A method and an integrated system for reducing CO.sub.2 emissions in industrial processes. The method and integrated system (100) capture carbon dioxide (CO.sub.2) gas from a first gas stream (104) with a chemical absorbent to produce a second gas stream (106) having a higher concentration of carbon monoxide (CO) gas and a lower concentration of CO.sub.2 gas as compared to first gas stream. The CO gas in the second gas stream is used to produce C.sub.5 to C.sub.20 hydrocarbons in an exothermic reaction (108) with hydrogen (H.sub.2) gas (138). At least a portion of the heat generated in the exothermic reaction is used to regenerate the chemical absorbent with the liberation of the CO.sub.2 gas (128) captured from the first gas stream. Heat captured during the exothermic reaction can, optionally, first be used to generate electricity, wherein the heat remaining after generating electricity is used to thermally regenerate the chemical absorbent.

The embodiments provide an acidic gas absorbent, an acidic gas removal method, and an acidic gas removal apparatus. The absorbent absorbs an acidic gas in a large amount and hardly diffuses in air. The acidic gas absorbent according to the embodiment comprises an amine compound having a sulfonyl group and two or more amino groups.

The embodiments provide an acidic gas absorbent having low diffusibility, an acidic gas removal method, and an acidic gas removal apparatus. The acidic gas absorbent according to the embodiment comprises: an amine compound having a vapor pressure of 0.001 to 10 Pa at 20 C.; a water-soluble polymer compound having a mass-average molecular weight of 900 to 200000 and not containing a functional group having a pKa value greater than 7 except for hydroxy; and water.

The present invention is related to a method for determination of unit operations of a chemical plant for acid gas removal, the method carried out by a computer or a distributed computer system and the method comprising the steps of: providing a first set of parameters for the unit operations; providing a second set of parameters for the unit operations based on the provided first set of parameters and based on data retrieved from a database; determining a digital model of the chemical plant based on the first set of parameters and the second set of parameters, wherein the digital model comprises a system of equations defining the unit operations of the chemical plant; selecting starting points for an equation-based solution method of the system of equations, wherein the starting points are at least partially selected from the: (i) the first set of parameters; (ii) the second set of parameters; and (iii) the data retrieved from the database; determining resultant settings for the unit operations of the chemical plant using the equation-based solution method for the system of equations initialized by the selected starting points.

The present invention relates to methods for improving carbon capture by providing particles within an amine solvent. The particles provide for increased turbulence at the interface between the counter-flowing gas and solvent, which allows for increased amine and carbamate salt diffusion between the liquid film and bulk.

An improved process for deacidizing a gaseous mixture with reduced overall energy costs is described. The process involves contacting the gaseous mixture with at least one of a vaporizing compound, a vaporized compound, a vaporizing solution of compound and a vaporized solution of compound, and forming a liquid or solid reaction product that can be easily separated from the gaseous mixture.

The invention relates to a process for removing hydrogen sulfide and carbon dioxide from a feed gas stream. H2S in the feed gas stream is converted to elemental sulfur in a Claus unit. At least a part of the gas stream obtained is contacted with an aqueous lean absorbing medium in an absorption zone at a pressure between 0.9 and 2 bara. The aqueous lean absorbing medium used comprises one or more amines chosen from: a polyamine in the absence of tertiary amine functionalities having a pKa sufficient to neutralize carbamic acid, the polyamine having at least one primary amine functionality having a pKa smaller than 10.0 at 25 C., a polyamine in the absence of tertiary amine functionalities having a pKa sufficient to neutralize carbamic acid, the polyamine having at least one secondary amine functionality having a pKa for each sorbing nitrogen smaller than 10.0 at 25 C. The process is improved as compared to a process involving Claus off-gas treatment with (activated) MDEA. Effective CO2 removal is achieved while at the same time a simplified line-up with less equipment can be used.

The embodiments provide an acidic gas absorbent, an acidic gas removal method using the absorbent, and an acidic gas removal apparatus using the absorbent. The absorbent absorbs an acidic gas in a large amount and is hardly diffused. The acidic gas absorbent according to the embodiment comprises an amine compound represented by the following formula (1):

##STR00001##

[In the formula, each R.sup.1 is independently hydrogen, an alkyl group, or a primary or secondary amino-containing aminoalkyl group provided that at least one of R.sup.1s is the aminoalkyl group, each R.sup.2 is independently hydrogen, an alkyl group, hydroxy, amino, hydroxyamino, or a primary or secondary amino-containing aminoalkyl group, the alkyl or aminoalkyl group contained in R.sup.1 or R.sup.2 has a straight-chain or branched-chain skeleton and may be substituted with hydroxy or carbonyl, and p is 2 to 4.]

The invention relates to a regeneration system for a carbon-rich amine solution produced in carbon dioxide capture from a mixed gas and a method for using the same. This regeneration system is composed of a bipolar membrane electrodialysis apparatus and a carbon dioxide removal apparatus, wherein the bipolar membrane electrodialysis apparatus is composed of a bipolar membrane electrodialysis membrane stack fixed between an anode plate and a cathode plate, the carbon dioxide removal apparatus is composed of one or more hollow fiber membrane contactors, the inlet of the carbon dioxide removal apparatus is fluidly connected with the outlet of the acid chamber of the bipolar membrane electrodialysis apparatus, the outlet of the carbon dioxide removal apparatus is fluidly connected with the acid solution storage tank, and carbon dioxide gas removed by the carbon dioxide removal apparatus is collected in a carbon dioxide storage tank. In the invention, by treating a carbon-rich amine solution having heat stable salts with a combined apparatus of bipolar membrane electrodialysis and carbon dioxide removal, individual operation for conventional heat stripping and organic amine regeneration is avoided, the energy consumption of carbon capture is reduced, the process flow is simplified, and the overall net capture efficiency of carbon dioxide is improved.

A carbon dioxide absorbent composition is disclosed. Based on 100 parts by weight of the carbon dioxide absorbent composition, the carbon dioxide absorbent composition includes 5 to 45 parts by weight of sodium 2-[(2-aminoethyl)amino]ethanesulfonate. Moreover, a method for capturing carbon dioxide using the carbon dioxide absorbent composition is disclosed.