B01J29/044

Pt/Pd Sodalite Caged Catalyst Combination with Sulfided Base Metal Catalyst for the Improved Catalytic Hydroprocessing of Feedstock

A novel pt/pd sodalite caged catalyst combination with sulfided base metal catalyst for improved catalytic hydroprocessing of renewable feedstock. Particularly, the invention relates to a process for preparation of the said catalyst. More particularly, the invention relates to a process for the preparation of hydrocarbon fuel from the feed stock using a said catalyst. Further, the invention discloses a novel catalyst and a process for the preparation of the Pt/Pd encapsulated in sodalite cage with silica-alumina ZSM-5 synthesized around it supported with nickel, molybdenum, cobalt, tungsten or one or more thereof. The invention also provides process to convert vegetable oils, free fatty acids, and microbial lipids, bio-crude and conventional non-renewable crude based feed stocks such as diesel, naphtha, kerosene, gas oil, residue, etc., into gasoline, aviation, diesel, fuel and other hydrocarbons fuel with reduced coke formation and hydrogen generation due to formation of napthenes and aromatics using the novel catalyst.

METHOD FOR MANUFACTURING OF MULTI-LEVEL PORE ZEOLITE AND UTILIZATION AS CATALYST FOR HYDROISOMERIZATION OF NORMAL PARAFFINS OF MULTI-LEVEL PORE ZEOLITE PREPARED THEREBY

The present disclosure relates to a method for preparing a multi-level pore zeolite, including: (A) a step of mixing a silicon precursor, an aluminum precursor, a phosphorus precursor, a structure directing agent and water; a step of (B) adding phenylphosphonic acid, carbon black or a mixture thereof to the mixture prepared in the step (A) and mixing the same; a step of (C) crystallizing the mixture prepared in the step (B) by heat-treating the same; and a step of (D) calcining the crystallization product, and utilization of the prepared multi-level pore zeolite as a catalyst for hydroisomerization of normal paraffins. The catalyst exhibits improved isoparaffin yield when it is used as a catalyst for hydroisomerization of normal paraffins such as diesel or lube base oil by supporting an active metal component because residence time of reactants and products in the zeolite crystals are decreased due to mesopores and the proportion of external acid sites to total acid sites is low. Also, cloud point and pour point are effectively improved and high hydroisomerization reactivity is achieved without product loss.

SCR METHOD FOR REDUCING OXIDES OF NITROGEN AND METHOD FOR PRODUCING A CATALYST FOR SUCH METHOD

A method of reducing nitrogen oxides in exhaust gas of an internal combustion engine by selective catalytic reduction (SCR) comprises contacting the exhaust gas also containing ammonia and oxygen with a catalytic converter comprising a catalyst (2) comprising at least one crystalline small-pore molecular sieve catalytically active component (Z.sub.M,I) having a maximum ring opening of eight tetrahedral basic building blocks, which crystalline small-pore molecular sieve catalytically active component (Z.sub.M,I) comprising mesopores.

Process for preparing a spherical material with a hierarchical porosity comprising metallic particles trapped in a mesostructured matrix

A process is described for the preparation of an inorganic material with a hierarchical porosity in the micropore and mesopore domains. The material has at least two elementary spherical particles having a maximum diameter of 200 microns. The process comprises: a) preparing a solution containing zeolitic nanocrystals with a maximum nanometric dimension equal to 60 nm based on silicon and/or precursor elements of proto-zeolitic entities based on silicon; b) mixing, in solution, metallic particles or at least one metallic precursor of metallic particles, a surfactant and the solution obtained in accordance with a) such that the ratio of the volumes of inorganic and organic materials, V.sub.inorganic/V.sub.organic, is 0.29 to 0.50; c) aerosol atomization of the solution obtained in b) resulting in formation of spherical particles; d) drying the particles; g) eliminating any remaining precursor elements of proto-zeolitic entities based on silicon and the surfactant.

CATALYST FOR TREATING EXHAUST GAS

Catalyst compositions and methods of preparation comprising: exchanging a rare earth element into a molecular sieve; incorporating a promoter metal into the molecular sieve; wherein the rare earth element exchanging step and the promoter metal incorporation step are performed as separate steps.

Mesoporous zeolite catalyst supports
09573121 · 2017-02-21 · ·

Compositions and methods for preparing a catalyst composition containing mesoporous materials are described herein. In particular, various embodiments described herein relate to the preparation of catalytic compositions containing a mesoporous zeolite and one or more catalytic nanoparticles dispersed therein. In various embodiments described herein, such catalyst compositions can be used in various catalytic conversion processes, such as hydrocracking.

HYDROCRACKING CATALYST, PROCESS FOR PREPARING THE SAME AND USE THEREOF
20170043323 · 2017-02-16 ·

The present invention relates to a hydrocracking catalyst, a process for preparing the same and use thereof The present catalyst comprises a cracking component and a hydrogenation component, wherein the cracking component comprises from 0 to 20 wt. % of a molecular sieve and from 20 wt. % to 60 wt. % of an amorphous silica-alumina, the hydrogenation component comprises at least one hydrogenation metal in a total amount of from 34 wt. % to 75 wt. % calculated by the mass of oxides, each amount is based on the total weight of the catalyst. The present catalyst is prepared by directly mixing an acidic component powder material with an impregnating solution, impregnating, filtering, drying, molding, and drying and calcining.

Metal-carbon composite supported catalyst for hydrogen production using co-evaporation and method of preparing the same

A metal-carbon composite supported catalyst for hydrogen production using co-evaporation and a method of preparing the same, wherein the catalyst is configured such that a metal-carbon composite having a core-shell structure resulting from co-evaporation is supported on the surface of an oxide-based support coated with carbon, thereby maintaining superior durability without agglomeration even in a catalytic reaction at a high temperature. Because part or all of the surface of metal is covered with the carbon shell, even when the catalyst is applied under severe reaction conditions including high temperatures, long periods of time, acidic or alkaline states, etc., the metal particles do not agglomerate or are not detached, and do not corrode, thus exhibiting high performance and high durability. Therefore, inactivation of the catalyst or the generation of side reactions can be prevented, so that the catalyst can be efficiently utilized in hydrogen production.