A three-product PSA system which produces three product streams from a feed gas mixture comprising a light key component, at least one heavy key component, and at least one intermediate key component is described. The three-product PSA system produces a high pressure product stream enriched in the light key component, a low pressure tail gas stream enriched in the at least one heavy key component, and an intermediate pressure vent gas stream enriched in the at least one intermediate key component.

In various aspects, methods are provided for hydrogen production while reducing and/or mitigating emissions during various refinery processes that produce syngas, such as power generation. Syngas can be effectively separated to generate high purity carbon dioxide and hydrogen streams, while reducing and/or minimizing the energy required for the separation, and without needing to reduce the temperature of the flue gas. In various aspects, the operating conditions, such as high temperature, mixed metal oxide adsorbents, and cycle variations, for a pressure swing adsorption reactor can be selected to minimize energy penalties while still effectively capturing the CO.sub.2 present in syngas.

A process and apparatus for separating components of a source gas is provided in which more soluble components of the source gas are dissolved in an aqueous solvent at high pressure. The system can utilize hydrostatic pressure to increase solubility of the components of the source gas. The apparatus includes gas recycle throughout multiple mass transfer stages to improve mass transfer of the targeted components from the liquid to gas phase. Separated components can be recovered for use in a value added application or can be processed for long-term storage, for instance in an underwater reservoir.

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve performing dampening for fluctuations in the streams conducted away from the adsorbent bed unit. The process may be utilized for swing adsorption processes, such as rapid cycle TSA and/or rapid cycle PSA, which are utilized to remove one or more contaminants from a gaseous feed stream.

A pressure swing adsorption (PSA) system and a PSA process including a PSA cycle schedule are disclosed. The PSA cycle schedule includes an unlimited number of equalization steps, no idle steps, no dead time and a minimum number of three PSA adsorbent beds assisted with two or more equalization tanks. The PSA system, process and cycle schedule include the following sequence of cycle steps: a feed step, two or more down equalization steps either between beds or between a bed and a tank, an optional forced cocurrent depressurization step coupled with a forced intermediary light end pressurization step, a countercurrent depressurization step, a light reflux step, two or more up equalization steps between beds or between a bed and a tank, an optional forced intermediary light end pressurization step coupled with the forced cocurrent depressurization step, and a light product pressurization step.

Processes and apparatuses for reducing molecular weight fluctuation in a tail gas stream from a pressure swing adsorption process. Multiple PSA separation zone are synchronized such that when one of the PSA units is generating a low molecular weight tail gas, there is another PSA unit generating a high molecular weight tail gas.

The invention relates to a method for regulating a unit for separating a gas stream, having P adsorbers, where P2, each following a PSA-type adsorption cycle with a phase time shift, the method involving the steps of operating the unit according to the nominal cycle when the required flow rate is equal to a nominal flow rate or optionally when the required flow rate is higher than the nominal flow rate, and operating the unit according to the reduced cycle when the required flow rate is lower than or equal to a predetermined flow rate, the predetermined flow rate being lower than the nominal flow rate.