The present invention relates to a method for producing chlorinated polyvinyl chloride resin in which polyvinyl chloride resin is chlorinated by radiating ultraviolet light in a reactor into which polyvinyl chloride resin and chlorine have been introduced, wherein the radiation of the ultraviolet light is performed by using at least one light source selected from the group consisting of an ultraviolet LED, an organic EL and an inorganic EL, the light source is disposed within the reactor, at least one radiation direction of the ultraviolet light is within a range of 30 or more and 115 or less with respect to a stirring direction of polyvinyl chloride resin, and an amount of ultraviolet light radiated within the range of 30 or more and 115 or less with respect to the stirring direction of polyvinyl chloride resin is 24% or more based on a total amount of ultraviolet light radiated from the light source taken as 100%.

The invention discloses a continuous process for producing high-pure quadricyclane, in which a reaction-rectification integral process or a reaction followed by rectification process may be employed. The two processes both use a novel composite catalyst which is obtained by loading an organic photo-sensitizer on a solid photocatalyst, and the composite catalyst has a high activity and a good stability. In the reaction-rectification integral process, the composite catalyst is used by being blended with rectification fillers or covering the rectification fillers, so as to achieve the integration of the reaction and the rectification. In the reaction followed by rectification process, the composite catalyst and the rectification fillers are placed separately from each other. The two processes achieve a relatively short residence time of reactants, produce highly-pure quadricyclane, and reduce the formation of cokes.

Compositions comprising branched C.sub.10 mercaptans selected from the group consisting of 5-methyl-1-mercapto-nonane, 3-propyl-1-mercapto-heptane, 4-ethyl-1-mercapto-octane, 2-butyl-1-mercapto-hexane, 5-methyl-2-mercapto-nonane, 3-propyl-2-mercapto-heptane, 4-ethyl-2-mercapto-octane, 5-methyl-5-mercapto-nonane, and combinations thereof.

The present invention relates to methods and devices for providing microbial control and/or disinfection/remediation of an environment. The methods generally comprise generating a Purified Hydrogen Peroxide Gas (PHPG) that is substantially free of, e.g., hydration, ozone, plasma species, and/or organic species; and directing the gas comprising primarily PHPG into the environment such that the PHPG acts to provide microbial control and/or disinfection/remediation in the environment, preferably both on surfaces and in the air.

A hybrid slurry reactor for performing photocatalytic reactions is provided. The hybrid slurry reactor includes a photoreactor, including a conduit, having a transparent portion, a light-emitting diode (LED) array disposed within the conduit; wherein the conduit is configured such that photons from an external source enter the conduit through the transparent portion and the LED array is directed to emit photons into the conduit.

A system and process for recycling machining waste into a solid/scrap material component and a recyclable machining coolant. The system and process comprise collecting the waste machining waste and mechanically separating the machining waste into a solid/scrap material component and a machining waste liquid component. The machining waste liquid component is decanted to separate oils and solids from the recyclable machining coolant. The machine recyclable machining coolant is then filtered through at least a first filter and preferably a second, finer mesh filter. The recyclable machining coolant is then exposed to UV light to kill bacteria and microorganisms. Lastly, ultrapure water is added to dilute the recyclable machining coolant and form the recycled machining coolant. If desired, a virgin machining coolant can be added to the recycled machining coolant, to replenish any additive(s) stripped during the recycling process, prior to resale of the recycled machining coolant.

Compositions comprising branched C.sub.10 mercaptans selected from the group consisting of 5-methyl-1-mercapto-nonane, 3-propyl-1-mercapto-heptane, 4-ethyl-1-mercapto-octane, 2-butyl-1-mercapto-hexane, 5-methyl-2-mercapto-nonane, 3-propyl-2-mercapto-heptane, 4-ethyl-2-mercapto-octane, 5-methyl-5-mercapto-nonane, and combinations thereof. Compositions comprising C.sub.11+ mercaptans, wherein the C.sub.11+ mercaptans are characterized by structure R.sup.6SH, wherein R.sup.6 is an alkyl group derived from one or more C.sub.11+ monoolefins, and wherein the one or more C.sub.11+ monoolefins comprise C.sub.11 internal monoolefins, C.sub.12 internal monoolefins, C.sub.13 internal monoolefins, C.sub.14 internal monoolefins, 1-tetradecene, 1-hexadecene, or combinations thereof. Compositions comprising branched C.sub.10+ mercaptans, wherein the branched C.sub.10+ mercaptans are characterized by structure R.sup.14SH, wherein R.sup.14 is an alkyl group derived from one or more branched C.sub.10 to C.sub.30 monoolefins.

A method of determining degradation of a thermoplastic when exposed to light and heat includes illuminating the thermoplastic with a desired wavelength of light at a desired irradiance while maintaining the ambient air surrounding the thermoplastic at a desired temperature. The method is useful to measure the discoloration rate of transparent, translucent and opaque thermoplastics such as polycarbonates, the discoloration rate being determined by transmission or reflectance spectra of transmitted or reflected white light through or from the thermoplastic.

A flow reactor for photochemical reactions comprises an extended flow passage (20) surrounded by one or more flow passage walls (22), the flow passage having a length and a light diffusing rod (30) having a diameter of at least 500 m and a length, with at least a portion of the length of the rod (30) extending inside of and along the flow passage (20) for at least a portion of the length of the flow passage (20).

The present invention discloses processes for producing a thiol compound or a sulfide compound from an olefin compound. Diphenylamine or a phenol compound can be used to increase the rate of conversion of the olefin compound to the thiol compound or the sulfide compound.