A method is used to provide an electrically-conductive polyaniline pattern by providing a uniform layer of a photocurable composition on a substrate. The photocurable composition comprises a water-soluble reactive polymer comprising (a) greater than 40 mol % of recurring units comprising sulfonic acid or sulfonate groups, and (b) at least 5 mol % of recurring units comprising a pendant group capable of crosslinking via [2+2] photocycloaddition. The photocurable composition is exposed to cause crosslinking via [2+2] photocycloaddition of the (b) recurring units, thereby forming a crosslinked polymer. Any remaining water-soluble reactive polymer is removed. The crosslinked polymer is contacted with an aniline reactive composition having aniline monomer and up to 0.5 molar of an aniline oxidizing agent, thereby forming an electrically-conductive polyaniline disposed either within, on top of, or both within and on top of, the crosslinked polymer.

The attachment and proliferation of antibiotic resistant, biofilm-forming bacteria to oft-handled material surfaces has emerged as a growing concern, particularly in the biomedical, healthcare and food packaging industries. UV-curable phosphoniums bearing benzophenone anchors have been synthesized with a variety of alkyl, aryl, and fluoroalkyl functional groups at phosphorus to probe their efficacy as thermally stable antimicrobial additives in plastics or as surface coatings. In an embodiment, a phosphonium compound having the following formula has been synthesized:

##STR00001##

in which R is a phosphine group substituted with alkyl, aryl, substituted alkyl, substituted aryl, heteroalkyl or any combination thereof. These materials maintained the ability to kill biofilm-forming bacteria even after being subject to abrasion processes, demonstrating the potential to serve as long-term antimicrobial materials.

A free radical curable liquid for inkjet printing of food packaging materials includes no initiator or otherwise one or more initiators selected from the group consisting of non-polymeric di- or multifunctional initiators, oligomeric initiators, polymeric initiators, and polymerizable initiators; wherein the polymerizable composition of the liquid consists of: a) 25-100 wt % of one or more polymerizable compounds A having at least one acrylate group G1 and at least one second ethylenically unsaturated polymerizable functional group G2 different from the group G1; b) 0-55 wt % of one or more polymerizable compounds B selected from the group consisting of monofunctional acrylates and difunctional acrylates; and c) 0-55 wt % of one or more polymerizable compounds C selected from the group consisting of trifunctional acrylates, tetrafunctional acrylates, pentafunctional acrylates and hexafunctional acrylates.

The present invention is directed to an ultraviolet curing ink jet ink composition which contains at least a polymerizable compound and a photopolymerization initiator, and is free from an aqueous solvent. The polymerizable compound comprises at least a urethane oligomer, and the photopolymerization initiator comprises an acylphosphineoxide and α-hydroxyketone. The polymerizable compound further comprises an allyl compound and/or an N-vinyl compound.

A method for coating a building panel, including applying a first coating fluid including an organic binder on a surface of the building panel to obtain at least one coating layer, and applying barrier components and photocatalytic particles, preferably TiO.sub.2, on the at least one coating layer. Also, a building panel formed by the method.

Urethane (multi)-(meth)acrylate (multi)-silane compositions, and articles including a (co)polymer reaction product of at least one urethane (multi)-(meth)acrylate (multi)-silane precursor compound. The disclosure also articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urethane (multi) (meth)acrylate (multi)-silane precursor compound. The substrate may be a (co)polymeric film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making urethane (multi)-(meth)acrylate (multi)-silane precursor compounds and their use in composite multilayer barrier films are also described. Methods of using such barrier films in articles selected from a solid state lighting device, a display device, and combinations thereof, are also described.

UV curable coatings containing dual phase filler-polymer compositions with high resistivity, low dielectric constant, good optical density, and controlled electrical resistivity are described, and cured coatings or films formed thereof, along with their use in black matrix, black column spacers, and other light shielding coating elements in LCD. Devices having these black matrices, black column spacers, and/or other light shielding coating elements, and methods of preparing and making these various materials and products are also described.

The present invention relates to a UV coating layer hardening device for hardening of a coating in a repair workshop for an automobile by means of UV radiation suitable for irradiating of a coating layer to be hardened that is applied to a surface of the automobile, including: a number of bearer elements for bearing of a number of LED based UV radiation sources, optics per radiation source for spreading of the UV radiation at a predetermined manner under an irradiation angle, the number of UV radiation sources in cooperation with the respective optics per radiation source are arranged in such a manner that a predetermined area of the surface is arrangeable with an intensity or intensity per time period with a predetermined minimum and a predetermined maximum, in which the minimum provides a predetermined degree of hardening and in which the maximum does not exceed a certain threshold.

There is provided a composition for forming a hard coat layer which has high slippage and is excellent in water/oil repellency and also has antifouling properties such as fingerprint resistance and dirt wiping-off properties, and which is curable through ultraviolet irradiation in a nitrogen atmosphere or an air atmosphere that is generally used. A silicon-containing highly branched polymer obtained by polymerization of a monomer A having two or more radically polymerizable double bonds in a molecule and a monomer B having a polysiloxane chain and at least one radically polymerizable double bond in a molecule in the presence of a polymerization initiator D in an amount of 5 to 200% by mole relative to the number of moles of the monomer A; a curable composition including the highly branched polymer; a cured film obtained from the composition; and a hard coat film obtained by use of the composition.

Described herein are inks and coating compositions comprising semiconductor metal oxides and composites thereof, which are natural environmentally sustainable materials that may be recycled and/or reused indefinitely. Semiconductor metal oxides offer an alternative to relatively more toxic, non-sustainable, photo and heat-degrading, migrating traditional photoinitiator agents used in actinic radiation curable compositions. The semiconductor metal oxides and composites thereof absorb visible or UV-light as photocatalysts and/or semiconductors, or absorb electron beam radiation, forming radicals for radical events as polymerization reactions and color enhancement events.