The present invention discloses a novel method and novel compositions comprising well-dispersed particulate metal materials, including metal nanoparticles and/or metal single-atom materials, on various substrates, said method comprising the use of atomic layer deposition (ALD) and optimization of the metal precursor dose time and the number of ALD cycles. Illustrative of the metals are Fe, Ni, Co, Ru, Rh, Ir, Os, Pt, Pd, and the like; and illustrative of the various substrates are carbon nanotubes (CNTs) (including multi-walled carbon nanotubes (MWCNTs), SiO.sub.2, TiO.sub.2, alumina, CeO.sub.2, ZnO, ZrO.sub.2, activated carbon, CuO, Fe.sub.2O.sub.3, MgO, CaO, graphene, and the like. The density of the dispersed metals on the substrates is significantly higher than the metal density

The present invention relates in part to a method of fabricating multimetallic nanoparticles, the method comprising the steps of providing a substrate; activating the substrate surface; adsorbing a cationic transition metal complex onto the substrate surface to form a substrate-supported cationic transition metal complex; adsorbing an anionic transition metal complex onto the substrate-supported cationic transition metal complex to form a substrate-supported multimetallic complex salt; and reducing the substrate-supported multimetallic complex salt to provide a plurality of multimetallic nanoparticles. The invention also relates in part to a composition of multimetallic nanoparticles comprising at least two metals M.sub.a and M.sub.b; wherein the ratio of M.sub.a to M.sub.b is between about 2:1 and about 1:2.

Proposed are a water-splitting hydrogen production photocatalyst including spatially separated cocatalysts and a method of preparing the same. The photocatalyst is shaped to be hollow. The photocatalyst includes a first cocatalyst core containing a first cocatalyst, a catalyst layer positioned on the first cocatalyst core and containing a first catalyst and a second catalyst, and a second cocatalyst layer positioned on the catalyst layer and containing a second cocatalyst. The photocatalyst exhibits excellent hydrogen production efficiency and charge transfer efficiency.

Methods, compositions, and articles of manufacture for alkane activation with single- or bi-metallic catalysts on crystalline mixed oxide supports.

A catalyst structure includes a carrier having a porous structure composed of a zeolite type compound and at least one catalytic material existing in the carrier. The carrier has channels communicating with each other, and the catalytic material is a metal fine particle and exists at least in the channel of the carrier.

Methods of synthesizing and isolating facial-tris-homoleptic phenylpyridinato iridium (III) photocatalysts are disclosed. Also disclosed are methods of recovering excess 2-phenylpyridine ligands from said syntheses.

A polymer-catalyst assembly includes polarized polymeric nanofibers retaining a plurality of catalytic metallic nanoparticles. A method of making the polarized polymer-catalyst assembly may include providing a fiber mat having polymeric nanofibers retaining a plurality of catalytic metallic nanoparticles, stretching the fiber mat in a uniaxial direction, simultaneous with the step of stretching, thermally heating the fiber mat, simultaneous with the steps of stretching and thermally heating, subjecting the fiber mat to an electric field, whereby the simultaneous steps of stretching, thermally heating, and subjecting thereby form a polarized fiber mat.

The present invention provides a method for preparing 1,5-pentanediol via hydrogenolysis of tetrahydrofurfuryl alcohol. The catalyst used in the method is prepared by supporting a noble metal and a promoter on an organic polymer supporter or an inorganic hybrid material supporter, wherein the supporter is functionalized by a nitrogen-containing ligand. When the catalyst is used in the hydrogenolysis of tetrahydrofurfuryl alcohol to prepare 1,5-pentanediol, a good reaction activity and a high selectivity can be achieved. The promoter and the nitrogen-containing ligand in the supporter are bound to the catalyst through coordination, thereby the loss of the promoter is significantly decreased, and the catalyst has a particularly high stability. The lifetime investigation of the catalyst, which has been reused many times or used continuously for a long term, suggests that the catalyst has no obvious change in performance, thus reducing the overall process production cost.

Disclosed are a low-temperature de-NO.sub.x catalyst using a ceria-alumina complex support, and a method of manufacturing the same. According to the present invention, provided is a low-temperature de-NO.sub.x catalyst using a ceria-alumina complex support, manufactured by impregnating noble metal and metal oxides into a ceria-alumina complex support synthesized by treating a ceria precursor and an alumina precursor in a predetermined mass ratio by a co-precipitation method.

A manufacturing method thereof, and the catalyst for removing the nitrogen oxide includes a powdery gamma alumina support on which at least one selected from a group of titanium (Ti), lanthanum (La), or zirconium (Zr) is supported, wherein the support may be further supported with iridium (Ir) and ruthenium (Ru).