A Pd—Ru alloy catalyst for hydrogen production and its preparation methods are provided. The catalyst can include a plurality of particles comprising an alloy of at least palladium (Pd) and ruthenium (Ru). Moreover, the catalyst can further include a support material such as carbon support having external or internal surfaces on which the plurality of particles is dispersed. The alloy catalyst can have a molar ratio of Pd:Ru in a range of about 0.5:1 to about 9:1. For hydrogen evolution reaction (HER), the Pd—Ru alloy catalyst exhibits increased catalytic activities comparing to some well-known catalysts.

A method of synthesizing a doped carbonaceous material includes mixing a carbon precursor material with at least one dopant to form a homogeneous/heterogeneous mixture; and subjecting the mixture to pyrolysis in an inert atmosphere to obtain the doped carbonaceous material. A method of purifying water includes providing an amount of the doped carbonaceous material in the water as a photocatalyst; and illuminating the water containing the doped carbonaceous material with visible light such that under visible light illumination, the doped carbonaceous material generates excitons (electron-hole pairs) and has high electron affinity, which react with oxygen and water adsorbed on its surface forming reactive oxygen species (ROS), such as hydroxyl radicals and superoxide radicals, singlet oxygen, hydrogen peroxide, that, in turn, decompose pollutants and micropollutants.

The invention provides a process for regenerating a catalyst used for the ring hydrogenation of an aromatic species, especially an aromatic ester, wherein a gas stream containing a particular amount of oxygen is used for the regeneration.

Described herein are catalysts and methods for converting waste biogas (e.g., a mixture of carbon dioxide and methane) into useful products. In some embodiments, the biogas is converted into a highly purified methane, that can be further processed to generate fuel products, including recycled natural gas (RNG) and liquid fuels. The described catalysts and methods may be advantageous over conventional methods, including by reducing catalyst costs, decreasing temperature requirements and/or providing higher purity products by reducing carbon dioxide and carbon monoxide in product streams.

The invention relates to a process for the production of ethylene glycol including the steps of: (i) reacting, in a reactor, at a temperature in the range from equal to or more than 170° C. to equal to or less than 270° C., at least a portion of a carbohydrate source in the presence of hydrogen, a solvent, a homogeneous catalyst, which homogeneous catalyst contains tungsten, and a heterogeneous catalyst, which heterogeneous catalyst contains one or more transition metals from groups 8, 9 and 10 of the Periodic Table of the Elements, yielding ethylene glycol and a spent heterogeneous catalyst; (ii) regenerating the spent heterogeneous catalyst by removing at least a portion of deposited tungsten species from the spent heterogeneous catalyst, yielding a regenerated heterogeneous catalyst; and (iii) using at least a portion of the regenerated heterogeneous catalyst as heterogeneous catalyst in the reaction of step (i). The invention further relates to a regenerated heterogeneous catalyst composition obtainable therein.

An exhaust gas purifying catalyst (10) according to the present invention is an exhaust gas purifying catalyst including the first catalyst layer (12). The first catalyst layer (12) includes the first section (14) and the second section (15) in the exhaust gas flow direction. The first section (14) is located on the upstream side in the exhaust gas flow direction relative to the second section (15). A catalyst layer (16) contains a catalytically active component including a specific element. The concentration of the specific element in the catalyst layer (12) is higher in the first section (14) than in the second section (15), in terms of mass per unit volume. When the first section is divided in half along the thickness direction of the first catalyst layer (12), the ratio of a1 to a2, a1/a2, is 1.1 or more, where a1 represents the mass of the specific element that is present on the surface side of the catalyst layer (12) and a2 represents the mass of the specific element that is present on the other side than the surface side of the catalyst layer.

A method can include incorporating graphene oxide (GO) in a solution, reducing the graphene oxide (GO) by refluxing carbon nitride (C.sub.3N.sub.4) in the solution to form carbon-nitride refluxed-graphene-oxide (C.sub.3N.sub.4-rGO) composites, and incorporating ruthenium ions into the C.sub.3N.sub.4-rGO composites to form C.sub.3N.sub.4-rGO-Ru complexes.

Provided are a hydrocarbon adsorbent, an exhaust gas purifying catalyst, and an exhaust gas purifying system, which are capable of adsorbing hydrocarbons, storing the adsorbed hydrocarbons up to a relatively high temperature, and desorbing the adsorbed and stored hydrocarbons at a relatively high temperature.

The hydrocarbon adsorbent contains a multipore zeolite containing, outside the zeolite framework, at least one metal selected from the group consisting of transition metals belonging to Groups 3 to 12 in the periodic table, amphoteric metals belonging to Groups 13 and 14 in the periodic table, alkali metals, and alkaline earth metals; and has a content ratio of the metal of 9% by mass or less relative to the multipore zeolite containing the metal.

The present disclosure provides processes for the purification of 2,5-furandicarboxylic acid (FDCA). The present disclosure further provides crystalline preparations of purified FDCA, as well as processes for making the same. In addition, the present disclosure provides mixtures used in processes for the purification of FDCA.

Catalysts for the hydrogenation of aromatic containing polymers are described. Such a catalyst can include, based on the total weight of the catalyst, 99.1 wt. % to 99.95 wt. % of a metal oxide support, and 0.05 wt. % to 0.9 wt. % of catalytic metal nanoparticles comprising platinum (Pt), palladium (Pd), ruthenium (Ru), any combination thereof, or alloy thereof. The catalyst can have a specific surface area of 5 m.sup.2/g to 80 m.sup.2/g, a pore volume of 0.01 cm.sup.3/g to 0.35 cm.sup.3/g, and a catalyst median particle size of less than 300 microns. Processes to produce the catalyst and methods of hydrogenating aromatic containing polymers are also described.