Provided is an interfacial polymerization process for preparation of a highly permeable thin film composite membrane, which can be used for nanofiltration, forward osmosis, or reverse osmosis, particularly for use with brackish water or seawater. The process includes contacting a porous support membrane with an aqueous phase containing a polyamine to form a coated support membrane, and applying an organic phase containing a polyfunctional acid halide to the coated support membrane to interfacially polymerize the polyamine and the polyfunctional acid halide to form a discrimination layer of a thin film composite membrane, where the aqueous and/or organic phases include a flux-enhancing additive and a boron rejection-enhancing additive that includes a biguanide compound, dicarbonate compound, pentathiodicarbonate compound, or salts thereof. Also provided are the membranes prepared by the methods and reverse osmosis modules containing the membranes.

A method for making a graphene oxide membrane and a resulting free-standing graphene oxide membrane that provides desired qualities of water permeability and selectivity at larger sizes, thinner cross sections, and with increased ruggedness as compared to existing membranes and processes.

The present invention relates to an anti-fouling, semi-permeable membrane comprising a porous support layer, a thin film composite (TFC) layer formed on a surface of the support layer, and a cross-linked polyvinyl alcohol (PVA) layer formed on top of the TFC layer, wherein the cross-linked PVA layer is the reaction product of PVA and a cross-linking agent, said cross-linking agent being a polybasic acid comprising three or more acid groups or precursors thereof. The obtained membrane shows a high water flux and a low roughness suitable for an effective membrane notable for feed solution having a tendency of fouling the membrane.

Embodiments described herein relate generally to graphene oxide membranes for fluid filtration and more specifically to graphene oxide membranes having tunable permeability, rejection rate, and flux. Some embodiments of the graphene oxide membranes disclosed herein are characterized as having a flux of at least about 2.510.sup.4 gallons per square foot per day per psi with a 1 wt % lactose solution at room temperature, and a lactose rejection rate of at least 50% with a 1 wt % lactose solution.

Filtration apparatus including Graphene Oxide (GO) are described herein. The GO membranes include a plurality of graphene oxide sheets, each of the graphene oxide sheets covalently bound to a chemical spacer. The filtration apparatus can include a GO membrane and a sulfonated polyethersulfone (S-PES). The filtration apparatus can exhibit improved performance with respect to prior art membranes (e.g., high flux and rejection rate) in applications such as pulp and paper processing, which facilitates achieving permeate quality targets. The filtration apparatus described herein can also offer a more stable replacement for reverse osmosis membranes which are known to degrade under strongly alkaline conditions and high temperatures.

The present invention relates to laminate membranes for filtration of solutes. The membranes comprise graphene oxide and polyvinyl amine. The invention also relates to methods of reducing the amount of solutes in a mixture using said membranes, methods of making said membranes, and uses of said membranes.

Ion exchange membranes obtainable by curing a composition comprising: (a) a monomer comprising an aromatic group and at least one polymerisable ethylenically unsaturated group; (b) a photoinitiator which has an absorption maximum at a wavelength longer than 380 nm when measured in one or more of the following solvents at a temperature of 23 C.: water, ethanol and toluene; and (c) at least one co-initiator.