Catalysts, catalytic systems and related synthetic methods for in situ production of H.sub.2O.sub.2 and use thereof in reaction with oxidizable substrates.

An iridium-containing oxide having a total pore volume of 0.20 cm.sup.3/g or more, calculated by a BJH method from nitrogen adsorption/desorption isotherm measurement, and a pore distribution having an average pore diameter of 7.0 nm or more.

A composite catalyst includes a carrier and noble metal particles supported by the carrier, wherein the carrier is a nitrogen-doped porous carbon composite material having a plurality of passages. The nitrogen-doped porous carbon composite material can include a nitrogen-doped porous carbon material and a plurality of metal oxide particles. The plurality of metal oxide particles can be uniformly distributed in the nitrogen-doped porous carbon material. The plurality of metal oxide particles can be partially exposed through the plurality of passages. The noble metal particles can be tightly combined with the exposed metal oxide particles to achieve recombination. And the noble metal particles can be at least one of Pd metal particles, Pt metal particles, Ru metal particles, Rh metal particles, Ir metal particles, Au metal particles, or a combination thereof.

Disclosed are devices capable of heterogeneous electrochemical catalysis. Also disclosed are methods of using the devices in various electrochemical reactions.

A process for the preparation of a catalyst composition for catalysing hydrogenation and hydrogenolysis reactions wherein, (a) a carbon support is contacted with a catalyst precursor solution comprising at least one element from groups 7, 8, 9, 10 and 11 of 5 the periodic table to form a metal impregnated carbon; (b) the metal impregnated carbon is dried at a temperature of no greater than 400 C. and placed in a reactor vessel; (c) the reactor vessel is sealed; and (d) the metal impregnated carbon is treated in the reactor 10 vessel in an atmosphere comprising hydrogen at a temperature of from 25 C. to 350 C.

A process for the production of glycols is provided, the process comprising the steps of: (i) contacting a saccharide-containing feedstock with a catalyst system in a reactor in the presence of a reaction medium, a buffer system for controlling the pH within the reactor, and hydrogen; (ii) withdrawing a reactor product stream from the reactor; (iii) separating the reactor product stream into at least a glycol product stream and a hydrocarbon heavies stream; and (iv) recycling the hydrocarbon heavies stream at least partially back to the reactor; wherein components of the buffer system withdrawn from the reactor in the reactor product stream separate with the heavies stream and are recycled therewith.

Water electrolyzer comprising a membrane having first and second opposed major surfaces, a thickness extending between the first and second major surfaces, and first, second, and third regions equally spaced across the thickness, wherein the first region is the closest region to the first major surface, wherein the second region is the closest region to the second major surface, wherein the third region is located between the first and second regions, wherein the first and third regions are each essentially free of both metallic Pt and Pt oxide, and wherein the second region comprises at least one of metallic Pt or Pt oxide; a cathode comprising a first catalyst on the first major surface of the membrane; and an anode comprising a second catalyst on the second major surface of the membrane.

A problem of the present invention is to provide a solid polymer membrane electrode capable of obtaining electrolyzed hydrogen water in which an increase of the pH is suppressed and which has a sufficient dissolved-hydrogen amount. The present invention is concerned with a solid polymer membrane electrode for generating electrolyzed water, wherein the solid polymer membrane electrode includes a solid polymer membrane and catalyst layers containing a platinum group metal and provided on the back and front of the solid polymer membrane; and the solid polymer membrane is a hydrocarbon-based cation exchange membrane and has an ion exchange capacity per unit area of 0.002 mmol/cm.sup.2 or more and 0.030 mol/cm.sup.2 or less.

The present invention provides a method for preparing 1,5-pentanediol via hydrogenolysis of tetrahydrofurfuryl alcohol. The catalyst used in the method is prepared by supporting a noble metal and a promoter on an organic polymer supporter or an inorganic hybrid material supporter, wherein the supporter is functionalized by a nitrogen-containing ligand. When the catalyst is used in the hydrogenolysis of tetrahydrofurfuryl alcohol to prepare 1,5-pentanediol, a good reaction activity and a high selectivity can be achieved. The promoter and the nitrogen-containing ligand in the supporter are bound to the catalyst through coordination, thereby the loss of the promoter is significantly decreased, and the catalyst has a particularly high stability. The lifetime investigation of the catalyst, which has been reused many times or used continuously for a long term, suggests that the catalyst has no obvious change in performance, thus reducing the overall process production cost.

[Problem] To provide an electrode manufacturing method and an electrode manufacturing device with high productivity, and an electrode obtained therewith.

[Solution] Provided is an electrode manufacturing method, comprising performing pyrolysis while simultaneously directly spraying a coating liquid onto a heated substrate to form a catalytic layer or intermediate layer on the substrate.