A laminate containing a metallic base layer and a transparent colored layer formed on the metallic base layer. The metallic base layer contains an aluminum pigment, a light-scattering component, a surface adjusting agent, and a rheology control agent, the aluminum pigment being present in an amount of 15 to 70 parts by mass, on a solids basis; and the light-scattering component being present in an amount of 5 to 55 parts by mass, on a solids basis, based on 100 parts by mass of the metallic base layer. The transparent colored layer contains a resin component, a curing agent, and a color pigment, the color pigment being present in an amount of 0.5 to 10 parts by mass, based on 100 parts by mass of the resin solids content of the transparent colored layer.

Disclosed is a method for treating a grained material. A nonlimiting example of the method includes the operations of providing a workpiece having grains, exasperating a surface of the workpiece to open the grains, applying at least one coat of a base paint to the exasperated surface, applying at least one layer of clear coat on the base paint, applying at least one of a glaze and a paint on the clear coat, and surface treating to reveal grains of the workpiece. Disclosed also are items of furniture and sheet materials treated by the aforementioned process.

Surfacing films and related processes are provided. These films include a first clear coat layer comprising a first crosslinked polyurethane that is the reaction product of an isocyanate; a polyol selected from the group consisting of: a caprolactone polyol, polycarbonate polyol, a polyester polyol, acrylic polyol, polyether polyol, polyolefin polyol, and mixtures thereof; and a hydroxy-functional silicone poly(meth)acrylate; a second clear coat layer comprising a crosslinked polymer that is essentially free of hydroxy-functional silicone poly(meth)acrylate; a bulk layer comprising a thermoplastic polyurethane; and an adhesive layer. The provided films overcome the problem of migration of solvents and other impurities into the polyurethane bulk layer because the clear coat layer is cured, and solvents removed, prior to the coating of the polyurethane bulk layer. Manufacturing of these films can provide substantially faster line speeds and reduced waste.

The present invention relates to a polyol component comprising a1) a polyol having a weight averaged molecular weight Mw of from 1,000 to 4,000 Dalton, a number averaged molecular weight Mn of from 600 to 2,500 Dalton, an OH value between 80 and 300 mg KOH/g of resin and a glass transition temperature Tg of from −10 to 90° C., and a2) between 0.1 and 10% by weight of polyurea product as rheological agent, as well as it use in a crosslinkable composition especially suitable for clear coat applications.

Multi-layer coatings comprising polymerization reaction products of 1,1-di-activated vinyl compounds are described. Also provided are processes for coating substrates with curable compositions comprising 1,1-di-activated vinyl compounds. Also provided are articles coated with this composition.

Provided herein is a process for the pretreatment coating and subsequent lacquering of plastics substrates, wherein a pretreatment layer is produced on a plastics substrate via application, onto the plastics substrate, of a solution or dispersion including at least one organic solvent (L) and, dispersed or dissolved therein, at least one plastic (K), and subsequent evaporation to remove the organic solvent. Then a lacquer layer is produced on the pretreated plastics substrate.

Provided is a multilayer coating film including a metallic base coating film and a transparent colored coating film that contains a blue pigment and that is disposed on the metallic base coating film, wherein the value of hue angle h in an L*C*h color space diagram of the multilayer coating film is within the range of 225° to 300°, and when X=C*45/L*45 and Y=[(L*15).sup.2+(C*15).sup.2)].sup.1/2+[(L*25).sup.2+(C*25).sup.2)].sup.1/2, X is 2 to 20 and Y is 50 to 250, provided that C*15, C*25, and C*45 each represent a chroma of the multilayer coating film calculated from a spectral reflectance of light illuminated at an incident angle of 45° with respect to the multilayer coating film and received at angles of 15°, 25°, and 45° deviated from specular reflection light, and that L*15, L*25, and L*45 each represent a lightness of the multilayer coating film calculated from a spectral reflectance of light illuminated at an incident angle of 45° with respect to the multilayer coating film and received at angles of 15°, 25° and 45° deviated from specular reflection light.

A method for forming a multilayer coating film includes forming a base coating film, a photoluminescent coating film, and forming a clear coating in this order, wherein the photoluminescent coating film uses a photoluminescent pigment dispersion containing a scaly photoluminescent pigment having a thickness T of 1 to 65 nm, wherein when all photoluminescent pigment present in the multilayer coating film is projected onto the surface of the multilayer coating film, the area occupancy ratio R indicating how much of the surface of the multilayer coating film is occupied by the parts in which the photoluminescent pigment is projected, is 0.1 to 50 percent; and the T and R satisfy “T (nm)×R (%)≤2000”. The obtained multilayer coating film can manifest excellent photoluminescence.

Multi-layer coatings comprising polymerization reaction products of 1,1-di-activated vinyl compounds are described. Also provided are processes for coating substrates with curable compositions comprising 1,1-di-activated vinyl compounds. Also provided are articles coated with this composition.

A multi-layer coating system includes: (a) a first basecoat layer formed from a first coating composition including a free polyisocyanate and hydroxyl functional polymeric core-shell particles; (b) a second basecoat layer applied over at least a portion of the first basecoat layer, the second basecoat layer formed from a second coating composition including carboxylic acid functional polymeric core-shell particles; and (c) a topcoat layer applied over at least a portion of the second basecoat layer, the topcoat layer formed from a coating composition including least one free polyisocyanate having a weight average molecular weight of less than 600 g/mol and at least one film-forming resin in which an amount of free polyisocyanate having a weight average molecular weight of less than 600 g/mol is greater than 5 weight %, based on the total resin solids of the coating composition that forms the topcoat layer.