A matte clear coating composition for an aluminum member, comprising acrylic resin (A) having a hydroxy value of 100 to 200 mgKOH/g; melamine resin (B); silica particles (C) having an average particle size of 1.0 to 15 m; and polyolefin wax (D) having an average particle size of 10 to 40 m and a melting point of 145 C. to 180 C., the matte clear coating composition comprising 5 to 20 mass % of silica particles (C) and 3 to 15 mass % of polyolefin wax (D) based on the total solids content of acrylic resin (A) and melamine resin (B). The matte clear coating composition for an aluminum member satisfies both corrosion resistance and abrasion resistance (scratch resistance).

The present invention relates to a process for applying a topcoat to at least one side of a substrate, comprising a step (a) of at least partly coating at least one substrate metal surface, at least partly coated with at least one primer coat, with an aqueous coating composition which comprises at least one polymer dissolved or dispersed therein, the coating composition further comprising at least one mixed hydroxide of the general formula (I), and the process being a coil coating process; to a topcoat applied to at least one side of the substrate and obtainable by this process; to a substrate at least partly coated on at least one side with a topcoat by this process; and also to a use of this coating composition for at least partly coating at least one substrate metal surface, at least partly coated with at least one primer coat, with a topcoat in a coil coating process.

A curable film-forming composition is provided, comprising: (a) a polymeric polyester binder comprising a plurality of carbamate groups; (b) a curing agent reactive with the carbamate functional groups of (a); and (c) a reaction product of: (1) a hydroxyl functional polymer comprising the reaction product of: (i) a monomer comprising at least two ethylenically unsaturated double bonds; (ii) a monomer comprising a carbon atom that is bonded to four moieties wherein one of the moieties is a hydrogen atom and the remainder of the moieties comprises an alkyl group, wherein at least one of the alkyl group-containing moieties comprises an ethylenically unsaturated double bond; and (iii) at least one monomer that is polymerizable with (i) and (ii); and (2) a lactone or lactam. Also provided are a multi-component composite coating composition that includes the curable film-forming composition described above and methods for forming a composite coating on a substrate.

A coating method for forming a laminated coating film including a lower layer formed on a base material and an upper layer formed on the lower layer including: preparing a thermosetting coating material as a lower layer-coating material and preparing a thermosetting coating material as an upper layer-coating material; forming an uncured laminated coating film by applying the lower layer-coating material and the upper layer-coating material on the base material using a wet-on-wet technique; and simultaneously curing the lower layer-coating material and the upper layer-coating material by baking the uncured laminated coating film. In the preparation step, the lower layer-coating material and the upper layer-coating material are selected so that an absolute value of a difference in shrinkage ratio between the lower layer and the upper layer coating materials is 2.0% or smaller at a late stage of the baking step.

A coating composition includes a flexible hyperbranched polyol preparable by (a) reacting a polyol comprising at least three hydroxyl groups with an aliphatic dicarboxylic acid having from 6 to 36 carbon atoms or an esterifiable derivative of the aliphatic dicarboxylic acid to form a hydroxyl-functional first intermediate product; (b) reacting the first intermediate product with a cyclic carboxylic acid anhydride to form a carboxylic acid-functional second intermediate product; and (c) reacting the second intermediate product with an epoxide-functional compound having one epoxide group to form the hyperbranched polyol. The coating composition may be cured to a coating layer having excellent flexibility.

Provided is a coating composition containing: a hydroxyl group-containing resin (A), a curing agent (B), and cellulose nanocrystal particles (C), where a viscosity (V.sub.1) measured under conditions of a temperature of 25 C. and a shear rate of 1500 sec.sup.1 is in a range from 10 to 70 mPa.Math.s, and a viscosity (V.sub.2) measured under conditions of a temperature of 25 C. and a shear rate of 0.1 sec.sup.1 is in a range from 10000 to 50000 mPa.Math.s.

Disclosed herein is a tinted clearcoat composition including at least one binder resin (A) having functional groups (i), at least one curing agent (B) having functional groups (ii) being reactive with the functional groups (i), and at least one pigment (C), where the tinted clearcoat composition (TCC) is produced by (a) providing a clearcoat system (CS) including at least one binder resin (A) and at least one curing agent (B), (b) providing at least one pigment premixture (PP) including at least one pigment (C), (c) combining all or part of the clearcoat system (CS) with at least one pigment premixture (PP), (d) milling the mixture obtained in step (c), and (e) mixing, if applicable, the mixture obtained in step (d) with any yet missing parts of the tinted clearcoat composition (TCC).

The present invention provides a coloring base coating material capable of forming a base coating film superior in design property (e.g., unevenness of a luster pigment), adhesion, and water resistance while satisfying environmental considerations such as shortening of drying time, and also provides a coated article obtained from the coloring base coating material. The present invention provides a coating method including: a step of applying a coloring base coating material to a molded article for an automobile part made of a plastic material to form an uncured first coating film, a step of applying a two-pack clear coating material to the uncured first coating film to form an uncured second coating film, and a step of baking and curing the uncured first coating film and the uncured second coating film to form a multilayer coating film, wherein the coloring base coating material is specified.

A method and related apparatus for generating a surface structure includes the steps of: (A) applying a resin A on the surface of a material; (B) applying a liquid B on at least one portion of the resin A, when the resin A is liquid or partially solidified; (C) polymerizing, also separately, the resin A and the liquid B; and (D) removing the polymerized liquid B.

An object of the present invention is to provide a copolymer having the characteristic of developing high viscosity, and lowering its viscosity with an increase in rate of shear, particularly a copolymer having the characteristic of developing viscosity, and lowering its viscosity with an increase in rate of shear even in an aqueous coating composition that contains a surfactant. The present invention provides a copolymer obtainable by copolymerization of a monomer component (m) that includes: (m-1), a macromonomer having (i) a backbone that comprises a polymer chain having a number average molecular weight of 1,000 to 10,000 obtainable by polymerizing a monomer component (I) that contains 5 to 100 mass % of a C4-C24 alkyl-containing polymerizable unsaturated monomer (a), and (ii) a polymerizable unsaturated group; and (m-2) a polymerizable unsaturated monomer containing a hydrophilic group.