B01D71/5222

CROSS-LINKED HIGH STABLE ANION EXCHANGE BLEND MEMBRANES WITH POLYETHYLENEGLYCOLS AS HYDROPHILIC MEMBRANE PHASE
20200023348 · 2020-01-23 ·

The invention relates to: anion exchange blend membranes consisting the following blend components: a halomethylated polymer (a polymer with (CH.sub.2).sub.xCH.sub.2Hal groups, Hal=F, Cl, Br, I; x=0-12), which is quaternised with a tertiary or a n-alkylated/n-arylated imidazole, an N-alkylated/N-arylated benzimidazole or an N-alkylated/N-arylated pyrazol to form an anion exchanger polymer. an inert matrix polymer in which the anion exchange polymer is embedded and which is optionally covalently crosslinked with the halomethylated precursor of the anion exchanger polymer, a polyethyleneglycol with epoxide or halomethyl terminal groups which are anchored by reacting with NH-groups of the base matrix polymer using convalent cross-linking optionally an acidic polymer which forms with the anion-exchanger polymer an ionic cross-linking (negative bound ions of the acidic polymer forming ionic cross-linking positions relative to the positive cations of the anion-exchanger polymer) optionally a sulphonated polymer (polymer with sulphate groups SO.sub.2Me, Me=any cation), which forms with the halomethyl groups of the halomethylated polymer convalent crosslinking bridges with sulfinate S-alkylation. The invention also relates to a method for producing said membranes, to the use of said membranes in electrochemical energy conversion processes (e.g. Redox-flow batteries and other flow batteries, PEM-electrolyses, membrane fuel cells), and in other membrane methods (e.g. electrodialysis, diffusion dialysis).

Ceramic proton-conducting membranes

Disclosed herein are ceramic selective membranes and methods of forming the ceramic selective membranes by forming a selective silica ceramic on a porous membrane substrate. Representative ceramic selective membranes include ion-conductive membranes (e.g., proton-conducting membranes) and gas selective membranes. Representative uses for the membranes include incorporation into fuel cells and redox flow batteries (RFB) as ion-conducting membranes.

High selectivity membranes for hydrogen sulfide and carbon dioxide removal from natural gas
11931698 · 2024-03-19 · ·

A thin film composite gas separation membrane comprising a polyether block amide copolymer coating layer and a nanoporous asymmetric support membrane with nanopores on the skin layer surface of the support membrane and gelatin polymers inside the nanopores on the skin layer surface of the support membrane. A method for making the thin film composite gas separation membrane is provided as well as the use of the membrane for a variety of separations such as separations of hydrogen sulfide and carbon dioxide from natural gas, carbon dioxide removal from flue gas, fuel gas conditioning, hydrogen/methane, polar molecules, and ammonia mixtures with methane, nitrogen or hydrogen and other light gases separations, but also for natural gas liquids recovery and hydrogen sulfide and carbon dioxide removal from natural gas in a single step.

MEMBRANE BUNDLE FOR FUEL DEOXYGENATION WITH ENHANCED DURABILITY

A method of forming a degassing system includes the step of forming a bundle of hollow tube membrane members by wrapping hollow tube membrane members to form the bundle at a temperature above 100? F. (38? C.). Another method of forming a degassing system includes the step of the inserting bundle into an outer canister at a temperature above 100? F. (38? C.). A fuel supply system made by these methods is also disclosed.

Separation membrane

The present invention provides a separation membrane that is suitable for separating an acid gas from a gas mixture containing the acid gas and has a high acid gas permeability. A separation membrane (10) of the present invention includes: a separation functional layer (1); a porous support member (3) supporting the separation functional layer (1); and an intermediate layer (2) disposed between the separation functional layer (1) and the porous support member (3), and including a matrix (4) and nanoparticles (5) dispersed in the matrix (4).

CERAMIC PROTON-CONDUCTING MEMBRANES

Disclosed herein are ceramic selective membranes and methods of forming the ceramic selective membranes by forming a selective silica ceramic on a porous membrane substrate.

Latent and sensible cooling membrane heat pump

A membrane-based assembly and process for cooling and/or de-vaporizing a gas. The assembly and process can provide sensible cooling and/or dehumidification of air, and can be contained within a single, integrated apparatus.

ION EXCHANGING MEMBRANE, METHOD FOR MANUFACTURING THE SAME AND ENERGY STORAGE SYSTEM COMPRISING THE SAME

The present invention relates to an ion exchanging membrane, a method for manufacturing the same, and an energy storage system comprising the same. The ion exchanging membrane includes a porous support including a plurality of pores, a first ion conducting material located on one surface of the porous support, and a second ion conducting material located on the other surface of the porous support, in which the first ion conducting material and the second ion conducting material are polymers including hydrophilic repeating units and hydrophobic repeating units, and the first ion conducting material and the second ion conducting material have different molar ratios of the hydrophilic repeating units and the hydrophobic repeating units.

According to the ion exchanging membrane, it is possible to improve overall efficiency of the energy storage system by improving both performance efficiency and voltage efficiency of the energy storage system due to excellent ion-conductivity performance and reduced membrane resistance and ensure durability of the energy storage system by having excellent morphological stability and reducing a crossover of vanadium ions.

Composite membranes with improved performance and/or durability and methods of use

A composite membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., first liquid such as a high octane compound) from a mixture comprising the first fluid (e.g., first liquid such as a high octane compound) and a second fluid (e.g., second liquid such as gasoline). The composite membrane includes a porous substrate comprising opposite first and second major surfaces, and a plurality of pores. A pore-filling polymer is disposed in at least some of the pores so as to form a layer having a thickness within the porous substrate. The composite membrane further includes at least one of: (a) an ionic liquid mixed with the pore-filling polymer; or (b) an amorphous fluorochemical film disposed on the composite membrane.

APPARATUS FOR ENRICHING THE CONCENTRATION OF TRACE COMPONENTS IN AIR FLOW
20240123410 · 2024-04-18 ·

Various embodiments of a system and method for enriching a concentration of components of interest in an air flow are described. The system includes an apparatus for enriching a concentration of components of interest in an air flow. The apparatus includes a chamber and a tube having a tube wall made of a selectively permeable material positioned within the chamber. A first end of the tube is connected to the inlet port of the chamber and a second end of the tube is connected to the outlet port of the chamber. The selectively permeable material has a lower permeability to components of interest than to inert gases, and the selectively permeable material is non-reactive with components of interest. The apparatus is configured to receive a sample stream and the chamber is maintained at a chamber pressure that is different than a stream pressure of the sample stream.