Patent classifications
B01J23/464
EXHAUST PURIFICATION FILTER
The present invention provides an exhaust purification filter with which pressure loss can be reduced, the filter having high exhaust purification performance and granular-substance-filtering performance. The exhaust purification filter comprises a filter base material having a wall flow structure, and an exhaust purification catalyst supported on a dividing wall of the filter base material, the exhaust purification filter being such that: a median pore diameter (D50) of the filter base material according to a volumetric basis is 15 μm or greater; and the exhaust purification catalyst is unevenly supported on a high-density layer, in which the density of the exhaust purification catalyst is relatively high, and a low-density layer, in which the density of the exhaust purification catalyst is relatively low.
EXHAUST GAS PURIFICATION CATALYST AND PRODUCTION METHOD THEREFOR
A substrate (11) of an exhaust gas purification catalyst (10) includes inflow-side cells (21), outflow-side cells (22), and porous partition walls (23) each separating the inflow-side cell and the outflow-side cell. Catalyst portions (14, 15) are provided on surfaces of the partition walls that each face the inflow-side cell and/or surfaces of the partition walls that each face the outflow-side cell. In a cross section vertical to an exhaust gas flow direction, the percentage of the total area of voids, each void satisfying the expression L/{2(πS).sup.1/2}≤1.1, wherein L is the perimeter of the void in the cross section and S is the area of the void in the cross section, is from 3 to 10% based on the apparent area of the catalyst portion present on the partition wall.
LAYERED TRI-METALLIC CATALYTIC ARTICLE AND METHOD OF MANUFACTURING THE CATALYTIC ARTICLE
The presently claimed invention provides a tri-metallic layered catalytic article comprising: a) a top layer comprising platinum supported on at least one of an oxygen storage component, zirconia component and an alumina component, and rhodium supported on an oxygen storage component; b) a bottom layer comprising a front zone and a rear zone, said front zone comprising palladium supported on an oxygen storage component and an alumina component, and the rear zone comprises platinum supported on at least one of an alumina component, a ceria component, and an oxygen storage component; and c) a substrate, wherein the weight ratio of palladium to platinum is in the range of 1.0:0.4 to 1.0:2.0.
CATALYST ARTICLE HAVING HIGH LOCAL RHODIUM CONCENTRATION
The present invention provides a catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end and an outlet end with an axial length L; a first catalytic region comprising support material particles; at least some of the support material particles are rhodium-supporting support material particles having rhodium supported thereon at a concentration of from 0.001 to 3.5 wt. %, based on the weight of the rhodium-supporting support material particle; and the rhodium is present at a loading of up to 20 g/ft.sup.3 relative to the first catalytic region.
Method for manufacturing nonylcyclohexanol
A method for manufacturing nonylcyclohexanol is provided. The method includes steps as follows: adding a liquid phase reactant into a reactor, and the liquid phase reactant includes a molten nonylphenol and a catalyst; introducing a gas phase reactant to maintain a pressure of the gas phase reactant to be from 36.5 bar to 70 bar, and the gas phase reactant consists of hydrogen; rotating a hollow stirring shaft of the reactor at a temperature of from 100° C. to 130° C. so that the gas phase reactant is transported through a channel formed in the hollow stirring shaft into the liquid phase reactant for carrying out a reaction; obtaining a product that contains nonylcyclohexanol. A conversion rate of the nonylcyclohexanol is higher than or equal to 99.0%.
Exhaust Gas Purification Catalyst
An exhaust gas purification catalyst for providing removal performance of methane, which is chemically stable includes a substrate that divides cells through which an exhaust gas flows and a catalyst layer that is provided on a surface of the substrate. The catalyst layer includes a palladium layer containing palladium that extends from a first end part which is an end part on the side of the cells into which an exhaust gas flows to a second end part which is an end part on the side from which an exhaust gas flows out, a platinum layer containing platinum that extends from the second end part to the first end part, and a rhodium layer containing rhodium that is laminated on both the palladium layer and the platinum layer.
CATALYZED GASOLINE PARTICULATE FILTER
The present invention relates to a catalyzed particulate filter and methods comprising the filter for treatment of an exhaust gas from a gasoline engine, the catalyzed particulate filter comprising a gasoline particulate filter (GPF); a major catalytic layer coated onto or within an inlet side, an outlet side, or both sides of the GPF surfaces, the major catalytic layer comprising a first composition, wherein the first composition comprising a first support material; and a first platinum group metal (PGM); and a minor functional material layer placed onto or within an inlet side, an outlet side, or both sides of the GPF surfaces; the minor catalytic layer comprising a second composition; wherein the major catalytic layer has a higher loading than the minor functional material layer; the minor functional material layer is placed on top of the major catalytic layer, or the major catalytic material layer is placed on top of the minor functional layer. The catalyzed particulate filter provides an improved catalytic efficiency in conjunction with an efficient filter.
LAYERED TWC
The present invention relates to a three-way catalyst (TWC) for treatment of exhaust gases from internal combustion engines operated with a predominantly stoichiometric air/fuel ratio, so called spark ignited engines.
HYDROTHERMALLY AND THERMALLY STABLE CATALYTIC MATERIALS BASED ON THETA-ALUMINA
A material and a method of making hydrothermally stable (catalytic) materials on the basis of theta-alumina support that is thermally and hydrothermally stable up to 1,150 C with metal, mixed metal-, metal-oxide nanoparticles dispersed upon it. Such materials did not lose significant amounts of their catalytic activity at temperature ranges for industrially relevant applications (including hydrocarbon oxidation, nitric oxide reduction, carbon monoxide oxidation) even after hydrothermal aging up to 1,150° C.
Three-way catalyst
The present invention relates to a catalyst comprising a carrier substrate of the length L extending between substrate ends a and b and three washcoat zones A, B and C wherein washcoat zone A comprises one or more first platinum group metals and extends starting from substrate end a over a part of the length L, washcoat zone C comprises one or more first platinum group metals and extends starting from substrate end b over a part of the length L, and washcoat zone B comprises the same components as washcoat zone A and in addition, one or more second platinum group metals and extends between washcoat zones A and C, wherein L=L.sub.A+L.sub.B+L.sub.C, wherein L.sub.A is the length of washcoat zone A, L.sub.B is the length of substrate length B and L.sub.C is the length of substrate length C.