B01J23/68

Photocatalyst, and method for producing photocatalyst

A photocatalyst, represented by the following general formula (1):
X(VO.sub.4).sub.6(OH).sub.2General Formula (1) wherein X represents Z.sub.a1Ti.sub.b1 or Z.sub.a2Ti.sub.b2Ag.sub.c2 (where Z is Ca or Sr; a1 is 7.0 to 9.5; b1 is 0.5 to 3.0; a2 is 7.0 to 9.5; b2 is 0.4 to 1.5; c2 is 0.1 to 2.0; a1+b1 is 9.0 to 10.0; and a2+b2+c2 is 9.0 to 10.0) in the general formula (1).

Photocatalyst, and method for producing photocatalyst

A photocatalyst, represented by the following general formula (1):
X(VO.sub.4).sub.6(OH).sub.2General Formula (1) wherein X represents Z.sub.a1Ti.sub.b1 or Z.sub.a2Ti.sub.b2Ag.sub.c2 (where Z is Ca or Sr; a1 is 7.0 to 9.5; b1 is 0.5 to 3.0; a2 is 7.0 to 9.5; b2 is 0.4 to 1.5; c2 is 0.1 to 2.0; a1+b1 is 9.0 to 10.0; and a2+b2+c2 is 9.0 to 10.0) in the general formula (1).

Antibacterial material and antibacterial film and antibacterial member using the same

In one embodiment, an antibacterial material includes at least one microparticles selected from tungsten oxide microparticles and tungsten oxide complex microparticles. The microparticles, which have undergone a test to evaluate viable cell count by inoculating in a test piece, to which the microparticles are adhered in a range of 0.02 mg/cm.sup.2 or more and 40 mg/cm.sup.2 or less, at least one bacterium selected from among Staphylococcus aureus, Escherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa, methicillin-resistant Staphylococcus aureus, and enterohemorrhagic Escherichia coli, and storing for 24 hours, have an antibacterial activity value R of 0.1 or more expressed by the following: R=log(B.sub.1/C.sub.1) where, B.sub.1 denotes an average value (number) of viable cell count after storing an untreated test piece for 24 hours, and C.sub.1 denotes an average value (number) of viable cell count after storing the test piece on which the microparticles are coated for 24 hours.

CATALYST FOR REDUCTION REACTION OF 3,4-DIHYDROXYTETRAHYDROFURAN, AND METHOD FOR PRODUCING 3,4-DIHYDROXYTETRAHYDROFURAN REDUCED PRODUCT

Provided is a catalyst for reduction reaction with which 1,4-butanediol or tetrahydrofuran can be obtained with higher selectivity than with the related art, using a raw material derived from biomass. The catalyst is used in a reduction reaction of 3,4-dihydroxytetrahydrofuran with hydrogen, wherein the catalyst contains metal catalysts (1) and (2) below; metal catalyst (1): a catalyst containing M1 and M2 below as metal species and supported on a carrier; and metal catalyst (2): a catalyst containing M1 below as a metal species and supported on a carrier; M1: one or more selected from the group consisting of iron and elements belonging to periods 4 to 6 and groups 5 to 7 of the periodic table; and M2: one or more selected from the group consisting of ruthenium, osmium, and elements belonging to periods 4 to 6 and groups 9 to 11 of the periodic table.

GASOLINE ENGINE EXHAUST GAS PURIFYING CATALYST FILTER

It is an object of the present invention to provide an exhaust gas purifying catalyst filter which has enhanced soot collection performance without increasing pressure loss caused by the formation of a catalyst layer in a partition wall of a wall flow type substrate.

A gasoline engine exhaust gas purifying catalyst filter for purifying exhaust gas of a gasoline engine includes: a wall flow type substrate in which an introduction-side cell having an open exhaust gas introduction-side end, and a discharge-side cell adjacent to the introduction-side cell and having an open exhaust gas discharge-side end are defined by a porous partition wall; and a catalyst layer formed in a pore of the partition wall. An absolute value of a maldistribution degree of the catalyst layer formed in the pore of the partition wall is 4.50 or less. A wash coat amount, excluding a mass of a platinum group, of the catalyst layer formed in the pore of the partition wall, is 40 g/L or more and 50 g/L or less. The catalyst layer formed in the pore of the partition wall is a single layer. The catalyst layer is free of Ba.

