Patent classifications
B01J27/198
CATALYST SYSTEM FOR OXIDIZING O-XYLOL AND/OR NAPHTHALENE INTO PHTHALIC ANHYDRIDE
The present invention relates to a catalyst system for oxidation of o-xylene and/or naphthalene to phthalic anhydride (PA), comprising a plurality of catalyst zones arranged in succession in the reaction tube, which have been produced using antimony trioxide comprising a noticeable proportion of senarmontite wherein some of the primary crystallites have a size of less than 200 nm. The present invention further relates to a process for gas phase oxidation, in which a gas stream comprising at least one hydrocarbon and molecular oxygen is passed through a catalyst system which comprises a plurality of catalyst zones arranged in succession in the reaction tube and which has been produced using an antimony trioxide comprising a noticeable proportion of senarmontite wherein some of the primary crystallites have a size of less than 200 nm.
Composition and method for capture and degradation of PFAS
Materials for binding per- and polyfluoroalkyl substances (PFAS) are disclosed. A fluidic device comprising the materials for detection and quantification of PFAS in a sample is disclosed. The fluidic device may be configured for multiplexed analyses. Also disclosed are methods for sorbing and remediating PFAS in a sample. The sample may be groundwater containing, or suspected of containing, one or more PFAS.
Composition and method for capture and degradation of PFAS
Materials for binding per- and polyfluoroalkyl substances (PFAS) are disclosed. A fluidic device comprising the materials for detection and quantification of PFAS in a sample is disclosed. The fluidic device may be configured for multiplexed analyses. Also disclosed are methods for sorbing and remediating PFAS in a sample. The sample may be groundwater containing, or suspected of containing, one or more PFAS.
METHOD FOR PRODUCING HYDROXYCARBOXYLIC ACID ESTER
An object of the present invention is to provide a method for selectively producing a hydroxycarboxylic acid ester, the method including reducing a dicarboxylic acid monoester by means of a heterogeneous reaction. According to a method for producing a hydroxycarboxylic acid ester in an embodiment of the present invention, a hydroxycarboxylic acid ester represented by Formula (2) is produced by reducing a substrate dicarboxylic acid monoester represented by Formula (1) in the presence of a catalyst.
The catalyst comprises: metal species including M.sub.1 and M.sub.2; and a support supporting the metal species, and wherein M.sub.1 is rhodium, platinum, ruthenium, iridium or palladium; M.sub.2 is tin, vanadium, molybdenum, tungsten or rhenium; and the support is hydroxyapatite, fluorapatite, or hydrotalcite.
##STR00001##
METHOD FOR PRODUCING HYDROXYCARBOXYLIC ACID ESTER
An object of the present invention is to provide a method for selectively producing a hydroxycarboxylic acid ester, the method including reducing a dicarboxylic acid monoester by means of a heterogeneous reaction. According to a method for producing a hydroxycarboxylic acid ester in an embodiment of the present invention, a hydroxycarboxylic acid ester represented by Formula (2) is produced by reducing a substrate dicarboxylic acid monoester represented by Formula (1) in the presence of a catalyst.
The catalyst comprises: metal species including M.sub.1 and M.sub.2; and a support supporting the metal species, and wherein M.sub.1 is rhodium, platinum, ruthenium, iridium or palladium; M.sub.2 is tin, vanadium, molybdenum, tungsten or rhenium; and the support is hydroxyapatite, fluorapatite, or hydrotalcite.
##STR00001##
Catalyst system for producing maleic anhydride by means of the catalytic oxidation of n-butane
The invention relates to a catalyst system for producing maleic anhydride by means of the catalytic oxidation of n-butane, comprising at least one reactor tube, which has two catalyst layers consisting of different catalyst particles, characterized in that the geometric surface area per catalyst particle is greater in the catalyst layer that is first in the gas flow direction than in the second catalyst layer. The invention further relates to a process for producing maleic anhydride by means of the catalytic oxidation of n-butane, wherein a mixture of oxygen and n-butane is fed through the catalyst system according to the invention and the at least one reactor tube is at elevated temperature.
Shaped catalyst body with improved properties, its preparation and use
A shaped catalyst body for heterogeneously catalyzed reactions of organic compounds in the gas-phase in fixed-bed reactors, containing an element from group 3 to 12 of the Periodic Table of the Elements, and having a three-lobed structure with a lateral surface around the lobes, a top cover and a bottom cover, as well as three continuous holes running from one cover side to the other cover side, wherein each hole is assigned to one lobe and wherein the cover sides have outwardly shaped arches, its production and a process for its use in the heterogeneously catalyzed reaction of an organic compound in the gas phase.
Shaped catalyst body with improved properties, its preparation and use
A shaped catalyst body for heterogeneously catalyzed reactions of organic compounds in the gas-phase in fixed-bed reactors, containing an element from group 3 to 12 of the Periodic Table of the Elements, and having a three-lobed structure with a lateral surface around the lobes, a top cover and a bottom cover, as well as three continuous holes running from one cover side to the other cover side, wherein each hole is assigned to one lobe and wherein the cover sides have outwardly shaped arches, its production and a process for its use in the heterogeneously catalyzed reaction of an organic compound in the gas phase.
Method for preparing linear hydrocarbon double acid with cyclic hydrocarbon oxidation catalyst
The present invention relates to a method for preparing hydrocarbon double acids using a cyclic hydrocarbon oxidation catalyst, wherein adipic acid and dodecanedioic acid may be produced with high yield while solving the problem of environmental pollution, the adipic acid and the dodecanedioic acid being prepared by using an oxidation reaction of a cyclohexane-cyclohexanone mixture and an oxidation reaction of a cyclododecane-cyclododecanone mixture, respectively, in the presence of a vanadium phosphate oxide-based catalyst and/or a cobalt-manganese oxide-based catalyst.
Method for preparing linear hydrocarbon double acid with cyclic hydrocarbon oxidation catalyst
The present invention relates to a method for preparing hydrocarbon double acids using a cyclic hydrocarbon oxidation catalyst, wherein adipic acid and dodecanedioic acid may be produced with high yield while solving the problem of environmental pollution, the adipic acid and the dodecanedioic acid being prepared by using an oxidation reaction of a cyclohexane-cyclohexanone mixture and an oxidation reaction of a cyclododecane-cyclododecanone mixture, respectively, in the presence of a vanadium phosphate oxide-based catalyst and/or a cobalt-manganese oxide-based catalyst.