Provided is a method of producing graphene directly from a non-intercalated and non-oxidized graphitic material, comprising: (a) dispersing the graphitic material in a liquid solution to form a suspension, wherein the graphitic material has never been previously exposed to chemical intercalation or oxidation; and (b) subjecting the suspension to microwave or radio frequency irradiation with a frequency and an intensity for a length of time sufficient for producing graphene; wherein the liquid solution contains a metal salt dissolved in water, organic solvent, ionic liquid solvent, or a combination thereof. The method is fast (minutes as opposed to hours or days of conventional processes), environmentally benign, and highly scalable.

A microwave device includes a microwave generator generating a microwave and outputting the microwave, a waveguide guiding the microwave output from the microwave generator, a cavity resonator, and a flow tube. In some embodiments, the cavity resonator has an irradiation chamber as a quadrangular prism cavity into which the microwave guided by the waveguide is introduced, resonates the microwave in the irradiation chamber, and generates an electric field in TM110 mode along a direction of a center axis through centers of top and bottom faces of the irradiation chamber. The flow tube is installed in the irradiation chamber and formed in a helical fashion by winding and extending around the center axis, and causes a liquid to be treated to flow in a direction crossing the electric field generated in the irradiation chamber. The center axis is a location where the electric field is the strongest in the irradiation chamber.

This invention provides an innovative method to manufacture graphene layers or quantities and graphene oxide layers or quantities from graphite, coal slags, asphalt, and other carbon-rich sold materials in nature. The present invention uses controllable microwave irradiation to heat the mixtures of basic material, graphite, or coal slags, or asphalt, or their combinations with ionic liquids and surfactant plus environmentally friendly oxidation agents. This invention can generate the said-products of graphene layers and graphene oxides in a short time period of one second to 300 seconds. The present invention does not involve any concentrated sulfuric acid, nitric acid, nor huge water quantities needed for the purification, unlike the prior art. The as-produced graphene-based materials can be used for preparing conductive films for touch screens, producing graphene carbon fibers and three-dimensional porous graphene nanomaterials, and preparing graphene-based other intelligent nanocomposites for super-light-weight machines and vehicles.

Systems and methods for plasma based synthesis of graphitic materials. The system includes a plasma forming zone configured to generate a plasma from radio-frequency radiation, an interface element configured to transmit the plasma from the plasma forming zone to a reaction zone, and the reaction zone configured to receive the plasma. The reaction zone is further configured to receive feedstock material comprising a carbon containing species, and convert the feedstock material to a product comprising the graphitic materials in presence of the plasma.

According to an aspect of the disclosure, there is provided a microwave reactor including a container for storing a bath fluid, a tube including an inlet at one end through which a target fluid is introduced, an outlet at another end through which the target fluid is discharged, wherein at least a portion of the tube is submerged in the bath fluid, and at least one radiator located outside the container and configured to irradiate microwaves into the container.

A device and a process for producing undecylenic acid methyl ester using methyl ricinoleate as raw material are provided. The device comprises a feed pump, a raw material pre-heater, a microwave catalytic reactor, a microwave generator, a temperature controller and an infrared sensor, a condenser, a product tank and a discharge pump. The feed pump is connected with the raw material pre-heater, which is connected with the inlet of the microwave catalytic reactor. The outlet of the microwave catalytic reactor is connected with the condenser, which is connected to the product tank and the discharge pump. The microwave catalytic reactor is located in the microwave generator, which is connected with the temperature controller and the infrared sensor. The process is as follows: high-purity methyl ricinoleate, used as the raw material, is converted to methyl undecene and heptaldehyde by microwave-assisted pyrolysis process, followed by isolation and purification to produce methyl undecene.

A method for detecting an influence of microwaves on a measurement value of a temperature sensor of a core temperature probe of a cooking appliance, includes: recording the measurement value of the temperature sensor; determining the slope of the course of the recorded measurement values in at least one analysis interval (A, B) which is in a predetermined relation to a switch-on time and/or a switch-off time of a microwave generator; determining whether the slope lies above or below a predefined threshold; interpreting the exceedance of or falling below the threshold to the effect that the corresponding temperature sensor is not located in a food to be cooked and/or the core temperature probe is not correctly inserted into the food or into a receptacle provided for the same.

An instrument and method for high pressure microwave assisted chemistry are disclosed. The method includes the steps of applying microwave radiation to a sample in a sealed vessel while measuring the temperature of the sample and measuring the pressure generated inside the vessel and until the measured pressure reaches a designated set point, opening the vessel to release gases until the pressure inside the vessel reaches a lower designated set point, closing the vessel, and repeating the steps of opening the vessel at designated pressure set points and closing the vessel at designated pressure set points to the sample until the sample reaction reaches a designated high temperature. The designated set points can controllably differ from one another as the reaction proceeds. Microwave energy can be applied continuously or intermittently during the opening and closing steps. The apparatus includes a microwave cavity, a microwave transparent pressure resistant reaction vessel in the cavity, a cap on the reaction vessel, a pressure sensor for measuring pressure in the vessel, a temperature sensor, and means for opening and closing the cap at predetermined pressure set points measured by the pressure sensor to release pressure from the vessel.

A vessel system for high-pressure reactions is disclosed. The system includes a plugged polymer cylinder reaction vessel with a pressure vent opening extending radially through the wall of the reaction vessel and a supporting frame into which the vessel is received. Complementing keying structure elements on the vessel and on the frame limit the orientation of the reaction vessel in the supporting frame and the radially extending vent opening to a defined single position.

The present invention is directed in a first aspect to a process for forming a deep eutectic solvent chemical precursor. The process includes the steps of providing one or more metal ion donors, preferably one or more salts; providing one or more hydrogen bond donors, and combining the one or more salts with the one or more hydrogen bond donors. The present invention is directed in a second aspect to forming one or more metal oxides by reacting one or more of the deep eutectic solvents of the first aspect of the invention through the application of heat via methods such as flame spray pyrolysis or the application of microwaves.