Porous shaped metal-carbon products

The present invention provides a porous metal-containing carbon-based material that is stable at high temperatures under aqueous conditions. The porous metal-containing carbon-based materials are particularly useful in catalytic applications. Also provided, are methods for making and using porous shaped metal-carbon products prepared from these materials.

Porous bodies with enhanced crush strength

A porous body with enhanced fluid transport properties and crush strength is provided. The porous body includes the porous body includes at least 80 percent alpha alumina and having a pore volume from 0.3 mL/g to 1.2 mL/g, a surface area from 0.3 m.sup.2/g to 3.0 m.sup.2/g, and a pore architecture that provides at least one of a tortuosity of 7 or less, a constriction of 4 or less and a permeability of 30 mdarcys or greater, wherein the porous body is a cylinder comprising at least two spaced apart holes that extend through an entire length of the cylinder. The porous body has a flat plate crush strength improved by more than 10% over a porous body cylinder having a same outer diameter and length, but having only a single hole.

Catalyst for hydrogen peroxide decomposition, process for producing the same, and method for decomposing hydrogen peroxide using the catalyst

The present invention provides a catalyst for hydrogen peroxide decomposition with which hydrogen peroxide present in acid-containing water to be treated can be efficiently decomposed at low cost and which is less apt to dissolve away in the water being treated, can be stably used over a long period, and renders acid recovery and recycling possible. The present invention has solved the problems with a catalyst for hydrogen peroxide decomposition which is for use in decomposing hydrogen peroxide present in acid-containing water to be treated, the catalyst including a base and, a catalyst layer that is amorphous, includes a platinum-group metal having catalytic function and a Group-6 element metal having catalytic function and is formed over the base.

CATALYTIC CONVERSION OF BIO-MASS DERIVABLE ALIPHATIC ALCOHOLS TO VALUABLE ALKENES OR OXYGENATES
20190308174 · 2019-10-10 ·

Disclosed is a catalyst system, its methods of preparation and its use for producing, among others, alkenes and/or saturated or unsaturated oxygenates and, which include at least one of an aldehyde and an acid (such as propyl aldehyde, acrolein, acrylic acid, isobutyl aldehyde, methacrolein, methacrylic acid), comprising subjecting the corresponding an alcohol or a diol selected from the group consisting of propanol, propanediol and isobutanol that is derivable from biomass, to a vapor phase process over the catalytic system described herein in the presence of a gas mixture of oxygen, air or nitrogen and/or other suitable diluting gas. In the case where one of 1-propanol, or 1,2-propanediol or 1,3-propanediol) or a mixture thereof is subjected to a vapor phase catalytic process over the said catalytic system in the presence of air or oxygen, and a co-fed gas, such as nitrogen or other diluting gas, the product is at least one of propylene, propyl aldehyde, acrolein and acrylic acid. In the case where isobutanol is subjected to such a process, the product is at least one of isobutylene, isobutyl aldehyde, methacrolein and methacrylic acid. The catalyst system comprises a single catalytic zone or multi-catalytic zones, in each of which the composition of the co-feed and other reaction parameter can be independently controlled.

PHOTOCATALYST DECOMPOSITION SYSTEM

To provide a photocatalyst decomposition apparatus that can supply a liquid phase containing a substance to be decomposed by a photocatalyst and that can perform decomposition of the substance more efficiently than in the related art. A photocatalyst decomposition system according to the invention includes: a gas phase generation apparatus configured to convert a liquid phase containing a decomposition object into a gas phase; and a photocatalyst member configured to come into contact with the gas phase to decompose the decomposition object by light from a light source. The photocatalyst member includes a base material formed of a porous material and a photocatalyst layer provided on a surface of the base material.