The present disclosure is directed to a low temperature method of preparing graphene. The method comprises applying a graphene oxide to a substrate and treating the graphene oxide on the substrate using photoreduction to reduce and stitch the graphene oxide to graphene. The present disclosure is also directed to graphene produced according to the aforementioned method.

Embodiments described herein relate generally to continuous flow photoreactors with easily replaceable and adjustable components. The photoreactor includes a reactor flow system, a lighting system, and a temperature control system. The reactor flow system includes a reactor inlet port, a reactor outlet port, and a length of reactor tubing fluidically coupled to the reactor inlet port and reactor outlet port. The lighting system includes a light emitting apparatus (e.g., a plurality of LEDs) configured to emit light in a defined wavelength range toward the length of reactor tubing. The temperature control system includes an inlet port, an outlet port, and a length of temperature control tubing fluidically coupled to the inlet port and the outlet port. In some embodiments, the temperature control system can be configured to circulate a fluid to cool the lighting system.

An anti-bacterial lighting device includes a translucent housing, a first light source, a second light source, an air-inflow port, and an air circulation mechanism. The translucent housing is air-permeable and coated with an anti-bacterial photocatalyst on its surface. The first light source is a visible light source emitting a visible light with a spectral power distribution (SPD)>95% in a visible light wavelength range (>400 nm). The second light source is a far-UVC light source emitting a non-visible light with an SPD>90% in a 200 nm230 nm wavelength range. The lights of the first light source and the second light source shine through the translucent housing and activates the anti-bacterial photocatalyst on the housing. The air circulation mechanism sucks an ambient air into the housing through the air-inflow port and forces the air out through the air-permeable housing.

The invention consists of an assembly of a light (e.g., UV, visible, IR) source, a reaction vial holder and a photochemistry device that allows for conducting arrays of photochemical reaction conditions at room temperature with magnetic stirring. The photochemistry assembly is compatible with multiple reaction vial size holder.

A method of forming three-dimensional shaped microparticles in a microfluidic device includes flowing a mixture of a monomer and photoinitiator in a microfluidic channel having a plurality of pillars disposed therein to define a flow stream having a pre-defined shape and temporarily stopping the same. One or more portions of the flow stream are polymerized by passing polymerizing light through one or more masks and onto the flow stream, the polymerization process forming a plurality of three-dimensional shaped microparticles. The three-dimensional shape of the microparticle may be geometrically complex by using non-rectangular 2D orthogonal shapes for the flow and/or masked light source. The microparticles may include protected regions on which cells can be adhered to and protected from shear forces. The flow stream is restarted to flush out the newly formed microparticles and prepare the device for the next cycle of particle formation.

A multicomponent photocatalyst includes a reactive component optically, electronically, or thermally coupled to a plasmonic material. A method of performing a catalytic reaction includes loading a multicomponent photocatalyst including a reactive component optically, electronically, or thermally coupled to a plasmonic material into a reaction chamber; introducing molecular reactants into the reaction chamber; and illuminating the reaction chamber with a light source.

Apparatus for facilitating a chemical reaction through the application of light, including a light source providing illumination at a selected wavelength, a lens material adapted to be in physical contact with the light source, when in use, and a receptacle for holding a reaction vial in which the chemical reaction takes place, the receptacle adapted to position a portion of the reaction vial in physical contact with the lens material when in use, wherein the lens material has a refractive index that facilitates the transmission of the illumination from the light source to the reaction vial. Alternatively, the receptacle and vial may be replaced by a reaction plate in which reaction wells are formed.

Disclosed is a method of irradiating a composition having water and hydrogen-terminated nanodiamonds with light that generates water-solvated electrons from the nanodiamonds. The method can be used to degrade fluoroalkyl compounds such as perfluorooctane sulfonate.

A visibly transparent, homogeneous UV-blocking cellulose nanocrystal/lignin nanocomposite film and a method of making the same. The film is made by dispersing cellulose nanocrystals and lignin in an aqueous, alkaline solution to yield a dispersion; casting the dispersion onto a substrate; and evaporating the aqueous, alkaline solution to yield a homogeneous, visibly transparent film that at least partially absorbs ultraviolet (UV) radiation.

Methods, systems, and apparatuses for producing one or more of photon enhanced oxidizing agents, trioxygen, hydrogen and its ions, oxygen and its ions, ROS and electronically modified oxygen derivatives from oxidizing agents that are exposed to photon emissions at a wavelength in a range of 0.01 nm to 845 nm, wherein wavelengths that photo-dissociate trioxygen may be excluded. The methods, systems and apparatuses enhance the effectiveness of photo-oxidation, photocatalytic, and/or photochemical reactions or a combination of these reactions.