A method for enhancing degradation of ester volatile organic compounds with a cerium oxide supported palladium single atom catalyst under low-temperature microwave comprises the steps of firstly preparing a single atom catalyst Pd/CeO.sub.2, adding the catalyst Pd/CeO.sub.2 into a reaction cavity, initiating microwave radiation to enhance the catalysis reaction, and quickly introducing an ester compound with a concentration of 505000 mg/m.sup.3 and a space velocity of 2000100000 h.sup.1 into the reaction cavity from a vapor phase sampling port to react when the reaction temperature is 1080 C. A catalyst packed column is provided in the reaction cavity, the vapor phase sampling port is defined at the bottom of the reaction cavity, and an exhaust port is defined at the top of the cavity. The microwave method can enhance and activate active sites, prevent the aging of active sites, and enable the chemical reaction rate to be increased by more than 17.9%.

A method for the preparation of a catalyzed monolithic body or a catalyzed particular filter. The method includes the step of suctioning a sol-solution containing catalytically active material and metal oxide catalyst carriers or precursors thereof into pores of a monolithic substrate, solely by capillary forces and without the application of vacuum or pressure.

In one aspect, disclosed herein are devices comprising a disclosed hybrid microwave-thermal chemical reactor device. Also disclosed herein are methods of preparing hydrogen and a crystalline carbon material, such as a carbon nanotube, from methane using a hybrid heating comprising heating with both a thermal fluid and microwave irradiation of a catalyst. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

The present invention combines the advantages of fabrication of semiconductor heterostructure (Ag.sub.3PO.sub.4WO.sub.3) with plasmonic metals (Pt and Ag) with optical interference to optimize the visible light photo response of plasmonic metals deposited semiconductor (PtAg/Ag.sub.3PO.sub.4WO.sub.3) for visible light assisted H.sub.2 generation utilizing the aqueous bio-alcohols. Crystalline Ag.sub.3PO.sub.4 and WO.sub.3 nanofibers were synthesized by microwave and electrospinning methods. Three different WO.sub.3 nanofibers composition (5, 10 and 15 wt. %) were used to obtain Ag.sub.3PO.sub.4/WO.sub.3 nanocomposite heterostructures, which are effective visible light active photo catalysts. Further, a simple, enviro-friendly, and cost-effective biogenic synthesis method have been achieved using Salvia officinalis extract to decorate Pt and Ag metal nanoparticles on the surface of Ag.sub.3PO.sub.4WO.sub.3 composites. Presence of bioactive agents in the extract are responsible for the Pt and Ag.sub.3PO.sub.4 reduction and for prevention of the Pt nanoparticles from aggregation in aqueous medium.

In one aspect, disclosed herein are devices comprising a disclosed hybrid microwave-thermal chemical reactor device. Also disclosed herein are methods of preparing hydrogen and a crystalline carbon material, such as a carbon nanotube, from methane using a hybrid heating comprising heating with both a thermal fluid and microwave irradiation of a catalyst. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

The present invention combines the advantages of fabrication of semiconductor heterostructure (Ag.sub.3PO.sub.4WO.sub.3) with plasmonic metals (Pt and Ag) with optical interference to optimize the visible light photo response of plasmonic metals deposited semiconductor (PtAg/Ag.sub.3PO.sub.4WO.sub.3) for visible light assisted H.sub.2 generation utilizing the aqueous bio-alcohols. Crystalline Ag.sub.3PO.sub.4 and WO.sub.3 nanofibers were synthesized by microwave and electrospinning methods. Three different WO.sub.3 nanofibers composition (5, 10 and 15 wt. %) were used to obtain Ag.sub.3PO.sub.4/WO.sub.3 nanocomposite heterostructures, which are effective visible light active photo catalysts. Further, a simple, enviro-friendly, and cost-effective biogenic synthesis method have been achieved using Salvia officinalis extract to decorate Pt and Ag metal nanoparticles on the surface of Ag.sub.3PO.sub.4WO.sub.3 composites. Presence of bioactive agents in the extract are responsible for the Pt and Ag.sub.3PO.sub.4 reduction and for prevention of the Pt nanoparticles from aggregation in aqueous medium.

The invention relates to the field of oligomerization of olefins to produce linear -olefins, in particular hexene-1, with the use of a catalyst system. The catalyst system comprises a chromium source compound, a nitrogen-containing ligand, alkylaluminum, and a zinc compound, wherein catalyst system is activated during its preparation by 1) heating some and SHF irradiation (microwave irradiation) of alkylaluminum or a mixture of the alkylaluminum and the zinc compound, or by 2) heating alkylaluminum or a mixture of the alkylaluminum and the zinc compound, followed by holding (aging) the prepared catalyst system for a certain period of time.

The present invention relates to a catalyst for aromatization of alkanes having 4 to 7 carbon atoms, especially alkanes having carbon atoms. Said catalyst has the efficacy in the aromatics production with high conversion and high selectivity of aromatics or high yield of aromatics, wherein said catalyst comprises zeolite, at least 1 transition metal from group VIII transition metal in a range of 0.1 to 2% by weight based on the total weight of the catalyst, and at least 1 metal from group IIIA metal in a range of 0.1 to 5% by weight based on the total weight of the catalyst. Said catalyst is treated and dried with a microwave at a power in a range from 400 to 1,000 watts after step of contacting with a solution comprising at least 1 transition metal salt from group VIII transition metal and after step of contacting with a solution comprising at least 1 group IIIA metal salt. Moreover, this invention also relates to a process for preparing said catalyst and a process of aromatics preparation using said catalyst.

The present invention discloses a palladium oxide catalyst for a direct formic acid fuel cell and a preparation method thereof The preparation method is as follows: dissolving a palladium chloride to prepare an aqueous solution, adding a sodium citrate or a potassium citrate, adjusting the solution to a pH value ranging from 9 to 13; then, placing the above solution in a microwave reactor for microwave reaction for 3 minutes to 30 minutes, and refluxing and magnetically stirring simultaneously during the reaction to obtain a palladium oxide collid solution; after the palladium oxide colloid is cooled, adding a commercial carbon powder or a carbon nanotube to collect the palladium oxide; and performing suction filtration finally, washing a filter cake, drying the filter cake under vacuum, and grounding the filter cake to obtain a carbon-supported palladium oxide catalyst.

A method of making a titanium dioxide nanowire array includes contacting a substrate with a solvent comprising a titanium (III) precursor, an acid, and an oxidant while microwave heating the solvent, thereby forming a hydrogen titanate H2Ti2O5.H2O nanowire array. The hydrogen titanate nanowire array is annealed to form a titanium dioxide nanowire array. The substrate is seeded with titanium dioxide before starting the hydrothermal synthesis of the hydrogen titanate nanowire array. The titanium dioxide nanowire array is loaded with a platinum group metal to form an exhaust gas catalyst. The titanium dioxide nanowire array can be used to catalyze oxidation of combustion exhaust.