A description is given of a method for producing a molding material mixture or for producing a molding material mixture and a molding therefrom, preferably casting molds or cores, for use in the foundry industry, where the molding material mixture comprises a mold base material and a solution or dispersion comprising lithium-containing waterglass, comprising the following steps: (1) producing or providing a kit at least comprising as separate components: (K1) an aqueous solution or dispersion comprising waterglass and (K2a) a first waterglass-free solution or dispersion comprising lithium ions in solution in water, and also preferably (K2b) a second waterglass-free solution or dispersion, preferably o comprising lithium ions in solution in water with a lower concentration than in component (K2a), and thereafter (2) producing a mixture of the mold base material with a fraction of component (K1) and with a fraction of component (K2a), and also optionally with a fraction of component (K2b). Further described is an aforementioned kit, more particularly for application in the method of the invention. An installation is specified as well for producing an intermediate solution or dispersion, comprising lithium-containing waterglass, for use in producing a molding material mixture or for producing a molding material mixture and a molding therefrom.

A post-treatment process for increasing the hot strength of a formed part (100) made of particulate material and binder is disclosed, wherein the formed part (100) is formed a part manufactured by 3D printing (S72) and after its manufacture is heated (S30) using a heating device (40), and the heated formed part (100) is exposed (S50) to an atmosphere enriched with gaseous water generated by supplying water.

A curing agent for water glass molding comprises: ester; amorphous silica; and water. The amorphous silica is formed by means of a pyrolysis method and/or by means of a precipitation method. Also disclosed is a use of the curing agent for water glass molding in preparation of a casting mold and a mold core. Respective components of the curing agent comprising ester, amorphous silica and water are mixed at a high speed to form a suspension. Next, the suspension is applied to prepare a water glass self-hardening sand. The curing agent does not cause powder contamination, and can be measured and added conveniently. Also disclosed are a manufacturing method of the curing agent for water glass molding and a water glass self-hardening sand.

Purposes of the present invention are to provide a dry coated sand having a high degree of fluidity at the room temperature, a method of advantageously producing the coated sand, and a method of producing a casting mold having excellent properties, by using the coated sand. The dry coated sand is obtained by mixing an aqueous solution of a water glass used as a binder, with a heated refractory aggregate, whereby water in the aqueous solution is evaporated, and a coating layer of the binder is formed on surfaces of the refractory aggregate. A moisture percentage in the thus obtained dry coated sand is controlled so as to be not more than 0.5% by mass. The intended casting mold is obtained by filling a molding cavity of a forming mold, with the dry coated sand, and passing a steam through the coated sand, to solidify or cure the coated sand.

A sand mold-forming additive capable of making a sand mold-forming composition having excellent forming property and a sand mold having excellent moisture resistance is provided. The sand mold-forming additive contains 0.01-2.00 parts by weight of an inorganic alkali metal compound (B) per 100 parts by weight of anionic surfactant (A). The inorganic alkali metal compound (B) is at least one selected from sodium chloride and sodium sulfate. The ionic surfactant (A) is preferably at least one selected from alkyl sulfonic acid metal salts (A1), alkyl sulfuric acid metal salts (A2), and polyoxyalkylene alkyl ether sulfuric acid ester metal salts (A3).

Inorganic coated sand in a dry state having refractory aggregate; and an inorganic binder layer formed on a surface of the refractory aggregate, in which the inorganic binder layer contains a metasilicate hydrate.

The invention relates to an aqueous alkaline binder composition for curing with carbon dioxide gas, comprising a negatively charged or uncharged phenol-aldehyde resin, comprising phenol groups, which is selected from the group consisting of resoles and mixtures comprising one or more resoles and also one or more novolacs, an oxyanion selected from the group consisting of borate ions, aluminate ions, stannate ions, zirconate ions, titanate ions, and mixtures thereof, for forming a stable complex with the resole phenol-aldehyde resin, where the total molar amount of the phenol groups of the phenol-aldehyde resin in the aqueous alkaline binder composition is in the range from 1 to 3 mol/kg, based on the total mass of the aqueous alkaline binder composition, and where the phenol-aldehyde resin possesses an average molecular weight (Mw) in the range from 750 to 1200 g/mol, determined by means of gel permeation chromatography. The invention relates, moreover, to a corresponding use, to a molding mixture for producing a foundry molding, and also to a corresponding method for producing a foundry molding, and to a corresponding foundry molding.

A method for manufacturing a structure from a granular material, called sand, in particular a mold. A layer of sand is deposited. The layer of sand is selectively agglomerated by spraying, using a spray nozzle, an inorganic binder having an M2SiO3 type (meta)silicate dissolved in a solvent. Prior to the spraying, the inorganic binder is heated to a temperature to confer on it a viscosity less than 0.2 Pa.Math.s. A device for implementing the method is provided.

What is described is the use of a particulate material comprising, as its sole constituent or as one of multiple constituents, a particulate synthetic amorphous silicon dioxide having a particle size distribution with a median in the range from 0.1 to 0.4 ?m, determined by means of laser scattering, as additive for a molding material mixture at least comprising: a refractory mold base material having an AFS grain fineness number in the range from 30 to 100, particulate amorphous silicon dioxide having a particle size distribution with a median in the range from 0.7 to 1.5 ?m, determined by means of laser scattering, and water glass, for increasing the moisture resistance of a molding producible by hot curing of the molding material mixture. Also described are corresponding processes, mixtures and kits.

The invention relates to an aqueous alkaline binder composition for curing with carbon dioxide gas, comprising a negatively charged or uncharged phenol-aldehyde resin, comprising phenol groups, which is selected from the group consisting of resoles and mixtures comprising one or more resoles and also one or more novolacs, an oxyanion selected from the group consisting of borate ions, aluminate ions, stannate ions, zirconate ions, titanate ions, and mixtures thereof, for forming a stable complex with the resole phenol-aldehyde resin, and one or more silanes in a total amount in the range from 2.5 to 10 wt %, based on the total mass of the binder composition, where the total molar to amount of the phenol groups of the phenol-aldehyde resin in the aqueous alkaline binder composition is in the range from 1 to 3 mol/kg, based on the total mass of the aqueous alkaline binder composition. The invention relates, moreover, to a corresponding use, to a molding mixture for producing a foundry mold, and also to a corresponding method for producing a foundry mold, and to a corresponding foundry mold.