Patent classifications
B01J29/16
FUNCTIONAL STRUCTURAL BODY AND METHOD FOR MAKING FUNCTIONAL STRUCTURAL BODY
A functional structural body includes a skeletal body of a porous structure composed of a zeolite-type compound, and at least one type of metallic nanoparticles present in the skeletal body, the skeletal body having channels connecting with each other, the metallic nanoparticles being present at least in the channels of the skeletal body.
Hydrocracking catalyst
Process for preparing a hydrocracking catalyst carrier which process comprises subjecting a carrier comprising an amorphous binder and zeolite Y having a silica to alumina molar ratio of at least 10 to calcination at a temperature of from 700 to 900 C., hydrocracking catalyst carrier comprising amorphous binder and zeolite Y having a silica to alumina molar ratio of at least 10, the infrared spectrum of which catalyst has a peak at 3690 cm.sup.1, substantially reduced peaks at 3630 cm.sup.1 and 3565 cm.sup.1 and no peak at 3600 cm.sup.1, hydrocracking catalyst carrier comprising an amorphous binder and zeolite Y having a silica to alumina molar ratio of at least 10, which catalyst has an acidity as measured by exchange with perdeuterated benzene of at most 20 micromole/gram, hydrocracking catalyst derived from such carrier and hydrocracking process with the help of such catalyst.
Nano-sized zeolite supported catalysts and methods for their production
According to one or more embodiments described, a zeolite supported catalyst may be synthesized by a process that includes combining a colloidal mixture with a metal oxide support material to form a support precursor material, processing the support precursor material to form a support material, and impregnating the support material with one or more metals to form the zeolite supported catalyst. The colloidal mixture may include nano-sized zeolite crystals, and the nano-sized zeolite crystals may have an average size of less than 100 nm.
STRUCTURED CATALYST FOR CATALYTIC CRACKING OR HYDRODESULFURIZATION, CATALYTIC CRACKING APPARATUS AND HYDRODESULFURIZATION APPARATUS INCLUDING THE STRUCTURED CATALYST, AND METHOD FOR PRODUCING STRUCTURED CATALYST FOR CATALYTIC CRACKING OR HYDRODESULFURIZATION
To provide a structured catalyst for catalytic cracking or hydrodesulfurization that suppresses decline in catalytic activity, achieves efficient catalytic cracking, and allows simple and stable obtaining of a substance to be modified. The structured catalyst for catalytic cracking or hydrodesulfurization (1) includes a support (10) of a porous structure composed of a zeolite-type compound and at least one type of metal oxide nanoparticles (20) present in the support (10), in which the support (10) has channels (11) that connect with each other, the metal oxide nanoparticles (20) are present at least in the channels (11) of the support (10), and the metal oxide nanoparticles (20) are composed of a material containing any one or two more of the oxides of Fe, Al, Zn, Zr, Cu, Co, Ni, Ce, Nb, Ti, Mo, V, Cr, Pd, and Ru.
Method for preparing molecular sieve-multielement oxide composite integrally extruded denitration catalyst
A preparation method for a molecular sieve-multiple oxide composite integral extrusion type denitration catalyst includes constructing an organic structure coating on the surface of a metal ion-exchanged molecular sieves and synchronously adding multiple oxide components, thus obtaining an ion-exchanged molecular sieve-multiple oxide composite denitration catalyst active component; and then mixing, kneading into paste, staling, carrying out integral extrusion forming, drying, and calcining, thus obtaining the integral extrusion type denitration catalyst. The molecular sieve-multiple oxide composite integral extraction type denitration catalyst has a denitration efficiency more than 80% at the temperature ranging from 250 C. to 420 C. in the presence of 10% steam and 500 ppm sulfuric dioxide.
CATALYST COMPOSITION FOR ENHANCING YIELD OF OLEFINS IN FLUID CATALYTIC CRACKING PROCESS (FCC)
The present invention provides a catalyst composition comprising rare earth exchanged USY zeolite (REUSY); pentasil zeolite; phosphorous compound; clay, silica, alumina, and spinel to enhance the catalytic activity and selectivity for light olefins in FCC operation conditions. The present invention also provides a process for the preparation of Light olefin enhancing catalyst composition with high propylene yield and coke selectivity.
Process for preparing a hydrowax
The invention provides a process for preparing a hydrowax comprising the steps of: (a) providing a hydrocarbonaceous feedstock which contains more than 4% by weight of hydrocarbons boiling in the range of from 550 to 800 C.; (b) hydrotreating the hydrocarbonaceous feedstock with a hydrotreating catalyst in the presence of a hydrogen-containing gas under hydrotreating conditions to obtain a hydrotreated product; (c) hydrocracking at least part of the hydrotreated product as obtained in step (b) with a hydrocracking catalyst in the presence of a hydrogen-containing gas under hydrocracking conditions to obtain a hydrocracked product, which hydrocracking catalyst contains a zeolitic component which is present in an amount of at least 14 wt %, based on the total weight of the hydrocracking catalyst, and wherein the volume ratio of the hydrotreating catalyst as used in step (b) and the hydrocracking catalyst is more than 1; and (d) recovering from the hydrocracked product as obtained in step (c) the hydrowax.
Processes for producing beta-lactone with heterogenous catalysts
The present invention is directed to processes from producing beta-lactone and beta-lactone derivatives using heterogenous catalysts. In preferred embodiments of the present invention, the processes comprise the steps: passing a feed stream comprising an epoxide reagent and a carbon monoxide reagent to a reaction zone; contacting the epoxide reagent and the carbon monoxide reagent with a heterogenous catalyst to produce a beta-lactone product in the reaction zone; and removing the beta-lactone product from the reaction zone. In preferred embodiments, the heterogenous catalyst comprises a solid support containing a cationic Lewis acid functional group and a metal carbonyl compound comprising at least one of anionic metal carbonyl compound or a neutral metal carbonyl compound. In certain preferred embodiments, the epoxide reagent and carbon monoxide reagent have a biobased content.
HYDROCARBON CONVERSION CATALYST
The present invention relates to a hydrocarbon conversion catalyst, comprising: a first composition comprising a dehydrogenation active metal on a solid support, and a second composition comprising a transition metal and a doping agent, wherein the doping agent is selected from zinc, gallium, indium, lanthanum, and mixtures thereof, on an inorganic support.
Cluster-supporting catalyst and process for producing the same
Cluster-supporting catalyst having an improved heat resistivity, and method for producing the same are provided. The cluster-supporting catalyst includes boron-substitute zeolite particles, and catalyst metal clusters supported within the pores of the boron-substitute zeolite particles. The method for producing a cluster-supporting catalyst, includes the following steps: providing a dispersion liquid containing a dispersion medium and boron-substitute zeolite particles dispersed in the dispersion medium; and in the dispersion liquid, forming catalyst metal clusters having a positive charge, and supporting the catalyst metal clusters on the acid sites within the pores of the boron-substitute zeolite particles through an electrostatic interaction.