Patent classifications
B01J29/72
Disproportionation and transalkylation of heavy aromatic hydrocarbons
Disclosed herein is a process for producing para-xylene comprising the steps of: (a) contacting a feedstock comprising toluene with a first catalyst under effective vapor phase toluene disproportionation conditions to disproportionate said toluene and produce a first product comprising benzene, unreacted toluene and greater than equilibrium amounts of para-xylene; and (b) contacting a feedstock comprising C.sub.9+ aromatic hydrocarbons and benzene with a second catalyst in the presence of 0 wt. % or more of hydrogen having a 0 to 10 hydrogen/hydrocarbon molar ratio under effective C.sub.9+ transalkylation conditions to transalkylate said C.sub.9+ aromatic hydrocarbons and produce a second product comprising xylenes.
Molecular Sieve Intergrowths of cha and aft having an "sfw-GME tail," Methods of Preparation and Use
Molecular sieves comprising intergrowths of cha and aft having an sfw-GME tail, at least one structure directing agent (SDA) within the framework of the molecular sieve, an intergrowth of CHA and GME framework structures, cha cavities, and aft cavities are described. A first SDA comprising either an N,N-dimethyl-3,5-dimethylpiperidinium cation or a N,N-diethyl-2,6-dimethylpiperidinium cation is required. A second SDA, which can further be present, is a CHA or an SFW generating cation. The amount of the second SDA-2 used can change the proportion of the components in the cha-aft-sfw-GME tail. Activated molecular sieves formed from SDA containing molecular sieves are also described. Compositions for preparing these molecular sieves are described. Methods of preparing a SDA containing JMZ-11, an activated JMZ-11, and metal containing activated JMZ-11 are described. Methods of using activated JMZ-11 and metal containing activated JMZ-11 in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.
INTRA-CRYSTALLINE BINARY CATALYSTS AND USES THEREOF
The present disclosure describes, inter alia, binary catalyst compositions including a (metal) zeolite having a crystal lattice that incorporates a metal oxide, wherein the metal oxide is covalently bound to elements within the crystal lattice. The metal oxide forms an integral part of the (metal) zeolite crystal lattice, forming covalent bonds with at least the Si or Al atoms within the crystal lattice of the (metal) zeolite, and is dispersed throughout the (metal) zeolite crystal lattice. The metal oxide can substitute atoms within the crystal lattice of the (metal) zeolite.
Method for the direct synthesis of Cu-containing silicoaluminate material with the AEI zeolite structure, and the catalytic applications thereof
The main object of the present invention is to provide a new method for preparing the copper-containing silicoaluminate form of the AEI zeolite structure by means of a direct synthesis methodology. This new process involves combining a organometallic copper-complex with an additional organic molecule capable of directing the crystallisation of the silicoaluminate form of the AEI zeolite structure as organic structure-directing agents (OSDAs).
Method for the direct synthesis of Cu-containing silicoaluminate material with the AEI zeolite structure, and the catalytic applications thereof
The main object of the present invention is to provide a new method for preparing the copper-containing silicoaluminate form of the AEI zeolite structure by means of a direct synthesis methodology. This new process involves combining a organometallic copper-complex with an additional organic molecule capable of directing the crystallisation of the silicoaluminate form of the AEI zeolite structure as organic structure-directing agents (OSDAs).
CATALYSTS AND PROCESSES FOR THE CONVERSION OF SYNTHESIS GAS TO LIQUEFIED PETROLEUM GAS (LPG) HYDROCARBONS
Liquefied petroleum gas (LPG) synthesis catalyst systems are disclosed that provide activities for both alcohol (e.g., methanol) synthesis and in situ dehydration of the alcohol (e.g., methanol) to hydrocarbons, and particularly the LPG hydrocarbons propane and/or butane. The incorporation of a stabilizer such as platinum and/or yttrium (e.g., as yttria or yttrium oxide) can benefit these catalyst systems, particularly in terms of improving their activity and/or stability. Other advantages may be realized by the incorporation of promoters such as manganese (Mn), magnesium (Mg), and/or silicon (Si) into these catalyst systems, such as to improve selectivity to, and/or yield of, desired LPG hydrocarbons.
PROCESS FOR PREPARING IRON(III)-EXCHANGED ZEOLITE COMPOSITION
The present disclosure relates to processes for formation of a molecular sieve, particularly a metal-promoted molecular sieve, and more particularly an Iron(III) exchanged zeolite. Preferably, the zeolite is of the chabazite form or similar structure. The processes can include combining a zeolite with Iron(III) cations in an aqueous medium. The process can be carried out at a pH of less than about 7, and a buffering material can be used with the aqueous medium. The processes beneficially result in Iron exchange that can approach 100% along with removal of cations (such as sodium, NH.sub.4, and H) from the zeolite. An Iron(III)-exchanged zeolite prepared according to the disclosed processes can include about 2,000 ppm or less of cation and about 1% by weight or greater of Iron(III). The disclosure also provides catalysts (e.g., SCR catalysts) and exhaust treatment systems including the Iron(III)-exchanged zeolite.
Hydrocarbon conversion catalyst composition
A hydrocarbon conversion catalyst composition which comprises dealuminated ZSM-48 and/or EU-2 zeolite and a refractory oxide binder essentially free of alumina, processes for preparing such composition and processes for converting hydrocarbon feedstock with the help of such compositions.
Zeolite synthesis with alkaline earth metal
Provided are a novel form of AFX zeolite, a novel synthesis technique for producing pure phase small pore zeolites, a novel synthesis method for producing a zeolite with an increased Al pair content, a catalyst comprising the AFX zeolite in combination with a metal, and methods of using the same.
Zeolite synthesis with alkaline earth metal
Provided are a novel form of AFX zeolite, a novel synthesis technique for producing pure phase small pore zeolites, a novel synthesis method for producing a zeolite with an increased Al pair content, a catalyst comprising the AFX zeolite in combination with a metal, and methods of using the same.