A manufacturing method which manufactures articles which have hollow areas inside them which are subject to their own internal vacuum. A 3-D printer can be located inside a vacuum chamber and the article(s) can be 3-D printed, thereby the hollow area inside each such article is subject to its own vacuum. When removed from the vacuum chamber, the article's hollow area remains subject to its own internal vacuum.

A structured three-phase composite which include a metal phase, a ceramic phase, and a gas phase that are arranged to create a composite having low thermal conductivity, having controlled stiffness, and a CTE to reduce thermal stresses in the composite when exposed to cyclic thermal loads. The structured three-phase composite is useful for use in structures such as, but not limited to, heat shields, cryotanks, high speed engine ducts, exhaust-impinged structures, and high speed and reentry aeroshells.

The present disclosure provides a method for producing a metal structure having holes dispersed in a matrix and having inorganic particles disposed inside the holes, that are capable of moving in the holes independently of the matrix, the method making it possible to increase the proportion of inorganic particles in the metal structure that are capable of moving in the holes independently of the matrix. In the method for producing a metal structure whereby inorganic particles are disposed inside holes dispersed in a matrix so as to be capable of moving independently of the matrix, the hollow particles covering the inorganic particles which are distributed in the matrix of the metal structure are fragmented so that the inorganic particles are disposed inside the holes formed by fragmenting the hollow particles.

A manufacturing method of a graphene metal composite material includes the steps of providing metal powder including metal particles, graphene powder including graphene pieces and binder including wax material, wherein each graphene piece includes graphene molecules connected with each other and including six carbon atoms annually connected, and one of the carbon atom of each graphene molecule is bonded with a functional group by an SP3 bond; mixing the powders and the binder into a powder material, wherein the SP3 bond is heated and broken by friction, and the graphene molecules are connected with each other via the broken SP3 bond to wrap the respective metal particles; melting and molding the powder material to form a green part; removing the binder from the green part to form a brown part; and sintering the brown part to form a metal main part embedded a three-dimensional mash formed by the graphene molecules.

A graded multilayered composite comprises a metal matrix material having a first side and a second side opposite the first side. A first layer of microspheres is dispersed on the first side of the metal matrix material. A second layer of microspheres is dispersed on the second side of the metal matrix material.

A syntactic metal foam composite that is substantially fully dense except for syntactic porosity is formed from a mixture of ceramic microballoons and matrix forming metal. The ceramic microballoons have a uniaxial crush strength and a much higher omniaxial crush strength. The mixture is continuously constrained while it is consolidated. The constraining force is less than the omniaxial crush strength. The substantially fully dense syntactic metal foam composite is then constrained and deformation worked at a substantially constant volume. The deformation working is typically performed at a yield strength that is adjusted by way of selecting a working temperature at which the yield strength is approximately less than the omniaxial crush strength of the included ceramic microballoons. This deformation causes at least work hardening and grain refinement in the matrix metal.

A method is presented for producing hollow microspheres of metal oxides (HMOMS) and/or hollow metal silicates microspheres (HMSMS) in a transforming solution. The transforming solution contains an atom M, or an M-ion, or a radical containing M. M in the transforming solution has the thermodynamic ability to replace silicon atoms in hollow silica microspheres (HSMS) and/or hollow glass microspheres (HGMS). The maximum temperature for transformation is set by the chemical physical properties of the transforming solution, and the viscosity of the silica in the walls of the HSMS and/or the glass in the walls of the HGMS. Viscosity, of enough magnitude, helps retain the desired shape of the hollow sphere as it is transformed to HMOMS and/or HMSMS. Non-spherical shapes can be produced by increasing the transformation temperature whereby the viscosity of the walls of the HSMS and/or the HGMS is reduced. Transformation can take place at a single temperature or at several temperatures, each temperature for a separate hold time. Methods are presented for: 1. production of micro composite castings and continuous production of sheets of micro composites, both consisting of hollow spheres in a matrix, 2. harvesting of HMOMS and HMSMS, and 3. specialty castings for anisotropic properties using 3-dimensional printing.

A structured three-phase composite which include a metal phase, a ceramic phase, and a gas phase that are arranged to create a composite having low thermal conductivity, having controlled stiffness, and a CTE to reduce thermal stresses in the composite when exposed to cyclic thermal loads. The structured three-phase composite is useful for use in structures such as, but not limited to, heat shields, cryotanks, high speed engine ducts, exhaust-impinged structures, and high speed and reentry aeroshells.

Provided are a heat-resistant member provided with a heat-shielding coating suitable for stable manufacturing and excellent in heat-insulating, thermoresponsive and distortion accommodating properties, and a method for manufacturing the same. The heat-shielding coating includes a metallic portion formed of agglomerates of a plurality of metal particles, and inorganic compound particles dispersed in the metallic portion. The metal particles are diffusion-bonded each other, and the metallic portion and a base material of the heat-resistant member are diffusion-bonded each other. The manufacturing method includes the steps of depositing mixed particles of the metal particles and the inorganic compound particles on a surface of the base material in a film shape; resistance-heating the mixed particles by current-passing while pressurized in a thickness direction; diffusion-bonding the metal particles each other; and the metallic portion and the base material each other.

Provided are a heat-resistant member provided with a heat-shielding coating suitable for stable manufacturing and excellent in heat-insulating, thermoresponsive and distortion accommodating properties, and a method for manufacturing the same. The heat-shielding coating includes a metallic portion formed of agglomerates of a plurality of metal particles, and inorganic compound particles dispersed in the metallic portion. The metal particles are diffusion-bonded each other, and the metallic portion and a base material of the heat-resistant member are diffusion-bonded each other. The manufacturing method includes the steps of depositing mixed particles of the metal particles and the inorganic compound particles on a surface of the base material in a film shape; resistance-heating the mixed particles by current-passing while pressurized in a thickness direction; diffusion-bonding the metal particles each other; and the metallic portion and the base material each other.