Patent classifications
B01J29/78
Dual functional composite catalyst for olefin metathesis and cracking
Composite catalysts includes zeolite particles at least partially embedded in a catalyst support material and at least one catalytically active compound deposited on the outer surfaces and pore surfaces of the catalyst support material, zeolite particles, or both. A method of making the composite catalysts may include preparing a catalyst precursor mixture that includes the zeolite, catalyst support material, triblock copolymer surfactant, and the catalytically active compound precursor and spray drying the catalyst precursor mixture. The composite catalysts may be used as a single catalyst for conducting olefin metathesis and cracking reactions. A method for producing propene may include contacting a butene-containing feed with the composite catalysts.
Dual functional composite catalyst for olefin metathesis and cracking
Composite catalysts includes zeolite particles at least partially embedded in a catalyst support material and at least one catalytically active compound deposited on the outer surfaces and pore surfaces of the catalyst support material, zeolite particles, or both. A method of making the composite catalysts may include preparing a catalyst precursor mixture that includes the zeolite, catalyst support material, triblock copolymer surfactant, and the catalytically active compound precursor and spray drying the catalyst precursor mixture. The composite catalysts may be used as a single catalyst for conducting olefin metathesis and cracking reactions. A method for producing propene may include contacting a butene-containing feed with the composite catalysts.
SUPPORTED CATALYST AND METHOD FOR PREPARING LIGHT OLEFIN USING DIRECT CONVERSION OF SYNGAS
A supported catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is a supported zeolite. A carrier is one or more than one of hierarchical pores Al.sub.2O.sub.3, SiO.sub.2, TiO.sub.2, ZrO.sub.2, CeO.sub.2, MgO and Ga.sub.2O.sub.3; the zeolite is one or more than one of CHA and AEI structures; and the load of the zeolite is 4%-45% wt. A weight ratio of the active ingredients in the component I to the component II is 0.1-20. The reaction process has an extremely high light olefin selectivity; the sum of the selectivity of the light olefin comprising ethylene, propylene and butylene can reach 50-90%, while the selectivity of a methane side product is less than 7%.
SUPPORTED CATALYST AND METHOD FOR PREPARING LIGHT OLEFIN USING DIRECT CONVERSION OF SYNGAS
A supported catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is a supported zeolite. A carrier is one or more than one of hierarchical pores Al.sub.2O.sub.3, SiO.sub.2, TiO.sub.2, ZrO.sub.2, CeO.sub.2, MgO and Ga.sub.2O.sub.3; the zeolite is one or more than one of CHA and AEI structures; and the load of the zeolite is 4%-45% wt. A weight ratio of the active ingredients in the component I to the component II is 0.1-20. The reaction process has an extremely high light olefin selectivity; the sum of the selectivity of the light olefin comprising ethylene, propylene and butylene can reach 50-90%, while the selectivity of a methane side product is less than 7%.
CATALYTIC COMPOSITION WITH ADDED COPPER TRAPPING COMPONENT FOR NOx ABATEMENT
The present disclosure provides catalyst compositions for NO.sub.x conversion and wall-flow filter substrates comprising such catalyst compositions. Certain catalyst compositions include a zeolite with sufficient Cu exchanged into cation sites thereof to give a Cu/Al ratio of 0.1 to 0.5 and a CuO loading of 1 to 15 wt. %; and a copper trapping component (e.g., alumina) including a plurality of particles having a D.sub.90 particle size of about 0.5 to 20 microns in a concentration of about 1 to 20 wt. %. The zeolite and copper trapping component can be in the same washcoat layer or can be in different washcoat layers (such that the copper trapping component serves as a “pre-coating” on the wall-flow filter substrate).
MFI TOPOLOGICAL STRUCTURE SILICON MOLECULAR SIEVE, PREPARATION METHOD THEREOF AND CATALYST CONTAINING THE SAME
The present disclosure discloses a MFI topological structure silicon molecular sieve, a preparation method thereof and a catalyst containing the MFI topological structure silicon molecular sieve, wherein the molecular sieve containing a silicon element, an oxygen element and a metallic element, the ions of said metallic element have a Lewis acid characteristic; the content of the metallic element in the molecular sieve is within a range of 5-100 μg/g based on the total amount of the molecular sieve; the BET specific surface area of the molecular sieve is within a range of 400-500 m.sup.2/g.
MFI TOPOLOGICAL STRUCTURE SILICON MOLECULAR SIEVE, PREPARATION METHOD THEREOF AND CATALYST CONTAINING THE SAME
The present disclosure discloses a MFI topological structure silicon molecular sieve, a preparation method thereof and a catalyst containing the MFI topological structure silicon molecular sieve, wherein the molecular sieve containing a silicon element, an oxygen element and a metallic element, the ions of said metallic element have a Lewis acid characteristic; the content of the metallic element in the molecular sieve is within a range of 5-100 μg/g based on the total amount of the molecular sieve; the BET specific surface area of the molecular sieve is within a range of 400-500 m.sup.2/g.
METHOD FOR MAKING FUNCTIONAL STRUCTURAL BODY
A method for making a functional structural body includes a skeletal body of a porous structure composed of a zeolite-type compound, and at least one type of metallic nanoparticles present in the skeletal body, the skeletal body having channels connecting with each other, the metallic nanoparticles being present at least in the channels of the skeletal body.
EXHAUST TREATMENT SYSTEM FOR DUAL FUEL ENGINES
Disclosed herein are emission treatment systems comprising an oxidation catalyst composition in fluid communication with an exhaust gas stream emitted from an engine that combusts both hydrocarbon fuel and hydrogen; and optionally, at least one selective catalytic reduction (SCR) composition and/or at least one three-way conversion (TWC) catalyst composition, combustion systems comprising the same, and method of treating an exhaust gas stream, such as, e.g., an exhaust gas produced by combusting hydrogen fuel during a cold-start period, using the same.
Structured catalyst for catalytic cracking or hydrodesulfurization, catalytic cracking apparatus and hydrodesulfurization apparatus including the structured catalyst, and method for producing structured catalyst for catalytic cracking or hydrodesulfurization
To provide a structured catalyst for catalytic cracking or hydrodesulfurization that suppresses decline in catalytic activity, achieves efficient catalytic cracking, and allows simple and stable obtaining of a substance to be modified. The structured catalyst for catalytic cracking or hydrodesulfurization (1) includes a support (10) of a porous structure composed of a zeolite-type compound and at least one type of metal oxide nanoparticles (20) present in the support (10), in which the support (10) has channels (11) that connect with each other, the metal oxide nanoparticles (20) are present at least in the channels (11) of the support (10), and the metal oxide nanoparticles (20) are composed of a material containing any one or two more of the oxides of Fe, Al, Zn, Zr, Cu, Co, Ni, Ce, Nb, Ti, Mo, V, Cr, Pd, and Ru.