The present disclosure is directed to processing for preparing crystalline pure-silica and heteroatom-substituted LTA frameworks in fluoride media using a simple organic structure-directing agent (OSDA), having a structure of Formula (I):

##STR00001##

where substituents R.sup.1 to R.sup.9 are defined herein. Aluminosilicate LTA is an active catalyst for the methanol to olefins reaction with higher product selectivities to butenes as well as C5 and C6 products than the commercialized catalysts. Titanosilicate LTA is an active catalyst for the epoxidation of allyl alcohol using aqueous H.sub.2O.sub.2.

Methods and systems or devices for synthesis of dimethyl ether (DME) from carbon dioxide and hydrogen are provided. A high surface area hollow fiber catalytic membrane reactor such as with hollow fibers coated with a water permeable membrane material is used. The reactor also contains a bi-functional methanol synthesis component and dehydration catalyst component such that the two-step reaction takes place on the catalyst surface. Produced water permeates through the membrane, exiting the reactor immediately after it is formed. Unreacted reactants and products flow to the reactor exit.

A catalyst for the dehydroaromatization of lower alkanes comprising boron in an amount of less than 1 wt % is supported on an inorganic support. The catalyst is useful in the production of aromatics from lower alkanes.

A method for preparing molecular sieves with a Linde Type A (LTA) topology structure, and molecular sieves obtained thereby are described wherein a structure directing agent comprising a triquaternary cation is contacted with a source of a first oxide of a first tetravalent element or a source of a first oxide of a trivalent element; and a source of an oxide of a pentavalent elements.

Described is related to a nano-structured composite absorber for air detoxing and deodoring at ambient temperature to prevent harmful chemicals in the air from damaging human health. The nano-structured composite absorber consists of nano-porous carbon, zeolites with nano-sized pores and at least 1 other component chosen from nano-porous rare earth oxides and nano-sized catalysts. The synergetic action of those nano-structured components can effectively remove toxic chemicals including, but not limited to formaldehyde, benzene, toluene, xylene, propene, butadiene, acetone, carbon monoxide, nitric oxide, nitrogen dioxide, sulfur dioxide, hydrogen sulfide, ammonia, alcohols, chlorine, mercaptans, as well as malodors, such cigarette smoke, net/fish/poultry odors and bathroom/toilet smells.

The present invention provides an adsorbent and a method for preparation of the adsorbent, wherein, the average crystal grain diameter of 5A molecular sieves in the adsorbent is 0.2-2.1 m; measured on the basis of the dry weight of the adsorbent, the content of 5A molecular sieves in the adsorbent is 92 wt. % or higher; the breaking ratio of the adsorbent at 250N is 9% or lower. The method for preparation of the adsorbent comprises: processing a powder material that contains 4A molecular sieves and a binder source by roll forming to obtain beads; drying and calcining the beads to obtain matrix beads; pre-wetting the matrix beads and then processing the matrix beads by crystal transformation so that the binder in the matrix beads is essentially transformed into 4A molecular sieves, to obtain 4A molecular sieve beads; washing the 4A molecular sieve beads with water and then processing the 4A molecular sieve beads by calcium exchange to obtain 5A molecular sieve beads; washing the 5A molecular sieve beads with water and then drying and calcining the 5A molecular sieve beads. The adsorbent provided in the present invention has advantages such as high adsorptive capacity and adsorption efficiency for n-alkanes and high strength.

Described herein are zeolite bodies, in particular those having improved physical and chemical properties, methods of manufacturing the zeolite bodies, and uses of the zeolite bodies, in particular in catalysis and gas separation.

Compositions and methods for preparing mesoporous and/or mesostructured materials from low Si/Al zeolites. Various embodiments described herein relate to preparation of mesoporous and/or mesostructured zeolites via a framework modification step followed by a mesopore introduction step.

Mesoporous X and A zeolites and methods for production thereof are disclosed herein. Such mesoporous zeolites can be prepared by contacting an initial zeolite with an acid in conjunction with a mesopore forming agent. The initial zeolite can have a framework silicon-to-aluminum content in the range of from about 1 to about 2.5. Additionally, such mesoporous zeolites can have a total 20 to 135 diameter mesopore volume of at least 0.05 cc/g.

A molecular sieve blend with improved performance characteristics produced by preparing or obtaining a hydrophilic zeolite, particularly a hydrophilic zeolite A with a low SiO.sub.2:Al.sub.2O.sub.3 ratio, preparing or obtaining a hydrophobic silicon based binder, particularly a hydrophobic colloidal silica or a hydrophobic siloxane based material, mixing the zeolite with the silicon based binder and, in one embodiment, a seed containing small quantities of a clay binding agent and the zeolite, to form a mixture, and forming the mixture into the molecular sieve blend.