Patent classifications
B01J29/084
MANUFACTURING METHOD OF HONEYCOMB STRUCTURE
The manufacturing method includes a step of mixing a coarse particle zeolite, a fine particle zeolite, and a raw material of an inorganic bonding material to prepare a zeolite raw material; a step of forming the prepared zeolite raw material into a honeycomb shape to prepare a honeycomb formed body; and a step of firing the prepared honeycomb formed body to prepare the honeycomb structure. In the step of preparing the zeolite raw material, as the coarse particle zeolite, a chabazite type zeolite having a specific average particle diameter, the fine particle zeolite having a specific average particle diameter, the raw material of the inorganic bonding material which includes at least basic aluminum lactate is used.
MULTIPLE ZEOLITE HYDROCARBON TRAPS
Hydrocarbon (HC) traps are disclosed. The HC trap may include a first zeolite material having an average pore diameter of at least 5.0 angstroms and configured to trap hydrocarbons from an exhaust stream and to release at least a portion of the trapped hydrocarbons at a temperature of at least 225° C. The HC trap may also include a second zeolite material having an average pore diameter of less than 5.0 angstroms or larger than 7.0 angstroms. One or both of the zeolite materials may include metal ions, such as transition, Group 1A, or platinum group metals. The HC trap may include two or more discrete layers of zeolite materials or the two or more zeolite materials may be mixed. The multiple zeolite HC trap may form coke molecules having a relatively low combustion temperature, such as below 500° C.
PROCESS FOR PREPARING ORGANIC ESTERS
The present invention relates to a process for preparing an ester having formula R—COO—R′ (I), wherein R represents a group selected from: (i) a linear or branched alkyl, containing from 1 to 20 carbon atoms, (ii) an aryl containing from 6 to 12 carbon atoms, (iii) a heterocycle with 4 to 12 carbon atoms containing at least one heteroatom selected from O, N, P and S, R′ represents a linear or branched alkyl containing from 1 to 12 carbon atoms, said process comprising at least a phase of reacting a reaction mixture comprising at least one aldehyde having formula R—CHO (II), wherein R has the meanings defined above, and at least one alcohol having general formula R′—OH (III), wherein R′ has the meanings defined above, in the presence of at least one solid basic catalyst, at a temperature within the range of 120° C.-300° C., obtaining said ester having formula (I).
ONE-STEP METHOD FOR THE SYNTHESIS OF HIGH SILICA CONTENT ZEOLITES IN ORGANIC-FREE MEDIA
In an embodiment, the present disclosure pertains to a composition comprising a zeolite with high silica content. In some embodiments, the silica to aluminum ratio (SAR) for the zeolite is 2:1. In some embodiments, the zeolite comprises Zeolite HOU-2 (LTA-type). In some embodiments, the silica to aluminum ratio (SAR) for the zeolite is >3. In some embodiments, the zeolite comprises Zeolite HOU-3 (FAU type). In some embodiments, the zeolite is synthesized using a one-step method. In some embodiments, the zeolite is synthesized without the use of an organic structure-directing agent (OSDA). In some embodiments, the zeolite is synthesized without the use of post-synthesis dealumination. In some embodiments, the zeolite is synthesized without the use crystal seeds. In some embodiments, the zeolite is used in commercial ion exchange. In some embodiments, the zeolite is used for catalysis reaction. In some embodiments, the zeolite is highly thermostable.
Spherical agglomerates based on zeolite(s), process for the production thereof and use thereof in adsorption processes or in catalysis
The present invention relates to spherical agglomerates based on zeolite(s) and clay(s), having controlled size and morphology, in particular a size of less than or equal to 600 μm, very good sphericity, and a high content of zeolitic material, to the process for the production thereof. These agglomerates are particularly suitable for uses in gas-phase and/or liquid-phase adsorption processes.
Treatment of aromatic alkylation catalysts
The present disclosure relates to a method for treating a catalyst that is useful for producing mono-alkylaromatic compounds, the method comprises the steps of (a) contacting the untreated catalyst with water to produce water-contacted catalyst, and (b) drying the water-contacted catalyst with a drying gas without steam being formed at a temperature of less than 300° C. to produce a treated catalyst. The treatment is effective to improve the activity and catalyst selectivity. A process for producing a mono-alkylaromatic compound comprising such a catalyst treatment is also disclosed.
FCC process using a modified catalyst
Methods and systems for producing a hydrocarbon are provided. The method can include cracking one or more C.sub.2-C.sub.10 hydrocarbons in the presence of a catalyst under conditions sufficient to produce an effluent containing ethylene, propylene, gasoline, and a coked-catalyst, wherein the catalyst includes a first catalytic component having an average pore size of less than 6.4 Å and a second catalytic component having an average pore size of 6.4 Å or more, separating the effluent to provide a recovered coked-catalyst and a cracked product; and regenerating the recovered coked-catalyst to produce heat and the catalyst.
Method for preparing NaY molecular sieve of high silica-alumina ratio and product thereof
A method for preparing a NaY molecular sieve having a high silica-to-alumina ratio, wherein deionized water, a silicon source, an aluminum source, an alkali source, and ILs as a template agent are mixed to obtain an initial gel mixture; the initial gel mixture is maintained at a proper temperature and aged, then fed into a high pressure synthesis kettle for crystallization; the solid product is separated and dried, to obtain the NaY molecular sieve having a high silica-to-alumina ratio, wherein the ILs is a short-chain alkylimidazolium ionic liquid, the template agent is less volatile, and the resultant high-silicon Y molecular sieve has a high crystallinity and a silica-to-alumina ratio of 6 or more.
FCC catalyst with more than one silica, its preparation and use
Process for the preparation of a catalyst and a catalyst comprising the use of more than one silica source is provided herein. Thus, in one embodiment, the invention provides a particulate FCC catalyst comprising about 5 to about 60 wt % one or more zeolites, about 15 to about 35 wt % quasicrystalline boehmite (QCB), about 0 to about 35 wt % microcrystalline boehmite (MCB), greater than about 0 to about 15 wt % silica from sodium stabilized basic colloidal silica, greater than about 0 to about 30 wt % silica from acidic colloidal silica or polysilicic acid, and the balance clay and the process for making the same. This process results in attrition resistant catalysts with a good accessibility.
HIGH-SILICA Y MOLECULAR SIEVE HAVING FAU TOPOLOGY AND PREPARATION METHOD THEREFOR
Disclosed in the present application is a high-silica Y molecular sieve having FAU topology. The anhydrous chemical constitution of the molecular sieve is as shown in formula I: kM.mR1.nR2.(Si.sub.xAl.sub.y)O.sub.2 Formula I; wherein, M is at least one of alkali metal elements; R1 and R2 represent organic templating agent agents; k represents the numbers of moles of the alkali metal element corresponding to per mole of (Si.sub.xAl.sub.y)O.sub.2, k=0˜0.20; m and n represent the numbers of moles of templating agents R1 and R2 corresponding to per mole of (Si.sub.xAl.sub.y)O.sub.2, m=0˜0.20, n=0.01˜0.20; x, y respectively represents the mole fraction of Si and Al, 2x/y=7-40, and x+y=1; R1, R2 are independently selected from one of nitrogen-containing heterocyclic compounds and their derivatives, and quaternary ammonium compounds. Also disclosed in the present application is a synthesis method for the high-silica Y molecular sieve having FAU topology.