositions to form a multilayer coextrudate; (b) casting the coextrudate into a film; (c) extracting the film with an extractant; and (d) removing the extractant from the extracted film to form the multilayer sorbent polymeric membrane. The sorbent membrane of this disclosure can find a wide range of applications for use in filtration, separation and purification of gases and fluids, CO.sub.2 and volatile capture, structural support, vehicle emission control, energy harvesting and storage, electrolyte batteries, device, protection, permeation, packaging, printing, and etc.

The present disclosure relates to improved semipermeable membranes based on acrylonitrile copolymers for use in dialyzers for the extracorporeal treatment of blood in conjunction with hemodialysis, hemofiltration or hemodiafiltration. The present disclosure further relates to methods of producing such membranes.

A microporous membrane has average membrane thickness of 15 m or less, and relative impedance A after a heat compression treatment under a pressure of 4.0 MPa at 80 C. for 10 minutes of 140% or less, the relative impedance A being obtained by the equation below: Relative impedance A=(impedance measured at 80 C. after the heat compression treatment)/(impedance measured at room temperature prior to the heat compression treatment)100.

A film-stretching apparatus in accordance with an embodiment of the present invention includes a stretching furnace which is divided into a plurality of air amount control zones. In a case where the number of the plurality of air amount control zones is seven, a total amount of air to be discharged from, out of the plurality of air amount control zones, three air amount control zones which are located on an entrance side of the stretching furnace is controlled so as to be larger than a total amount of air to be discharged from, out of the plurality of air amount control zones, three air amount control zones which are located on an exit side of the stretching furnace.

Disclosed are hydrophilic porous PTFE membranes comprising PTFE and an amphiphilic copolymer of the formula (I): ##STR00001##
wherein Rf, Rh.sub.1, Rh.sub.2, Y, m, n, and o are as described herein. Also disclosed are a method of preparing hydrophilic porous PTFE membranes and a method of filtering fluids through such membranes.

The present invention relates to a composite porous hollow-fiber membrane including a first layer and a second layer which each include a fluororesin-based polymer, in which the first layer has a columnar texture oriented in a longitudinal direction of the composite porous hollow-fiber membrane, the columnar texture has an average value v of a Raman orientation parameter calculated with the specific formula, and the second layer has a three-dimensional network texture and has an average surface-pore diameter of 5.0 nm to 5.0 m.

Disclosed are a superhydrophobic microfiltration membrane capable of facilitating higher permeate flux without separation performance deterioration when performing a water treatment based on a membrane distillation method, a filtration module for membrane distillation comprising the same, and a method for manufacturing the same. The superhydrophobic microfiltration membrane of the present invention comprises a porous member having a plurality of fine pores having an average pore size of 1 m to 100 m and has a pure water contact angle of 130 or more.

The present invention relates to a polypropylene resin composition for a microporous film which can reduce the product defect rate due to stabilization of porous formation by stabilizing film formation and also can obtain a film suitably usable for a separator, a filtration membrane, a separation membrane and a filter since the microporous film can be thinned due to high rigidity, and more specifically, relates to a polypropylene resin composition for a microporous film wherein the composition comprises 5 to 30% by weight of polypropylene resin (X) having specific MFR, molecular weight distribution Mw/Mn by GPC, melt tension (MT), branching index g and mm fraction of the propylene unit triads by .sup.13C-NMR, satisfying specific conditions concerning gels and having a long chain branched structure and 95 to 70% by weight of polypropylene resin (Y) having a specific MFR and excluding the polypropylene resin (X).

An environmentally friendly closed loop manufacturing process (10.sub.1, 10.sub.2) produces microporous membranes (32) by cast or extrusion of polymer-plasticizer mixtures followed by non-porous film formation (20), extraction (22) of the plasticizer using an azeotrope solvent and thereby forming a solvent-laden sheet and a mixture of plasticizer and azeotrope solvent, distillation (28) of the mixture to separate the plasticizer and azeotrope solvent for reuse, evaporation (30) of the azeotrope solvent from the solvent-laden sheet to form the micropores, and capture of the resultant solvent vapor for subsequent adsorption-desorption of the azeotrope solvent from activated carbon (34) or by vapor condensation (36) for reuse in the manufacturing process. The azeotrope solvent is at least a two-component mixture of solvents, one of which is designed for efficient removal of the plasticizer, while the other component(s) render(s) the azeotrope solvent non-flammable.