Patent classifications
B01J23/462
Reverse Water-Gas Shift Catalyst, Electrolytic Reaction System, Hydrocarbon Production System, and Production Method and Use Method Therefor
A reverse water-gas shift catalyst that can be used at a high temperature is obtained, and a production method thereof is obtained. The reverse water-gas shift catalyst is obtained by at least supporting one or both of nickel and iron as a catalytically active component on a carrier containing a ceria-based metal oxide or a zirconia-based metal oxide as a main component, and a ratio of the carrier to the entire catalyst is 55% by weight or more.
Hydrocarbon Production System, and Production Method and Operation Method Thereof
As a hydrocarbon production system that synthesizes hydrocarbons using water and carbon dioxide as raw materials, a hydrocarbon production system capable of producing hydrocarbons by securing hydrogen and carbon monoxide required for hydrocarbon synthesis is provided. In a hydrocarbon production system that produces hydrocarbons from at least water and carbon dioxide, the hydrocarbon production system includes at least an electrolytic reaction unit, a reverse water-gas shift reaction unit, and a hydrocarbon synthesis reaction unit.
Ammonia membrane reactor comprising a composite membrane
The present specification discloses a membrane reactor comprising a reaction region; a permeate region; and a composite membrane disposed at a boundary of the reaction region and the permeate region, wherein the reaction region comprises a bed filled with a catalyst for dehydrogenation reaction, wherein the composite membrane comprises a support layer including a metal with a body-centered-cubic (BCC) crystal structure, and a catalyst layer including a palladium (Pd) or a palladium alloy formed onto the support layer, wherein ammonia (NH.sub.3) is supplied to the reaction region, the ammonia is converted into hydrogen (H.sub.2) by the dehydrogenation reaction in the presence of the catalyst for dehydrogenation reaction, and the hydrogen permeates the composite membrane and is emitted from the membrane reactor through the permeate region.
HYDROCARBON REFORMING CATALYST AND HYDROCARBON REFORMING APPARATUS
A hydrocarbon reforming catalyst used for forming a synthetic gas containing hydrogen and carbon monoxide from a hydrocarbon-based gas, the hydrocarbon reforming catalyst containing a complex oxide having a perovskite structure, wherein the complex oxide has a crystal phase containing SrZrO.sub.3 as a primary component and contains Ru.
HYDROCARBON REFORMING CATALYST, HYDROCARBON REFORMING APPARATUS, AND METHOD FOR RECOVERING HYDROCARBON REFORMING CATALYST FROM DETERIORATION DUE TO SULFUR
A catalyst for forming a synthetic gas containing hydrogen and carbon monoxide from a hydrocarbon-based gas, the catalyst containing a complex oxide having a perovskite structure, wherein the complex oxide has a crystal phase containing CaZrO.sub.3 as a primary component and contains Ru and at least one of Ce and Y.
Synthesis of N-vinyl compounds by reacting cylic NH-compounds with acetylene in presence of homogenous catalyst
A process can be used to produce N-vinyl compounds by homogeneous catalysis. In the process, acetylene is reacted with a cyclic compound having at least one nitrogen as a ring member, hearing a substitutable hydrogen residue (cyclic compound C), in a liquid phase in the presence of a ruthenium complex containing at least one phosphine as a ligand (RuCat).
AMMONIA SYNTHESIS CATALYST, METHOD OF PRODUCING THE SAME, AND METHOD OF SYNTHESIZING AMMONIA USING THE SAME
An ammonia synthesis catalyst, includes a composite oxide carrier in which at least one additive metal element selected from the group consisting of titanium (Ti), zirconium (Zr), hafnium (Hf), aluminum (Al), gallium (Ga), indium (In), silicon (Si), germanium (Ge), and tin (Sn) is solid-solutionized in a composite oxide containing cerium (Ce) and a lanthanide other than Ce and having a composition represented by the following formula:
Ce.sub.xA.sub.1−x−yB.sub.yO.sub.d
(in the formula, A represents a lanthanide other than Ce, B represents the additive metal element, x represents a molar fraction of Ce, y represents a molar fraction of the additive metal element, 1−x−y represents a molar fraction of a lanthanide other than Ce, x and y satisfy 0.1≤x≤0.9, 0.01≤y≤0.3, and 0.11≤x+y≤0.91, d represents a molar ratio of oxygen atoms, and 1.5≤d≤2 is satisfied); and ruthenium (Ru) supported on the composite oxide carrier.
MOLDING CATALYST FOR HYDROGEN CHLORIDE OXIDATION REACTION, AND METHOD FOR PRODUCING SAME
The present invention relates to a method for producing a molding catalyst for obtaining chlorine (Cl.sub.2) through an oxidation reaction of hydrogen chloride (HCl), and more specifically, to a method for producing an oxidation reaction molding catalyst by adding heterogeneous material to a ruthenium oxide (RuO.sub.2)-supported catalyst having titanium oxide (TiO.sub.2) as a supporting body, and molding so as to be usable in a fixed bed reactor to produce chlorine (Cl.sub.2) from hydrogen chloride (HCl).
Method for producing cyclobutanediol compound
Provided is a process in which a cyclobutanediol compound having a high cis:trans ratio can be stably obtained. The cyclobutanediol compound having a cis:trans ratio of 1.5:1 to 5000:1 is produced by using at least one compound selected from a group consisting of a cyclobutanedione compound, a cyclobutane ketol compound, and a cyclobutanediol compound as a raw material, and performing a catalytic hydrogenation reaction and an isomerization reaction in the cyclobutanediol compound in a solid phase state in the presence of a metal catalyst without adding a solvent.
Honeycomb catalytic converter
The present invention relates to a honeycomb catalytic converter, including: a honeycomb structured body in which multiple through-holes are arranged longitudinally in parallel with one another with a partition wall therebetween; and Pd and Rh supported on the partition walls of the honeycomb structured body, wherein the honeycomb structured body is an extrudate containing a ceria-zirconia complex oxide and alumina, a Pd-carrying region where only Pd is supported is formed on the partition walls within a predetermined width from one end of the honeycomb structured body, and a Rh-carrying region where only Rh is supported is formed on the partition walls within a predetermined width from the other end of the honeycomb structured body, and the Pd-carrying region extends to at least 50% of the length of the honeycomb structured body, and the Rh-carrying region extends to at least 20% of the length of the honeycomb structured body.