A method for the continuous production of ozone and recovery of oxygen in a purge cycle adsorption process having four adsorbent beds. The method has the steps of feeding a mixture of ozone and oxygen to a first and second adsorbent bed wherein the first and the second adsorbent bed adsorb ozone and allow oxygen to pass through; recovering the oxygen from the first bed; feeding the oxygen from the second bed to a fourth adsorbent bed, wherein ozone is desorbed from the fourth bed; feeding clean dry air through a valve to the third adsorbent bed, and measuring the flow rate of the clean dry air through the valve, comparing this flow rate to a pre-calculated value and adjusting the flow rate of the clean dry air to equal the pre-calculated value; desorbing ozone from the third bed; and recovering ozone from the third bed and the fourth bed.

Methods and systems for continuous pressure swing adsorption separation of a pressurized feed gas stream, the method including separating hydrocarbons heavier than methane from the pressurized feed gas stream to produce at least two product streams, a first product stream being substantially pure methane, and a second product stream being substantially comprised of components with a greater molecular weight than methane.

According to an exemplary embodiment of the present invention, a pressure swing adsorption process of a hydrogen production system is provided.

The hydrogen production system comprises a desulfurization process for removing sulfur components from raw natural gas; a reforming reaction process for producing a reformed gas containing hydrogen generated by the reaction of natural gas through the desulfurization process and steam; and a pressure swing adsorption process of concentrating the hydrogen using a pressure swing adsorption from the reformed gas.

In a desorption step of the pressure swing adsorption process, a cocurrent depressurization and a countercurrent depressurization are simultaneously performed.

Methods and systems for continuous pressure swing adsorption separation of a pressurized feed gas stream, the method including separating hydrocarbons heavier than methane from the pressurized feed gas stream to produce at least two product streams, a first product stream being substantially pure methane, and a second product stream being substantially comprised of components with a greater molecular weight than methane.

A temperature swing adsorption (TSA) process for removing a target component from a gaseous mixture (111), said process being carried out in a plurality of reactors (101, 102, 103), wherein each reactor (101) performs the following steps: an adsorption step (a) wherein an input stream (111) of said gaseous mixture is contacted with a solid adsorbent selective for said target component, producing a first waste stream (112) depleted of the target component; a heating step (b) for regeneration of the loaded adsorbent providing a first output stream (115) containing the target component; a cooling step (c) of the regenerated adsorbent, said TSA process also comprising: i) a pre-cooling step (b1) before said cooling step (c), wherein the regenerated adsorbent is contacted with a waste stream (137) which is produced by the adsorption step (a) of another reactor (103) and a second output stream (116) of the target component is produced; ii) a pre-heating step (a1) after said adsorption step (a) and before said heating step (b), wherein the loaded adsorbent is contacted with a rinse stream (126) which is produced by the pre-cooling step of another reactor (102).

A staged complementary pressure swing adsorption system and method for low energy fractionation of a mixed fluid. Two beds in a four-column PSA system are selective for component A, and another two columns are selective for component B. The cycle creates an intermittent A and B product, using the purge effluent from the complementary product fed at an intermediate pressure. This intermittent product is used as purge gas for low-pressure purged elsewhere in the cycle using appropriate storage tanks. The use of an intermediate pressure in this cycle enables continuous production of purified component A and B without the use of compressors. Columns may also be configured to enable pressure to equalize between complementary columns.

In a cyclic adsorptive gas purification process, an impurity laden adsorbent is regenerated by exposing it first to an unheated gas for a pre-determined time period to desorb at least some of the impurity, followed by heating the adsorbent using a flowing stream of a heated gas to desorb the remaining impurities over another pre-determined time period, further followed by cooling of the adsorbent using a flowing stream of gas for yet another pre-determined time period to make it ready for repeating the adsorptive cycle. Introducing an unheated purge stream reduces the energy requirements for the regeneration step compared to a traditional TSA process.

We provide a method for removing contaminants from a gas, comprising: alternating input of the gas between two or more beds of adsorbent particles that comprise zeolite SSZ-36, zeolite SSZ-39, or zeolite SSZ-45; wherein the gas contacts one of the beds during an adsorption and a tail gas is simultaneously vented from another of the beds by desorption; wherein a contacting pressure is from about 345 kPa to about 6895 kPa and produces a product gas containing no greater than about 2 mol % carbon dioxide, at least about 10 wppm water, at least about 65 mol % of methane recovered from the feed gas, and at least about 25 mol % of ethane recovered from the feed gas; and wherein the tail gas is vented from the feed end of the beds. We also provide a method for removing a contaminant from a gas, wherein the gas contains hydrogen sulfide.

We provide a method for removing contaminants from a gas, comprising: alternating input of the gas between two or more beds of adsorbent particles that comprise zeolite SSZ-36, zeolite SSZ-39, or zeolite SSZ-45; wherein the gas contacts one of the beds during an adsorption and a tail gas is simultaneously vented from another of the beds by desorption; wherein a contacting pressure is from about 345 kPa to about 6895 kPa and produces a product gas containing no greater than about 2 mol % carbon dioxide, at least about 10 wppm water, at least about 65 mol % of methane recovered from the feed gas, and at least about 25 mol % of ethane recovered from the feed gas; and wherein the tail gas is vented from the feed end of the beds. We also provide a method for removing a contaminant from a gas, wherein the gas contains hydrogen sulfide.

A method for controlling gas separation of a gas mixture comprising a first component and a second component, the method comprising contacting a feed containing the gas mixture with an adsorbent in a bed in a column in a dual reflux swing adsorption process such that a first component of a gas mixture attains or exceeds a desired purity and a second component of the gas mixture attains or exceeds a desired purity, wherein the mathematical product of the cycle feed time and the sum of the molar feed flow rate and the molar reflux flow rate directed to the column does not exceed the maximum number of moles that can be treated per bed per cycle and wherein the ratio of the first product flow rate to the feed flow rate is less than or equal to the first component's fraction of the feed, and the ratio of the second product flow rate to the feed flow rate is less than or equal to the second component's fraction of the feed.