A gas-shielded flux cored welding electrode comprises a ferrous metal sheath and a core within the sheath enclosing core ingredients. The core ingredients and sheath together comprise, in weight percentages based on the total weight of the core ingredients and the sheath: 0.25 to 1.50 manganese; 0.02 to 0.12 carbon; 0.003 to 0.02 boron; 0.2 to 1.5 silicon; 0 to 0.3 molybdenum; at least one of titanium, magnesium, and aluminum, wherein the total content of titanium, magnesium, and aluminum is 0.2 to 2.5; 3 to 12 titanium dioxide; at least one arc stabilizer, where the total content of arc stabilizers is 0.05 to 1.0; no greater than 10 of additional flux system components; remainder iron and incidental impurities.

A weld wire of the present invention comprises a steel sheath encapsulating a fluxed core having a combination of fluxing compounds and alloying elements. The fluxing compounds comprise up to 2% Wt of fluoride compounds and up to 49% Wt of oxide compounds. The alloying elements comprise Mn, Ni, Co, Ti and up to about 0.98% Wt of C. The amount of Co is sufficient to produce a ferrite-bainite weld metal morphology of a resulting weld. A yield strength of the resulting weld was measured from about 95 ksi to about 111 ksi.

A flux cored welding electrode includes a ferrous metal sheath and a core within the sheath including core ingredients, the core ingredients including, in weight percent based on the total weight of the flux cored welding electrode: 2.0-3.0 aluminum, 1.0-2.0 manganese, and 0.001-0.5 rare earth metal oxide including three or more of Cerium (Ce), Lanthanum (La), Neodymium (Nd) and Praseodymium (Pr).

The Cu core ball contains a Cu ball and one or more metal layer for covering a surface of the Cu ball, each layer including one or more element selected from Ni, Co, Fe and Pd. The Cu ball contains at least one element selected from Fe, Ag, and Ni in a total amount of 5.0 or more to 50.0 ppm by mass or lower, S in an amount of 0 ppm by mass or more to 1.0 ppm by mass or lower, P in an amount of 0 ppm by mass or more to less than 3.0 ppm by mass, and remainder of Cu and inevitable impurities. The Cu ball contains purity which is 99.995% by mass or higher and 99.9995% or lower, sphericity which is 0.95 or higher and a diameter of 1 m or more to 1000 m or lower.

A flux-cored wire according to an aspect of the present invention includes: a steel sheath; and a flux filling the inside of the steel sheath, in which the flux contains 0.11% or more in total of a fluoride in terms of F-equivalent value, 4.30% to 7.50% of a Ti oxide in terms of TiO.sub.2 equivalent, 0.30% to 2.40% in total of an oxide in terms of mass %, and 0% to 0.60% in total of a carbonate in terms of mass %, the amount of a Ca oxide in terms of CaO is less than 0.20% in terms of mass %, the amount of CaF.sub.2 is less than 0.50%, a chemical composition of the flux-cored wire is within a predetermined range, a Z value is 2.00% or less, a V value is 5.0 to 27.0, and Ceq is 0.30% to 1.00% or less.

It is an objective of the invention to provide a conductive joint article exhibiting electrical joinability comparable to that of solder joining of easy-to-solder joinable metals even when a joined member of the conductive joint article is made of a hard-to-solder joinable metal. There is provided a conductive joint article with conductive joined members electrically joined via a joining layer, at least one of the joined members being made of a hard-to-solder joinable metal. The joining layer comprises an oxide glass phase and a conductive metal phase. The oxide glass phase includes vanadium as a major constituent and at least one of phosphorus, barium and tungsten as an accessory constituent, and has a glass transition point of 390 C. or less. And, connection resistance between the joined members exhibits less than 110.sup.5 /mm.sup.2.

The invention provides an ignition flux for arc stud welding, including 30-55 wt % SiO.sub.2, 30-55 wt % NiO, 10-35 wt % AlF.sub.3, and 5-25 wt % NiF.sub.2, or including 30-55 wt % TiO.sub.2, 30-55 wt % NiO, 10-35 wt % AlF.sub.3, and 5-25 wt % NiF.sub.2. As such, the electric arc can be easily created and smoothly formed. The invention further provides an arc stud welding method utilizing such ignition flux. As such, the fastener and the metal workpiece can be tightly connected together without the need of inserting an ignition tip into the welding portion of a fastener.

This disclosure relates generally to welding and, more specifically, to electrodes for arc welding, such as Gas Metal Arc Welding (GMAW) or Flux Core Arc Welding (FCAW) of zinc-coated workpieces. In an embodiment, a welding consumable for welding a zinc-coated steel workpiece includes a zinc (Zn) content between approximately 0.01 wt % and approximately 4 wt %, based on the weight of the welding consumable. It is presently recognized that intentionally including Zn in welding wires for welding galvanized workpieces unexpectedly and counterintuitively alleviates spatter and porosity problems that are caused by the Zn coating of the galvanized workpieces.

A self-shielded flux cored arc welding electrode is disclosed including a ferrous metal sheath and a core within the sheath enclosing core ingredients comprise a composition window of aluminum, manganese and rare earth metals in wires of about 2.0-3.0 wt. % [Al], 1.0-2.0 wt. % [Mn] and 0.001-0.11 wt. % rare earth metals or 0.001-0.5% rare earth metal oxides, such as, but not limited to, La, Ce, etc. Resulting welds include 0.7-1.0 wt. % [Al] and 1.1-1.5 wt. % [Mn]. Resulting welds have a maximum diffusible hydrogen content of 5 mL/100 g or less, Resulting welds also have a Charpy V-notch toughness at 40 F. of at least 100 ft-lbs.

A flux-cored wire for gas shielded arc welding is provided which affords excellent welding workability for high heat input welding and enables weld metal having good mechanical properties to be obtained. The flux-cored wire for gas shielded arc welding includes C, Mn, Si, elemental Ti, elemental Al, Fe, ZrO.sub.2, TiO.sub.2, and NaF, each within a predetermined range relative to the total mass of the wire. In the flux-cored wire, 1[ZrO.sub.2]/[NaF]50 is satisfied, where [ZrO.sub.2] is the ZrO.sub.2 content, and [NaF] is the NaF content.