The present disclosure features a high metal cation content zeolite-based binary catalyst (e.g., a high copper and/or iron content zeolite-based binary catalyst, where the zeolite can be a chabazite) for NO.sub.x reduction, having relatively low N.sub.2O make, and having low corresponding metal oxide content; where the metal in the metal oxide corresponds to the metal of the metal cation. The present disclosure also describes the synthesis of the zeolite-based binary catalyst having high metal cation content.

A method of producing a hierarchical zeolite composite catalyst is provided. The method includes dissolving, in an alkaline solution and in the presence of a surfactant, a catalyst precursor comprising mesoporous zeolite to yield a dissolved zeolite solution, where the mesoporous zeolite comprises large pore ZSM-12 and medium pore ZSM-5. The method also includes condensing the dissolved zeolite solution to yield a solid zeolite composite from the dissolved zeolite solution and heating the solid zeolite composite to remove the surfactant. The method further includes impregnating the solid zeolite composite with one or more active metals selected from the group consisting of platinum, rhenium, rhodium, molybdenum, nickel, tungsten, chromium, ruthenium, gold, and combinations thereof to yield impregnated solid zeolite composite and calcining the impregnated solid zeolite composite to produce the hierarchical zeolite composite catalyst. The hierarchical zeolite composite catalyst has a mesostructure comprising at least one disordered mesophase and at least one ordered mesophase.

Embodiments of the present disclosure are directed to hydrocracking catalysts and methods of making same. The hydrocracking catalyst comprises a platinum encapsulated zeolite having a crystallinity greater than 20% determined by X-ray powder diffraction analysis.

A hydrocarbon conversion catalyst composition which comprises ZSM-48 and/or EU-2 zeolite particles and refractory oxide binder essentially free of alumina in which the average aluminium concentration of the ZSM-48 and/or EU-2 zeolite particles is at least 1.3 times the aluminium concentration at the surface of the particles, processes for preparing such catalyst compositions and processes for converting hydrocarbon feedstock with the help of such compositions.

The invention concerns a catalyst comprising at least one zeolite with structure type MTW, a matrix, at least one metal from group VIII of the periodic classification of the elements, said catalyst having a mesopore volume increased by at least 10% compared with its initial mesopore volume, which is generally in the range 0.55 to 0.75 mL/g, at the end of a treatment with steam at a partial pressure in the range 0.01 to 0.07 MPa and at a temperature in the range 300 C. to 400 C. for at least 0.5 hour. The invention concerns the process for the preparation of said catalyst as well as an isomerization process employing said catalyst.

The present invention relates to a particle filter which comprises a wall-flow filter and SCR-catalytically active material, wherein the wall-flow filter comprises ducts which extend in parallel between a first and a second end of the wall-flow filter and which are alternately closed off in gas-type fashion either at the first or at the second end and which are separated by porous walls, and wherein the SCR-active material comprises a zeolite which is exchanged with copper and/or iron and which is situated in the form of a coating in the porous walls of the wall-flow filter, characterized in that the SCR-catalytically active coating comprises palladium.

A particle filter for treating exhaust gases includes an SCR catalyst that, when in the presence of a reductant such as ammonia, promotes selective catalytic reduction of NO.sub.x; an active oxidation catalyst that promotes oxidation of hydrocarbons and carbon monoxide; and an oxygen storage catalyst that alternately stores and releases oxygen, enhances soot oxidation, and stores NOx at temperatures below optimal SCR functioning. The particle filter may be included in a system having an oxidation catalytic device (OCD) upstream of the particle filter, and optionally includes one or more SCR converters upstream and/or downstream of the particle filter, and/or an ammonia slip catalyst downstream of the particle filter. The system may further be adapted for operation under a high frequency injection fuel control with an OCD having substantial NOx storage material content, or an NSC for improving the efficiency tradeoffs between soot oxidation during filter regeneration and NO.sub.x reduction.

Provided is a -zeolite that has an SiO.sub.2/Al.sub.2O.sub.3 ratio of less than 20 but yet is comparable or superior in heat resistance to conventional -zeolites having SiO.sub.2/Al.sub.2O.sub.3 ratio of 20 or greater. This -zeolite is characterized in that: in powder X-ray diffractometry using a CuK-ray as a ray source, the full width at half maximum of a powder X-ray diffraction peak on the (302) plane is 0.15-0.50 inclusive; and the molar ratio of silica to alumina is less than 20.0. Preferably, the -zeolite is obtained by a production method which comprises a crystallization step for crystallizing a composition comprising an alumina source, a silica source, an alkali source, a tetraethylammonium cation source and water, characterized in that the composition contains potassium and the molar ratio of potassium to silica exceeds 0.04.

A system for treatment of an exhaust gas stream from an engine is provided, containing an upstream selective catalytic reduction (SCR) catalyst, which receives the exhaust gas stream without any intervening catalyst, a diesel oxidation catalyst (DOC) positioned downstream thereof; a catalyzed soot filter (CSF) downstream of the diesel oxidation catalyst; a second SCR catalyst positioned downstream of the catalyzed soot filter; and an ammonia oxidation (AMOx) catalyst. The application also describes use of such systems to reduce nitrogen oxides (NOx) and hydrocarbons (HC) in an exhaust gas stream.

A catalyst article including a substrate with an inlet side and an outlet side, a first zone and a second zone, where the first zone includes a passive NOx adsorber (PNA), and an ammonia slip catalyst (ASC) comprising a platinum group metal on a support and a first SCR catalyst; where the second zone includes a catalyst selected from the group consisting of a diesel oxidation catalyst (DOC) and a diesel exotherm catalyst (DEC); and where the first zone is located upstream of the second zone. The first zone may include a bottom layer with a blend of: (1) the platinum group metal on a support and (2) the first SCR catalyst; and a top layer with a second SCR catalyst, the top layer located over the bottom layer.