An article including a metal substrate, an anti-coking catalyst layer and an alumina barrier layer disposed between the metal substrate and the anti-coking catalyst layer is provided. A process for making the article is also provided.

Embodiments relate to a cerium-containing nano-coating composition, the composition including an amorphous matrix including one or more of cerium oxide, cerium hydroxide, and cerium phosphate; and crystalline regions including one or more of crystalline cerium oxide, crystalline cerium hydroxide, and crystalline cerium phosphate. The diameter of each crystalline region is less than about 50 nanometers.

Embodiments relate to a cerium-containing nano-coating composition, the composition including an amorphous matrix including one or more of cerium oxide, cerium hydroxide, and cerium phosphate; and crystalline regions including one or more of crystalline cerium oxide, crystalline cerium hydroxide, and crystalline cerium phosphate. The diameter of each crystalline region is less than about 50 nanometers.

The present invention relates to a catalytically active material, the preparation thereof, and the use of the catalytically active material, e.g. in the catalytic oxidation of CO to CO.sub.2 or in the catalytic hydrogenation of alkyne. The catalytically active material comprises a support5 comprising a metal oxide, and atomically dispersed noble metal on the surface of the support, wherein the metal oxide is selected from TiO.sub.2, CeO.sub.2, ZnO, SnO.sub.2, Ga.sub.2O.sub.3, In.sub.2O.sub.3, ZrO.sub.2, and Fe.sub.2O.sub.3, the noble metal is selected from Pt, Pd, Rh, and Au, and the catalytically active material is obtainable by a method comprising a step of non-thermal plasma treatment in the presence of O.sub.2.

Provided is a method for manufacturing a titania coated alumina fiber aggregate which includes the steps of: forming an aluminum fiber aggregate where aluminum fibers are aggregated with density per unit volume of 0.5 g/cm.sup.3 to 3 g/cm.sup.3; forming an alumina fiber aggregate where an oxide film having a film thickness of 50 nm or more is formed on alumina fibers; and forming a titania coated alumina fiber aggregate where a titania thin film is formed on alumina fibers.

Provided is a method of producing a catalyst or adsorbent carrier and a catalyst or adsorbent carrier which can enhance a catalyst or adsorbent function, and prevent fall-off of catalyst particles or adsorbent particles. The surface of a metal base material made of aluminum or an aluminum alloy is subjected to an etching process using an etchant containing iron chloride and an oxide to convert the surface to an uneven and rough surface. The uneven and rough surface of the metal base material is subjected to an anodizing process to form a porous coating along the uneven and rough surface. A large number of catalyst or adsorbent particles are thus carried on the surface of the metal base material on which the porous coating is formed along the uneven and rough surface.

The present invention relates to a method for producing supported catalysts, comprising: providing a metal foam element A, which consists of metallic cobalt, an alloy of nickel and cobalt, or an arrangement of layers of nickel and cobalt, lying one over the other; applying an aluminum-containing powder MP to metal foam element A in order to obtain metal foam element AX; thermally treating metal foam element AX to achieve alloy formation between metal foam element A and aluminum-containing powder MP, in order to obtain metal foam element B; oxidatively treating metal foam element B, in order to obtain metal foam element C; and applying a catalytically active layer, comprising at least one support oxide and at least one catalytically active component, to at least part of the surface of metal foam element C, in order to obtain a supported catalyst. The present invention further relates to the supported catalysts that can be obtained using the method and to the use of said supported catalysts in chemical transformations.

Described are a catalyst, a honeycomb-type catalyst body for decomposing perfluorocompounds (PFCs), and a method of preparing the same. The described catalyst for decomposing PFCs and the method of preparing the same are as follows. Zinc as an active component for performance improvement and tungsten (W) as an auxiliary component are added to alumina selected from at least one of gamma alumina, aluminum trihydroxide, boehmite, and pseudo-boehmite, and a weight ratio of Al, Zn, and W is at 100:30 to 100:1 to 11. The catalyst for decomposing PFCs not only has an effect of having durability against fluorine generated by decomposition of PFCs but also has a synergistic effect of improving reaction activity. Furthermore, the catalyst decomposes PFCs at a lower temperature than conventional catalysts for decomposing PFCs. Thus, it is possible to reduce operating costs and secure the durability of the system during continuous operation.

The invention relates to methods for producing supported catalysts, comprising: providing a metal foam element A made of nickel; applying an aluminum-containing powder MP to metal foam element A, such that metal foam element AX is obtained; thermally treating metal foam element AX in order to form an alloy between metal foam element A and the aluminum-containing powder MP, such that metal foam element B is obtained; oxidatively treating metal foam element B, such that metal foam element C is obtained; and applying a catalytically active layer, comprising at least one carrier oxide and at least one catalytically active component, to at least one part of the surface of metal foam element C, such that a supported catalyst is obtained. The invention also relates to the supported catalysts obtained according to the method, and to the use thereof in chemical transformations.