A Bayer process increases oxalate removal in the red side of the Bayer process and at least substantially minimises, for example by at least substantially suppressing, precipitation of oxalates in the white side of the Bayer process.

A process for the preparation from a partially decomposed organic material like peat a granulated or pelletized sorption medium using low-temperature, thermal activation of the sorption medium to produce a high degree of granule or pellet hardness balanced against an efficacious level of ion-exchange and adsorption capacity, followed by chemical treatment of the thermally-activated sorption material via an acid solution and a salt solution to increase its ion-exchange and adsorption performance while minimizing the transfer of natural impurities found in the sorption medium to an aqueous solution is provided by this invention. The sorption medium of this invention can be used in a variety of aqueous solution treatment processes, such as wastewater treatment.

The disclosure describes a pelletized sorbent comprising a first component comprising Basic Immobilized Amine Sorbent, a second component comprising inorganic strength additive, and a third component comprising polymer binder, where the Basic Immobilized Amine Sorbent and solid inorganic strength additive are interconnected by the polymer binder. The pelletized sorbent is useful for removing CO.sub.2 from a gaseous mixture such as a post combustion gas stream.

Proposed are a method of preparing a cesium adsorbent and a cesium adsorbent prepared thereby. The method includes (a) preparing a powder mixture of coal mine drainage sludge (CMDS) powder, sodium hydroxide (NaOH) powder, and sulfur (S) powder and (b) heat-treating the powder mixture to prepare a cesium adsorbent. The cesium adsorbent increases the active ion exchange of Na and Cs and the bonding of SCs when adsorbing cesium ions, resulting in an average of 5 times higher Cs removal efficiency and adsorption capacity under various conditions compared to CMDS since CMDS relies on cesium adsorption by simple physical and electrostatic attraction. Moreover, the cesium adsorbent is eco-friendly and has excellent economic efficiency by utilizing waste CMDS.

A functional ceramic material made from a raw material mixture which includes 0.1-0.5 wt % iron powder, 20-25 wt % bentonite, and a remainder of sludge (based on dry weight) which contains bacteria. To make the functional ceramic material, the raw material mixture is calcined at low temperature and anaerobic conditions. Use of the material for purifying a medium is also provided.

Systems and methods for treating a fluid with a body are disclosed. Various aspects involve treating a fluid with a porous body. In select embodiments, a body comprises ash particles, and the ash particles used to form the body may be selected based on their providing one or more desired properties for a given treatment. Various bodies provide for the reaction and/or removal of a substance in a fluid, often using a porous body comprised of ash particles. Computer-operable methods for matching a source material to an application are disclosed. Certain aspects feature a porous body comprised of ash particles, the ash particles have a particle size distribution and interparticle connectivity that creates a plurality of pores having a pore size distribution and pore connectivity, and the pore size distribution and pore connectivity are such that a first fluid may substantially penetrate the pores.

A process for the preparation from a partially decomposed organic material like peat a granulated or pelletized sorption medium using low-temperature, thermal activation of the sorption medium to produce a high degree of granule or pellet hardness balanced against an efficacious level of ion-exchange and adsorption capacity, followed by chemical treatment of the thermally-activated sorption material via an acid solution and a salt solution to increase its ion-exchange and adsorption performance while minimizing the transfer of natural impurities found in the sorption medium to an aqueous solution is provided by this invention. The sorption medium of this invention can be used in a variety of aqueous solution treatment processes, such as wastewater treatment.

The present invention relates to a method for preparing a solid amine gas adsorption material. The method synthesizes a porous solid amine gas adsorption material that loads organic amine evenly. In the method, a certain amount of acidic gas is introduced while organic amine molecules are introduced into a silicate solution as template agents, which not only makes sizes of SiO.sub.2 pore channels homogeneous, but also makes organic amine molecules highly evenly distributed on a surface of SiO.sub.2. In addition, the acidic gas protects NH.sub.2 groups of organic amine, and avoids NH.sub.2 adhesion inactivation due to hydrogen bonding during the synthesis process of the material. The present invention also relates to a method for preparing a solid amine gas adsorption material after obtaining a silicate solution from fly ash. The solid amine gas adsorption material prepared has more stable and effective gas adsorption performance.

A process for the preparation from a partially decomposed organic material like peat a granulated or pelletized sorption medium using low-temperature, thermal activation of the sorption medium to produce a high degree of granule or pellet hardness balanced against an efficacious level of ion-exchange and adsorption capacity, followed by chemical treatment of the thermally-activated sorption material via an acid solution and a salt solution to increase its ion-exchange and adsorption performance while minimizing the transfer of natural impurities found in the sorption medium to an aqueous solution is provided by this invention. The sorption medium of this invention can be used in a variety of aqueous solution treatment processes, such as wastewater treatment.

The present invention relates in general to a process for removing mercury from a mercury-containing flue gas using dregs from a Kraft pulp mill green liquor clarifier. The dregs are washed with water to produce a particulate carbon slurry which is activated with hydrobromic acid and injected into a mercury-containing flue gas to oxidize and adsorb the mercury at temperatures less than about 900 F. A slurry of sodium hydroxide and calcium carbonate, optionally also obtained from Kraft mill waste, is injected into the hot flue gas to absorb and remove CO.sub.2, SO.sub.2, and SO.sub.3.