An example porous composite membrane for solvent extraction is provided. The porous composite membrane includes a Janus membrane with a first side and a second side opposing the first side. The first side exhibits hydrophobic characteristics and the second side exhibits hydrophilic characteristics. At least one of the first side or the second side is sized to perform nondispersive membrane solvent extraction.

Compositions and methods directed to the production of single layer, highly porous, free-standing polytetrafluoroethylene (PTFE) membranes having macro-textured surfaces are provided. The macro-textured surfaces are due to the presence of macroscopic nodal aggregates within the membrane that are connected by fibrils The membranes have high porosity, high airflow, and a bulk density less than 1.0 g/cm3. Articles comprising the porous, single layer PTFE membranes are also provided.

Compositions and methods directed to the production of single layer, highly porous, free-standing polytetrafluoroethylene (PTFE) membranes having macro-textured surfaces are provided. The macro-textured surfaces are due to the presence of macroscopic nodal aggregates within the membrane that are connected by fibrils The membranes have high porosity, high airflow, and a bulk density less than 1.0 g/cm3. Articles comprising the porous, single layer PTFE membranes are also provided.

The present invention relates to new anion exchange polymers and (blend) membranes made from polymers containing highly fluorinated aromatic groups by means of nucleophilic substitution and processes for their production by means of nucleophilic aromatic substitution and their areas of application in membrane processes, in particular in electrochemical membrane processes such as fuel cells, electrolysis and redox flow batteries.

A provided stretched porous polytetrafluoroethylene membrane has a node-fibril structure including a plurality of nodes and a fibril connecting the plurality of nodes. A ratio of an average length of the plurality of nodes in a thickness direction of the stretched porous polytetrafluoroethylene membrane to a thickness of the stretched porous polytetrafluoroethylene membrane is 10% or more. The above stretched porous polytetrafluoroethylene membrane is less likely to suffer breakage. In the above stretched porous polytetrafluoroethylene membrane, assuming that there is a cuboid region having an upper surface and a lower surface respectively positioned at one membrane surface and the other membrane surface of the stretched porous polytetrafluoroethylene membrane, the number of the nodes included in the region may be 4 or less per micrometer thickness, the upper surface and the lower surface each having dimensions of 280 μm×280 μm.

A provided stretched porous polytetrafluoroethylene membrane has a node-fibril structure including a plurality of nodes and a fibril connecting the plurality of nodes. A ratio of an average length of the plurality of nodes in a thickness direction of the stretched porous polytetrafluoroethylene membrane to a thickness of the stretched porous polytetrafluoroethylene membrane is 10% or more. The above stretched porous polytetrafluoroethylene membrane is less likely to suffer breakage. In the above stretched porous polytetrafluoroethylene membrane, assuming that there is a cuboid region having an upper surface and a lower surface respectively positioned at one membrane surface and the other membrane surface of the stretched porous polytetrafluoroethylene membrane, the number of the nodes included in the region may be 4 or less per micrometer thickness, the upper surface and the lower surface each having dimensions of 280 μm×280 μm.

Provided is a porous polytetrafluoroethylene membrane in which an absolute value of a difference in lightness between one principal surface and the other principal surface is 1.0 or more, where the lightness is lightness L* of CIE 1976 (L*, a*, b*) color space specified in JIS Z8781-4: 2013. The porous polytetrafluoroethylene membrane may be colored black or gray. The porous polytetrafluoroethylene membrane provided can have properties with a reduced coloring-induced deterioration.

Provided is an internal pressure adjustment member to be attached to an outer surface of a housing, the member having high air permeability even when a differential pressure that can be generated between the inside and the outside of a housing to which the internal pressure adjustment member is attached is small, and inhibiting damage to the member and a reduction in the air permeability of the member due to coming soil and mud. The internal pressure adjustment member includes: a filter portion including a net-like or mesh-like support layer and first and second porous polytetrafluoroethylene (PTFE) membranes laminated on the support layer such that the support layer is interposed therebetween, the first porous PTFE membrane being exposed on one surface of the filter portion, the second porous PTFE membrane being exposed on another surface of the filter portion; and an adhesive portion, formed on the one surface of the filter portion, for attaching the filter portion to the outer surface of the housing. The first porous PTFE membrane and the second porous PTFE membrane each have an average pore diameter of 2.0 μm or more, the filter portion has a thickness of 140 μm or less, and the filter portion has a density of 0.60 g/cm.sup.3 or less.

Provided is an internal pressure adjustment member to be attached to an outer surface of a housing, the member having high air permeability even when a differential pressure that can be generated between the inside and the outside of a housing to which the internal pressure adjustment member is attached is small, and inhibiting damage to the member and a reduction in the air permeability of the member due to coming soil and mud. The internal pressure adjustment member includes: a filter portion including a net-like or mesh-like support layer and first and second porous polytetrafluoroethylene (PTFE) membranes laminated on the support layer such that the support layer is interposed therebetween, the first porous PTFE membrane being exposed on one surface of the filter portion, the second porous PTFE membrane being exposed on another surface of the filter portion; and an adhesive portion, formed on the one surface of the filter portion, for attaching the filter portion to the outer surface of the housing. The first porous PTFE membrane and the second porous PTFE membrane each have an average pore diameter of 2.0 μm or more, the filter portion has a thickness of 140 μm or less, and the filter portion has a density of 0.60 g/cm.sup.3 or less.

Composite polyether block amide (PEBA) copolymer tubes incorporate an ultra-thin PEBA layer that enables rapid moisture transfer and exchange through the tube. A composite PEBA film may include a porous scaffold support and may be formed or incorporated into the composite PEBA tube. A porous scaffold support may be coated or imbibed with PEBA to form a composite PEBA film. A composite PEBA film may be wrapped on a mandrel or over a porous scaffold support to form a composite PEBA tube. A film layer may be applied over a wrapped composite PEBA film to secure the layers together. The film layer by applied by dipping, spraying or painting.