The present invention relates to a catalyst for the oxidation of hydrocarbon and the selective catalytic reduction of nitrogen oxides, the catalyst comprising a substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the substrate extending therethrough; and a coating disposed on the surface of the internal walls of the substrate, wherein the surface de-fines the interface between the passages and the internal walls, wherein the coating comprises a platinum group metal component supported on a first oxidic material and further comprises a mixed oxide of vanadium and one or more of iron, erbium, bismuth, cerium, europium, gadolinium, holmium, lanthanum, lutetium, neodymium, praseodymium, promethium, samarium, scandium, terbium, thulium, ytterbium, yttrium, molybdenum, tungsten, manganese, cobalt, nickel, copper, aluminum and antimony, wherein the mixed oxide is supported on a second oxidic material.

A pillar shaped honeycomb structure for induction heating, the honeycomb structure being made of ceramics and including: an outer peripheral wall; and a partition wall disposed on an inner side of the outer peripheral wall, the partition wall defining a plurality of cells, each of the cells penetrating from one end face to other end face to form a flow path, wherein a composite material containing a conductor and a non-conductor is provided in the cells in a region of 50% or less of the total length of the honeycomb structure from one end face, and wherein the conductor is a conductor that generates heat in response to a change in a magnetic field.

Provided is a visible-light-responsive titanium oxide microparticle dispersion or the like readily enabling manufacture of a highly transparent photocatalyst thin film demonstrating photocatalyst activity even using visible light alone, and having exceptional titanium oxide microparticle dispersion stability even after storage for prolonged periods of time in cold and dark interior locations. The present invention makes it possible to: produce a peroxotitanic acid solution containing vanadium and a tin compound from a titanium compound, a vanadium compound, a tin compound, a basic substance, hydrogen peroxide, and an aqueous dispersion medium as starting materials; subject the peroxotitanic acid solution to a hydrothermal reaction under high pressure; subsequently admix a copper compound into the acid solution; and obtain a visible-light-responsive titanium oxide microparticle dispersion or the like.

The present invention relates to a catalytic bed for the production of phthalic anhydride by oxidation of o-xylene and/or naphthalene. The catalytic bed comprises at least four layers of vanadium and titanium mixed oxide (VTiO) catalyst, arranged in series with respect to the flow of a gaseous feed mixture comprising o-xylene and/or naphthalene and an oxygen-containing gas, where the chemical composition and the height of the four layers of catalyst are optimized to improve the catalytic performance and their lifetime. The present invention also relates to a process for the production of phthalic anhydride by oxidation of o-xylene and/or naphthalene, which uses the above catalytic bed.

Rapid, reversible redox activity may be accomplished at significantly reduced temperatures, as low as about 200 C., from epitaxially stabilized, oxygen vacancy ordered SrCoO.sub.2.5 and thermodynamically unfavorable perovskite SrCoO.sub.3-. The fast, low temperature redox activity in SrCoO.sub.3- may be attributed to a small Gibbs free energy difference between the two topotactic phases. Epitaxially stabilized thin films of strontium cobaltite provide a catalyst adapted to rapidly transition between oxidation states at substantially low temperatures. Methods of transitioning a strontium cobaltite catalyst from a first oxidation state to a second oxidation state are described.

Rapid, reversible redox activity may be accomplished at significantly reduced temperatures, as low as about 200 C., from epitaxially stabilized, oxygen vacancy ordered SrCoO.sub.2.5 and thermodynamically unfavorable perovskite SrCoO.sub.3-. The fast, low temperature redox activity in SrCoO.sub.3- may be attributed to a small Gibbs free energy difference between the two topotactic phases. Epitaxially stabilized thin films of strontium cobaltite provide a catalyst adapted to rapidly transition between oxidation states at substantially low temperatures. Methods of transitioning a strontium cobaltite catalyst from a first oxidation state to a second oxidation state are described.

Oxidative dehydrogenation of paraffins to olefins provides a lower energy route to produce olefins. Oxidative dehydrogenation processes may be integrated with a number of processes in a chemical plant such as polymerization processes, manufacture of glycols, and carboxylic acids and esters. Additionally, oxidative dehydrogenation processes can be integrated with the back end separation process of a conventional steam cracker to increase capacity at reduced cost.

Oxidative dehydrogenation of paraffins to olefins provides a lower energy route to produce olefins. Oxidative dehydrogenation processes may be integrated with a number of processes in a chemical plant such as polymerization processes, manufacture of glycols, and carboxylic acids and esters. Additionally, oxidative dehydrogenation processes can be integrated with the back end separation process of a conventional steam cracker to increase capacity at reduced cost.

Tantalum nitride and specifically a novel Ta.sub.3N.sub.5 nanoparticles, such as single crystalline Ta.sub.3N.sub.5 nanoparticles, are disclosed. The nanoparticles used with a co-catalyst is further disclosed. The present invention also relates to Ta.sub.3N.sub.5 nanoparticles modified with a metal oxide, such as a CoO.sub.xcocatalyst, wherein O.sub.x represents an oxide that is part of the cobalt oxide. A catalyst, such as for water oxidation to produce O.sub.2, is disclosed. The nanoparticles can further be modified to include a water reducing catalyst. A water splitting catalyst is further disclosed. Methods of making the nanoparticles and catalyst are also disclosed. Methods to split water utilizing the catalyst are further described.

The present disclosure provides SCR catalyst compositions capable of reducing nitrogen oxide (NO.sub.x) emissions in engine exhaust. The catalyst compositions include a reducible metal oxide support containing ceria, one or more transition metal oxides as a redox promotor; and an oxide of niobium, tungsten, silicon, molybdenum, or a combination thereof as an acidic promotor. The redox promotor and the acid promotor are both supported on the reducible metal oxide support. Further provided are SCR catalyst articles coated with such compositions, processes for preparing such catalyst compositions and articles, an exhaust gas treatment system including such catalyst articles, and methods for reducing NO.sub.x in an exhaust gas stream using such catalyst articles and systems.