The present invention discloses high pressure flow reactor vessels and associated systems. Also disclosed are processes for producing thiol compounds and sulfide compounds utilizing these flow reactor vessels.

A system for utilizing solar power to generate carbon nano-materials. A system for utilizing the carbon dioxide byproduct of a fossil fuel power generation process to drive an electrolysis reaction which produces carbon nano-materials, and methods of producing the same.

An apparatus for synergistically combining a plasma with a comminution means such as a fluid kinetic energy mill (jet mill), preferably in a single reactor and/or in a single process step is provided by the present invention. Within the apparatus of the invention potential energy is converted into kinetic energy and subsequently into angular momentum by means of wave energy, for comminuting, reacting and separation of feed materials. Methods of use of the apparatus in the practice of various processes are also provided by the present invention.

The present disclosure relates to a particle including at least one atomic-scale channel formed on a surface of the particle or on a surface and inside of the particle; a catalyst including the particle, particularly a catalyst for efficient and selective electrochemical conversion of carbon dioxide into high value-added C.sub.2+ fuel; and a method of preparing the particle.

Provided herein are a symmetrical pincer metal and bimetallic complexes. The symmetrical pincer metal complex includes a structure according to Formula I:

##STR00001##

wherein M is a metal; each N and N is independently nitrogen or carbon; Z is selected from the group consisting of CH, C, and N; n is 0-3; each L is independently a neutral or charged ligand; and each R is independently an alkyl, Nx, CH.sub.2TMS. The symmetrical bimetallic complex includes a structure according to Formula II:

##STR00002##

wherein M is a metal; each N and N is independently nitrogen or carbon; Z is selected from the group consisting of CH, C, and N; n is 0-3; each L is independently a neutral or charged ligand; and wherein each R is independently an alkyl, Nx, CH.sub.2TMS. Also provided herein is a method of catalyzing a reaction including administering one or more of the compounds disclosed herein.

The present invention relates to a microfluidic or millifluidic device (1) comprising: a support (2) made at least partially of a dielectric material, the support (2) comprising a first inlet (21a) adapted to be connected to a first reservoir containing gas, a second inlet (21b) adapted to be connected to a second reservoir containing liquid, an outlet (22) adapted to be connected to a receiver container containing gas and/or liquid, and a main microchannel or millichannel (3) present in the dielectric material allowing the liquid and the gas to flow from the inlets towards the outlet, one or several ground electrode(s) (4) embedded in said dielectric material and extending along the main microchannel or millichannel (3), and one or several high-voltage electrode(s) (5) embedded fi in said dielectric material and extending along the main microchannel or millichannel (3), wherein the high-voltage electrode(s) (5) and the ground electrode(s) (4) are located on opposite sides of the main microchannel or millichannel (3) so as to be able to generate an electric field inside the main microchannel or millichannel (3). The present invention relates also to a method for generating a plasma in a continuous manner using such a microfluidic or millifluidic device (1).

A plasma reactor comprises a housing, a first fluid inlet, a second fluid inlet, a first electric field generator, and an effluent outlet. The housing includes an axial aligned passageway and an internal reactor chamber coupled with the passageway. The first fluid inlet receives and delivers a first fluid to the reactor chamber. The second fluid inlet receives and delivers a second fluid to the reactor chamber. The first electric field generator is positioned in the reactor chamber and includes a first electrode and a spaced apart second electrode. The first electric field generator generates a first electric field, wherein the first fluid passes through the first electric field creating a plasma which is injected into the second fluid while the second fluid is flowing through the passageway to create an effluent. The effluent outlet receives the effluent from the reactor chamber and delivers it to a destination.

Removing GHGs from various industrial and agricultural sources while concurrently generating useful solid and/or gaseous output materials enables an environmentally-clean and scalable approach for permanently dissociating the GHGs. Intra-reactor conditions can be controlled such that the solids produced are useful in advanced materials (e.g., in carbon fibers, in cements and concretes, etc.), and/or controlled in a manner such that the generated gases are useful (e.g., as fuel in hydrogen powered vehicles, in aeronautical and aerospace applications, and in energy storage applications, etc.). Eradicating GHGs (i.e., by dissociating GHGs into constituent carbon, hydrogen, oxygen, sulfur, nitrogen, etc.) is facilitated through use of interconnected arc discharge reactors. Arc discharge reactors involve simple designs that are both energy efficient and highly scalable to virtually any specification. Moreover, the simplicity of arc discharge reactor designs lead to large scale configurations that can be reliably deployed into diverse geographies or environments having diverse operating conditions.

A system and method for performing plasma reactions creating a plasma area in a gas adjacent to a liquid. An embodiment of the plasma reactor includes a housing with an internal reaction chamber, first and second inlet paths to the reaction chamber, and electrodes for producing an electric field. The system may optionally further include a pre-ionization electrode and pre-ionization electric field for pre-ionizing a feed gas prior to entry into a reaction chamber. The reactor uses plasma to ionize gas adjacent with the liquid. The ionized gas reacts with the liquid to form an effluent. Exemplary uses of the plasma reactor include ionic injection, gas dissociation, liquid re-formation, and liquid dissociation.

A treatment liquid production device includes a first tank; a first plasma generating device that includes a first pair of electrodes and a first power supply, the first power supply applying a voltage between the first pair of electrodes, the first plasma generating device generating plasma in a liquid in the first tank; a second tank; a second plasma generating device that includes a second pair of electrodes and a second power supply, the second power supply applying a voltage between the second pair of electrodes, the second plasma generating device generating plasma in a liquid in the second tank; and a controller operative to produce a first treatment liquid having a high initial oxidizing power during a first period and a second treatment liquid having a high remaining oxidizing power during a second period which is longer than the first period.