B01J31/124

Olefin Coordination Polymerization Catalyst and Use Thereof

The present invention provides an olefin coordination polymerization catalyst and use thereof. The composition of the raw materials of the olefin coordination polymerization catalyst comprises: a main catalyst and a cocatalyst, wherein a molar ratio of the transition metal halide in the main catalyst to the cocatalyst is 1:10-500; and the composition of the raw materials of the main catalyst comprises a magnesium compound, a transition metal halide, an alcohol having 2 to 15 carbon atoms, and a star-shaped organosiloxane compound in a molar ratio of 1:1-40:0.01-10:0.001-10; and the cocatalyst comprises an organoaluminum compound. The above olefin coordination polymerization catalyst is used as a catalyst for ethylene polymerization, propylene polymerization, and copolymerization of ethylene or propylene with an -olefin. The olefin polymerization catalyst of the present invention has good catalytic activity.

RESIN COMPOSITION CONTAINING SUPPORTED PLATINUM CATALYST, THERMOSETTING ORGANOPOLYSILOXANE COMPOSITION USING THE RESIN COMPOSITION, AND METHOD FOR CURING THE THERMOSETTING ORGANOPOLYSILOXANE COMPOSITION

A resin composition includes: (a) a supported platinum catalyst having a structure shown by the following general formula (1) in which a platinum complex is supported on a surface of an inorganic oxide; and (b) a thermoplastic matrix resin. The resin composition is usable as an addition-reaction catalyst capable of imparting sufficient storability and quick curability to an addition-reaction curable composition.

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In the formula, L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound, and an isocyanide compound; and n represents the number of Ls and an integer from 0 to 2.

PERFLUORINATED AMIDE SALTS AND THEIR USES AS IONIC CONDUCTING MATERIALS

The invention concerns ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention is comprised of an amide or one of its salts, including an anionic portion combined with at least one cationic portion M.sup.+m in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO.sup.+, an ammonium NH.sub.4.sup.+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic portion matches the formula R.sub.FSO.sub.xN.sup.?Z, where R.sub.F is a perflourinated group, x is 1 or 3, and Z is an electroattractive substituent. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorants and the catalysis of various chemical reactions.

Process for Preparing 2,6-Substituted Phenols
20180305283 · 2018-10-25 ·

The present invention relates to a process for preparing 2,6-substituted phenols, and in particular to a process for preparing 2,6-diphenylphenol. This process is a doubling coupling of a boronic acid and a 2,6-dihalogenphenol in a Suzuki-Miyaura reaction on sterically hindered ortho positions. In a preferred embodiment, this process takes place in a continuous flow system. The present invention further relates to the composition obtained by this process, and to the use of this composition for preparing poly(2,6-diphenylphenylene oxide), for the manufacture of dyes, drugs, plastics, insulating materials and/or insecticides, and for use in medical applications and material research.

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METATITANIC ACID PARTICLE, COMPOSITION FOR FORMING PHOTOCATALYST, AND PHOTOCATALYST

A metatitanic acid particle includes a metal having a hydrocarbon group, which is bonded to a surface of the metatitanic acid particle through an oxygen atom, and absorbs light having a wavelength of 450 nm and light having a wavelength of 750 nm, wherein an element ratio C/Ti between carbon C and titanium Ti in a surface of the metatitanic acid particle is from 0.3 to 1.2, and a reduced amount of C/Ti on the surface of the metatitanic acid particle before and after irradiation with an ultraviolet ray having a wavelength of 352 nm and at an irradiation intensity of 1.3 mW/cm.sup.2 for 20 hours is from 0.1 to 0.9.

Stabilization of bulk catalysts with organo-metalloxane framework

Bulk metallic catalyst precursor compositions are provided that include a Group VIB metal, a Group VIII metal, an organic-compound based component, and an organo-metalloxane polymer or gel. The catalyst precursor compositions can further include a binder. Amorphous sulfided catalysts formed from the catalyst precursor compositions are also provided. The catalyst precursor compositions can have a surface area of about 20 m.sup.2/g or less.

STABILIZATION OF BULK CATALYSTS WITH ORGANO-METALLOXANE FRAMEWORK
20170080410 · 2017-03-23 ·

Bulk metallic catalyst precursor compositions are provided that include a Group VIB metal, a Group VIII metal, an organic-compound based component, and an organo-metalloxane polymer or gel. The catalyst precursor compositions can further include a binder. Amorphous sulfided catalysts formed from the catalyst precursor compositions are also provided. The catalyst precursor compositions can have a surface area of about 20 m.sup.2/g or less.

FLUORINE-CONTAINING TITANIUM OXIDE - NANO-SILICA COMPOSITE PARTICLES AND METHOD FOR PRODUCING THE SAME

Fluorine-containing titanium oxidenano-silica composite particles comprising a condensate of a fluorine-containing alcohol and an alkoxysilane, and titanium oxide and nano-silica particles, wherein the fluorine-containing alcohol is represented by the general formula:


R.sub.FAOH[I]

(wherein R.sub.F is a perfluoroalkyl group having 6 or less carbon atoms, or a polyfluoroalkyl group, in which some of the fluorine atom or atoms of the perfluoroalkyl group are replaced by a hydrogen atom or atoms, and which contains a terminal perfluoroalkyl group having 6 or less carbon atoms and a perfluoroalkylene group having 6 or less carbon atoms; and A is an alkylene group having 1 to 6 carbon atoms). The fluorine-containing titanium oxidenano-silica composite particles do not have difficulty in handling as with hydrogen fluoride, can be produced by using a fluorine-containing alcohol, which can be easily handled, and can produce a product capable of suppressing a decrease in the function of the titanium oxide as a photocatalyst even when subjected to a high-temperature heat treatment.

Composition for coating an overhead conductor
12565598 · 2026-03-03 · ·

A composition for coating an overhead conductor is disclosed comprising: (i) a reflective agent; (ii) a photocatalytic agent comprising 70 wt % anatase titanium dioxide (TiO.sub.2) having an average particle size (aps)100 nm; (iii) a polyorganosiloxane binder; and (iv) a superhydrophobic agent comprising either: surface functionalised silica nanoparticles, a functional polysiloxane or a polymethylsilsesquioxane.