A hierarchical catalyst composition comprising a continuous or particulate macroporous scaffold in which is incorporated mesoporous aggregates of magnetic nanoparticles, wherein an enzyme is embedded in mesopores of the mesoporous aggregates of magnetic nanoparticles. Methods for synthesizing the hierarchical catalyst composition are also described. Also described are processes that use the recoverable hierarchical catalyst composition for depolymerizing lignin, remediation of water contaminated with aromatic substances, polymerizing monomers by a free-radical mechanism, epoxidation of alkenes, halogenation of phenols, inhibiting growth and function of microorganisms in a solution, and carbon dioxide conversion to methanol. Further described are methods for increasing the space time yield and/or total turnover number of a liquid-phase chemical reaction that includes magnetic particles to facilitate the chemical reaction, the method comprising subjecting the chemical reaction to a plurality of magnetic fields of selected magnetic strength, relative position in the chemical reaction, and relative motion.

Methods and apparatus are disclosed for generating an electromagnetic field inside a reactor to trigger an exothermic reaction. The design and implementation of the electromagnetics are based on the requirements of a particular exothermic reaction or reactor. For example, the triggering mechanism of a particular exothermic reaction or reactor may require a magnetic field with a specific magnitude, polarity, and/or orientation.

An improved system for generating graphene involves a liquid reaction chamber configured to receive a working liquid source, a carbon atom source, and a catalyst to cause a chemical reaction in the reaction chamber and a resulting reactant liquid comprising ring structures having starved carbon atoms. The ring structures are provided to a graphene generation chamber having a magnetic structure that includes a two-dimensional array of alternating polarity magnetic sources that produce a magnetic field having a gradient sufficient to float graphene over the magnetic structure. The graphene generation chamber generates graphene from said ring structures over the magnetic structure such that the graphene floats over the magnetic structure due to said graphene being diamagnetic. The rate at which the ring structures are produced is controlled to control the rate of graphene generation. The magnetic field of the magnetic structure can be controlled to control the rate at which the generated graphene moves through the graphene generation chamber until it exits as a recovered graphene product.

Methods and apparatus are disclosed for generating an electromagnetic field inside a reactor to trigger an exothermic reaction. The design and implementation of the electromagnetics are based on the requirements of a particular exothermic reaction or reactor. For example, the triggering mechanism of a particular exothermic reaction or reactor may require a magnetic field with a specific magnitude, polarity, and/or orientation.

Disclosed herein is a rotary tube furnace configured to facilitate a chemical reaction between a solid mass and a gas in the furnace. The rotary tube furnace may comprise a reaction chamber extending through the furnace, the reaction chamber configured to control ingress and egress of each of the solid mass and the gas in the reaction chamber; a passage way configured to supply the solid mass to the reaction chamber; a passage way configured to supply the gas to the reaction chamber and circulate the gas through the reaction chamber; a heater providing heat to the reaction chamber and configured to control a reaction temperature in the reaction chamber; a magnetic field source in proximity to the reaction chamber for generating a magnetic field to one or more reaction zones of the reaction chamber; wherein the reaction chamber provides for mixing the solid mass and the gas.