Patent classifications
B01J29/26
Structured catalyst for catalytic cracking or hydrodesulfurization, catalytic cracking apparatus and hydrodesulfurization apparatus including the structured catalyst, and method for producing structured catalyst for catalytic cracking or hydrodesulfurization
To provide a structured catalyst for catalytic cracking or hydrodesulfurization that suppresses decline in catalytic activity, achieves efficient catalytic cracking, and allows simple and stable obtaining of a substance to be modified. The structured catalyst for catalytic cracking or hydrodesulfurization (1) includes a support (10) of a porous structure composed of a zeolite-type compound and at least one type of metal oxide nanoparticles (20) present in the support (10), in which the support (10) has channels (11) that connect with each other, the metal oxide nanoparticles (20) are present at least in the channels (11) of the support (10), and the metal oxide nanoparticles (20) are composed of a material containing any one or two more of the oxides of Fe, Al, Zn, Zr, Cu, Co, Ni, Ce, Nb, Ti, Mo, V, Cr, Pd, and Ru.
DISPROPORTIONATION AND TRANSALKYLATION CATALYST, AND PREPARATION AND APPLICATION THEREOF
A disproportionation and transalkylation catalyst can be used in the catalytic conversion of alkyl aromatic hydrocarbons. The catalyst contains an acidic molecular sieve, a first metal component immobilized on the acidic molecular sieve and an oxide additive. The first metal contained in the first metal component is at least one selected from the group of Group VB metals, Group VIB metals and Group VIIB metals, the catalyst has a mediate strong acid content of 0.05-2.0 mmol/g of catalyst, and a ratio of the mediate strong acid content to the total acid content of 60-99%. When used in the catalytic conversion of alkyl aromatic hydrocarbons, the catalyst exhibits high reaction activity, low aromatic hydrocarbon loss rate.
DISPROPORTIONATION AND TRANSALKYLATION CATALYST, AND PREPARATION AND APPLICATION THEREOF
A disproportionation and transalkylation catalyst can be used in the catalytic conversion of alkyl aromatic hydrocarbons. The catalyst contains an acidic molecular sieve, a first metal component immobilized on the acidic molecular sieve and an oxide additive. The first metal contained in the first metal component is at least one selected from the group of Group VB metals, Group VIB metals and Group VIIB metals, the catalyst has a mediate strong acid content of 0.05-2.0 mmol/g of catalyst, and a ratio of the mediate strong acid content to the total acid content of 60-99%. When used in the catalytic conversion of alkyl aromatic hydrocarbons, the catalyst exhibits high reaction activity, low aromatic hydrocarbon loss rate.
Coated hydroprocessing catalyst
Embodiments of the present disclosure are directed to a coated hydroprocessing catalyst comprising: a hydroprocessing catalyst comprising a porous support and at least one metal supported on the porous support; wherein the porous support comprising silica, alumina, titania, or combinations thereof; and the at least one metal selected from IUPAC Groups 6, 9 and 10 metals; a catalyst activation agent, a catalyst deactivation agent, or both loaded onto pores of the porous support, the catalyst activation agent comprising at least one sulfur compound and the catalyst deactivation agent comprising at least one nitrogen compound; and a coating layer on a surface of the hydroprocessing catalyst, the coating layer encapsulating the catalyst activation agent, the catalyst deactivation agent, or both within the hydroprocessing catalyst, wherein the coating layer comprises a polymer, or a paraffinic oil.
Catalyst containing LF-type B acid and method for preparing ethylene using direct conversion of syngas
A catalyst containing LF-type B acid preparing ethylene using direct conversion of syngas is a composite catalyst and formed by compounding component A and component B in a mechanical mixing mode. The active ingredient of the component A is a metal oxide; the component B is a zeolite of MOR topology; and a weight ratio of the active ingredients in the component A to the component B is 0.1-20. The reaction process has an extremely high product yield and selectivity, with the selectivity for light olefin reaching 80-90%, wherein ethylene has high space time yield and can reach selectivity of 75-80%. Meanwhile, the selectivity for a methane side product is extremely low (<15%).
Catalyst containing LF-type B acid and method for preparing ethylene using direct conversion of syngas
A catalyst containing LF-type B acid preparing ethylene using direct conversion of syngas is a composite catalyst and formed by compounding component A and component B in a mechanical mixing mode. The active ingredient of the component A is a metal oxide; the component B is a zeolite of MOR topology; and a weight ratio of the active ingredients in the component A to the component B is 0.1-20. The reaction process has an extremely high product yield and selectivity, with the selectivity for light olefin reaching 80-90%, wherein ethylene has high space time yield and can reach selectivity of 75-80%. Meanwhile, the selectivity for a methane side product is extremely low (<15%).
Method for producing xylene
A method for producing xylene, including a conversion reaction step of bringing a raw material containing a light hydrocarbon having 2 to 7 carbon atoms as a main component into contact with a crystalline aluminosilicate-containing catalyst to produce a product containing a monocyclic aromatic hydrocarbon having 6 to 8 carbon atoms and a xylene conversion step of subjecting the product to a disproportionation reaction or a transalkylation reaction.
Catalyst for Converting Alkylaromatic Hydrocarbon and Preparation Method Thereof
Disclosed are a bifunctional catalyst and a preparation method therefor, the bifunctional catalyst being suitable to produce high-value aromatic hydrocarbons by subjecting alkylaromatic hydrocarbons to a disproportionation/transalkylation/dealkylation reaction while suppressing aromatic loss or subjecting C8 aromatic hydrocarbons to an isomerization reaction while suppressing xylene loss.
Catalyst for Converting Alkylaromatic Hydrocarbon and Preparation Method Thereof
Disclosed are a bifunctional catalyst and a preparation method therefor, the bifunctional catalyst being suitable to produce high-value aromatic hydrocarbons by subjecting alkylaromatic hydrocarbons to a disproportionation/transalkylation/dealkylation reaction while suppressing aromatic loss or subjecting C8 aromatic hydrocarbons to an isomerization reaction while suppressing xylene loss.
Catalyst for converting alkylaromatic hydrocarbon and preparation method thereof
Disclosed are a bifunctional catalyst and a preparation method therefor, the bifunctional catalyst being suitable to produce high-value aromatic hydrocarbons by subjecting alkylaromatic hydrocarbons to a disproportionation/transalkylation/dealkylation reaction while suppressing aromatic loss or subjecting C8 aromatic hydrocarbons to an isomerization reaction while suppressing xylene loss.