Described herein are two-stage catalytic heating systems and methods of operating thereof. A system comprises a first-stage catalytic reactor and a second-stage catalytic reactor, configured to operate in sequence and at different operating conditions, For example, the first-stage catalytic reactor is supplied with fuel and oxidant at fuel-rich conditions. The first-stage catalytic reactor generates syngas. The syngas is flown into the second-stage catalytic reactor together with some additional oxidant. The second-stage catalytic reactor operates at fuel-lean conditions and generates exhaust. Splitting the overall fuel oxidation process between the two catalytic reactors allows operating these reactors away from the stoichiometric fuel-oxidant ratio and avoiding excessive temperatures in these reactors. As a result, fewer pollutants are generated during the operation of two-stage catalytic heating systems. For example, the temperatures are maintained below 1.000° C. at all oxidation stages.

Provided are catalyst particles for treating vehicle exhaust gas, containing semiconductor nanoparticles supported by noble metals.

The present disclosure provides methods for fabricating catalysts for ammonia decomposition. The method may comprise (a) subjecting a catalyst support to one or more physical or chemical processes to optimize one or more pores, morphologies, and/or surface chemistry or property of the catalyst support; (b) depositing a composite support material on the catalyst support, wherein the composite support material comprises a morphology or surface chemistry or property; and (c) depositing one or more active metals on at least one of the composite support material and the catalyst support, wherein the one or more active metals comprise one or more nanoparticles configured to conform to the morphology of the composite support material and/or catalyst support material, thereby optimizing one or more active sites on the nanoparticles for ammonia processing.

The present disclosure provides methods for fabricating catalysts for ammonia decomposition. The method may comprise (a) subjecting a catalyst support to one or more physical or chemical processes to optimize one or more pores, morphologies, and/or surface chemistry or property of the catalyst support; (b) depositing a composite support material on the catalyst support, wherein the composite support material comprises a morphology or surface chemistry or property; and (c) depositing one or more active metals on at least one of the composite support material and the catalyst support, wherein the one or more active metals comprise one or more nanoparticles configured to conform to the morphology of the composite support material and/or catalyst support material, thereby optimizing one or more active sites on the nanoparticles for ammonia processing.

Disclosed are shaped dehydrogenation catalysts, methods for making the catalysts, and methods for dehydrogenating a hydrocarbon using the catalyst. A method for making the shaped dehydrogenation catalyst can include combining a group 13 metal precursor and a group 1 metal precursor with a catalyst support precursor to form a shapeable material, shaping the shapeable material to form a wet shaped material, drying the wet shaped material to form a dry shaped material, and calcining the dry shaped material to form the shaped dehydrogenation catalyst.

Disclosed are shaped dehydrogenation catalysts, methods for making the catalysts, and methods for dehydrogenating a hydrocarbon using the catalyst. A method for making the shaped dehydrogenation catalyst can include combining a group 13 metal precursor and a group 1 metal precursor with a catalyst support precursor to form a shapeable material, shaping the shapeable material to form a wet shaped material, drying the wet shaped material to form a dry shaped material, and calcining the dry shaped material to form the shaped dehydrogenation catalyst.

Provided is a catalyst that is free from catalyst deactivation caused by reaction of the support and exhibits good catalytic activity in an ammonia synthesis reaction in a low-temperature, low-pressure process. The present invention relates to an ammonia synthesis catalyst having a structure in which at least one of ruthenium or an oxide of ruthenium is loaded on a titanium suboxide support represented by the composition formula TiOx where x represents a number satisfying 1.5<x<2.0.

A preparation method for a highly chlorine- and water-resistant catalyst is provided. A mixture of at least one of SnO.sub.2, GeO.sub.2, and MoO.sub.2 with CeO.sub.2 is used as a catalyst support, face-centered cubic ruthenium oxide is used as an active component, and the catalyst with excellent chlorine- and water-resistance is prepared through selective adsorption regulation, which can realize safe and efficient purification of chlorine-containing organic waste gas at temperatures below 250° C.

Described are a catalyst capable of effectively oxidizing an exhaust gas, a method for preparing the catalyst, and a method for oxidizing an exhaust gas using the catalyst. The exhaust gas oxidation catalyst includes at least two layers, a lower catalyst layer and an upper catalyst layer, laminated on a three-dimensional structure, wherein the lower catalyst layer and the upper catalyst layer independently contain precious metal and alumina and/or zeolite, and at least a part of the upper catalyst layer contains pores derived from a pore connecting agent with a combustion decomposition temperature of 300° C. or more to less than 450° C.

A catalyst-containing material includes a refractory matrix and particles of one or more catalytic metal elements or catalytic oxides. The particles are dispersed through, and embedded in, the refractory matrix.