A process is presented for the purification of an olefins feed stream to a benzene alkylation unit. The process removes heavy aromatics in a two adsorbent unit system. The unit passes the olefins feed stream to a first adsorbent unit, while the second adsorbent unit is either in regeneration mode, or standby mode. The process switches the feed stream to the second adsorbent unit and displaces the fluid in the second adsorbent unit, while maintaining the flow of the purified feed stream to the benzene alkylation unit.

A heat and mass exchanger system comprising: a first array of tubes, each of said tubes having an coating of a desiccant about a peripheral surface; an interstitial space between said tubes, said interstitial space arranged to receive a fluid, such that at least a portion of the peripheral surface is a wetted area of said fluid; said tubes arranged to transport a heat transfer liquid within an internal bore, said fluid and heat transfer liquid in heat transfer communication; wherein the cross sectional shape of each of said tubes is convex.

In accordance with exemplary inventive practice, a catalytic system and a temperature swing adsorption system are thermally integrated. The temperature range of the adsorption system is lower than the catalyst operating temperature. Benefits of inventive practice include reduction of total energy consumption and of generated waste-heat. Total energy consumption is reduced by transferring some of the waste-heat generated by the catalytic system into the adsorption system during the sorbent heat-up portion of the sorbent regeneration cycle. The heat is transferred using a thermal reservoir, which accumulates heat from the catalytic apparatus and transfers it to the adsorption apparatus at a later time, and which is repeatedly cycled as the sorbent is cycled. The catalytic system and the adsorption system can be inventively integrated in various ways to reduce the total energy consumed, and/or to modify the sorbent regeneration temperature profile, and/or to obtain an optimum power load profile.

In an example, a method of butadiene sequestration includes receiving an input stream that includes butadiene. The method includes directing the input stream to a first sulfur dioxide charged zeolite bed for butadiene sequestration via a first chemical reaction of butadiene and sulfur dioxide to form sulfolene.

Processes for regenerating adsorbent in a nitrile removal zone. The regenerant comprises a stream of hot liquid that may comprise a portion of the oligomerized effluent or a portion of a hydrotreated effluent. A spent regenerant comprising the desorbed nitriles may be processed along with the oligomerized effluent with existing separation equipment.

A process is presented for the purification of an olefins feed stream to a benzene alkylation unit. The process removes heavy aromatics in a two adsorbent unit system. The unit passes the olefins feed stream to a first adsorbent unit, while the second adsorbent unit is either in regeneration mode, or standby mode. The process switches the feed stream to the second adsorbent unit and displaces the fluid in the second adsorbent unit, while maintaining the flow of the purified feed stream to the benzene alkylation unit.

A honeycomb rotor recovering and concentrating apparatus recovers a gas such as carbon dioxide from flue gases and the like and may be capable of utilizing low-temperature waste heat 100 C. or less. The proposed method involves sorbing carbon dioxide while vaporizing and cooling by contacting a water-insoluble carbon dioxide sorbing material (solid amines, etc.) having an acidic gas sorptive capacity with a mixed gas containing carbon dioxide in a wet state. Warm water is brought into contact with the water-insoluble carbon dioxide sorbing material sorbed with carbon dioxide to desorb high concentration of carbon dioxide. The warm water is separated from the water-insoluble carbon dioxide sorbent material desorbed from carbon dioxide. Then the apparatus is returned from the separation step to the sorption step. Thereby, it is possible to drastically increase the recovery rate and recovery concentration of acidic gas (carbon dioxide) continuously.

In an example, a method of butadiene sequestration includes receiving an input stream that includes butadiene. The method includes directing the input stream to a first sulfur dioxide charged zeolite bed for butadiene sequestration via a first chemical reaction of butadiene and sulfur dioxide to form sulfolene.

The present disclosure provides a multiple-compression system and a process for capturing carbon dioxide (CO.sub.2) from a flue gas stream containing CO.sub.2. The disclosure also provides a process for regeneration of the carbon dioxide capture media.

In an example, a method of butadiene sequestration includes receiving an input stream that includes butadiene. The method includes directing the input stream to a first sulfur dioxide charged zeolite bed for butadiene sequestration via a first chemical reaction of butadiene and sulfur dioxide to form sulfolene.